Skip to main content
SpringerLink
Log in

Dinuclear copper(II) complexes with an unsymmetrical exchange fragment

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

New dinuclear copper(II) complexes with azomethines and hydrazones, which were produced by condensation of substituted salicylaldehyde derivatives with 1,3-diaminopropan-2-ol or carbo(thiocarbo) hydrazide, were studied. The structures of the [Cu2L(μ-CH2ClCOO)(CH3OH)]·(CH3OH) (L = C17H15N2O3) and [Cu2L2(Cl3CCO)(CH3OH)]·H2O (L2 = C32H42N4O3) complexes were established by X-ray diffraction. The magnetic properties of these complexes, including the influence of the nature of the substituents in the ligands on exchange interactions, were studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. A. Kogan, V. V. Zelentsov, O. A. Osipov, and A. S. Burlov, Usp. Khim., 1979, 48, 1208 [Russ. Chem. Rev., 1979, 48 (Engl. Transl.)].

    Google Scholar 

  2. V. A. Kogan and V. V. Lukov, Koord. Khim., 1997, 23, 13 [Russ. J. Coord. Chem., 1997, 23 (Engl. Transl.)].

    Google Scholar 

  3. V. A. Kogan and V. V. Lukov, Koord. Khim., 2004, 30, 219 [Russ. J. Coord. Chem., 2004, 30 (Engl. Transl.)].

    Google Scholar 

  4. V. T. Kalinnikov, Yu. V. Rakitin, and V. M. Novotortsev, Usp. Khim., 2003, 72, 1123 [Russ. Chem. Rev., 2003, 72 (Engl. Transl.)].

    Google Scholar 

  5. Yu. V. Rakitin and V. T. Kalinnikov, Sovremennaya magnetokhimiya [Modern Magnetochemistry], Nauka, St.-Petersburg, 1994, 272 pp. (in Russian).

    Google Scholar 

  6. M. Verdaguer, Polyhedron, 2001, 70, 1115.

    Article  Google Scholar 

  7. E. Ruiz, P. Alemany, S. Alvarez, and J. Cano, Inorg. Chem., 1997, 36, 3683.

    Article  PubMed  Google Scholar 

  8. Sh. Emori, G. Hirofumi, and M. Hiroshi, Bull. Chem. Soc. Jpn, 1996, 1921.

  9. R. Ando, M. Nagai, T. Yagyu, and M. Maeda, Inorg. Chim. Acta, 2003, 351, 107.

    Article  Google Scholar 

  10. E. Ruiz, P. Alemany, and S. Alvarez, J. Am. Chem. Soc., 1997, 119, 1297.

    Article  Google Scholar 

  11. A. Asokan, B. Varghese, and P. T. Monoharan, Inorg. Chem., 1999, 38, 4393.

    Article  PubMed  Google Scholar 

  12. S. Mukherjee, T. Weyhermiiller, and E. Bothe, Eur. J. Inorg. Chem., 2003, 863.

  13. Yu. P. Tupolova, V. V. Lukov, V. A. Kogan, L. D. Popov, V. V. Tkachev, and A. N. Chekhlov, Zh. Neorg. Khim., 2003, 48, 1780 [Russ. J. Inorg. Chem., 2003, 48 (Engl. Transl.)].

    Google Scholar 

  14. E. V. Dontsova, V. V. Lukov, V. A. Kogan, L. D. Popov, V. V. Tkachev, G. V. Shilov, and D. D. Makitova, Zh. Neorg. Khim., 2003, 48, 2063 [Russ. J. Inorg. Chem., 2003, 48 (Engl. Transl.)].

    Google Scholar 

  15. V. A. Kogan, V. V. Lukov, and S. I. Levchenkov, Mendeleev Commun., 1998, 4, 145.

    Article  Google Scholar 

  16. Y. Nishida and S. Kida, Inorg. Chem., 1988, 27, 447.

    Article  Google Scholar 

  17. Y. Mikariya, T. Sasaki, and A. Anjiki, Bull. Chem. Soc. Jpn, 1992, 62, 334.

    Google Scholar 

  18. D. S. Dash, A. K. Panda, and A. Mahapatra, J. Indian Chem. Soc., 2002, 79, 642.

    Google Scholar 

  19. V. M. Novotortsev, Yu. V. Rakitin, S. E. Nefedov, and I. L. Eremenko, Izv. Akad. Nauk, Ser. Khim., 2000, 437 [Russ. Chem. Bull., Int. Ed., 2000, 49, 438].

    Google Scholar 

  20. V. A. Kogan, V. V. Lukov, and V. M. Novotortsev, Koord. Khim., 2005, 31,No. 5 [Russ. J. Coord. Chem., 2005, 31 (Engl. Transl.)].

  21. Yu. P. Tupolova, V. V. Lukov, V. A. Kogan, L. D. Popov, I. E. Gevorkyan, V. V. Tkachev, G. V. Shilov, and D. D. Makitova, Zh. Neorg. Khim., 2004, 49, 1993 [Russ. J. Inorg. Chem., 2004, 49 (Engl. Transl.)].

    Google Scholar 

  22. I. B. Bersuker, Electronic Structure and Properties of Transition Metal Compounds: Introduction to the Theory, Wiley, New York, 1996.

    Google Scholar 

  23. A. J. Costa-Filho, O. R. Nascimento, L. Ghiveder, and R. Calvo, J. Phys. Chem. B, 2001, 105, 5039.

    Article  Google Scholar 

  24. C. Ruiz-Perez, M. Hernandez-Molina, P. Lorenzo-Luis, F. Lloret, J. Cano, and M. Julve, Inorg. Chem., 2000, 39, 3845.

    PubMed  Google Scholar 

  25. B. Bleaney and K. O. Bowers, Proc. Roy. Soc. London, Ser. A, 1952, 214, 451.

    Google Scholar 

  26. Yu. V. Rakitin, Magnitnye svoistva poliyadernykh kompleksov perekhodnykh metallov [Magnetic Properties of Polynuclear Transition Metal Complexes], in Itogi nauki i tekhniki. Stroenie molekul i khimicheskaya svyaz [Advances in Science and Tech nology, Ser. Molecular Structures and Chemical Bonding], VINITI, Moscow, 1986, p. 95.

    Google Scholar 

  27. G. M. Sheldrick, SHELXS97. Program for the Solution of Crystal Structures, University of Gottingen, Germany, 1997.

    Google Scholar 

  28. G. M. Sheldrick, SHELXL97. Program for the Refinement of Crystal Structures, University of Gottingen, Germany, 1997.

    Google Scholar 

  29. SMART (Control) and SAINT (Integration) Software, Version 5.0, Bruker AXS Inc., Madison, WI, 1997.

  30. A. C. T. North, D. C. Phillips, and F. S. Mattews, Acta Crystallogr., Sect. A, 1968, 24, 351; G. M. Sheldrick, SADABS, Program for Scaling and Correction of Area Detector Data, University of Gottingen, 1997 (based on the method of R. H. Blessing, Acta Crystallogr., Sect. A, 1995, 51, 33).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Rostov State University, 7 ul. Zorge, 344090, Rostov on Don, Russian Federation

    V. A. Kogan & V. V. Lukov

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    V. M. Novotortsev, I. L. Eremenko & G. G. Aleksandrov

Authors
  1. V. A. Kogan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. V. Lukov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. M. Novotortsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. L. Eremenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. G. Aleksandrov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

__________

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 592–596, March, 2005.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kogan, V.A., Lukov, V.V., Novotortsev, V.M. et al. Dinuclear copper(II) complexes with an unsymmetrical exchange fragment. Russ Chem Bull 54, 600–605 (2005). https://doi.org/10.1007/s11172-005-0294-4

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-005-0294-4

Key words

Search

Navigation