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Arene complexes [(η-C5H5)M(η-C6R6)]2+ (M = Rh, Ir)

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Abstract

The dicationic arene complexes [CpM(arene)](BF4)2 (arene = C6H6, 1,3,5-C6H3Me3, or C6Me6) were synthesized by the reactions of the solvated complexes [CpM(MeNO2)3](BF4)2 (M = Rh, Ir) with benzene and its derivatives. The solvated complexes were generated in situ by abstraction of I− from [CpMI2]2 with AgBF4. A procedure was developed for the synthesis of the iodide [CpRhI2]2 based on the reaction of the cyclooctadiene derivative CpRh(1,5-C8H12) with I2. The structure of the [CpRh(C6Me6)](BF4)2 complex was established by X-ray diffraction analysis.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    D. A. Loginov, M. M. Vinogradov, Z. A. Starikova, P. V. Petrovskii & A. R. Kudinov

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  1. D. A. Loginov
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  2. M. M. Vinogradov
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  3. Z. A. Starikova
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  4. P. V. Petrovskii
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  5. A. R. Kudinov
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1871–1874, September, 2004.

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Loginov, D.A., Vinogradov, M.M., Starikova, Z.A. et al. Arene complexes [(η-C5H5)M(η-C6R6)]2+ (M = Rh, Ir). Russ Chem Bull 53, 1949–1953 (2004). https://doi.org/10.1007/s11172-005-0054-5

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  • DOI: https://doi.org/10.1007/s11172-005-0054-5

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