Abstract
Pattern of soybean oil epoxidation catalyzed by chlorinated KU-2 × 8 cation exchanger in the presence of H2O2 and propanoic acid was studied. The epoxidation rate and the selectivity of formation and yield of the epoxidation product were studied as influenced by the concentration of H2O2, C2H5COOH, and the catalyst. Some kinetic and activation parameters of soybean oil epoxidation were determined.
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REFERENCES
Blagonravova, A.A. and Nepomnyashchii, A.I., Lakovye epoksidnye smoly (Varnish Epoxy Resins), Moscow: Khimiya, 1970.
US Patent 2 997 484.
Chalabiev, Ch.A., Guseinov, M.M., and Salakhov, M.S., Zh. Prikl. Khim., 1978, vol. 51, no.9, pp. 2036–2041.
Ermakov, O.A., Utkin, B.N., Yanova, N.A., and Makarcheva, T.V., Zh. Prikl. Khim., 1976, vol. 49, no.9, pp. 2059–2061.
Kozlov, Yu.N., Mandelli, D., Voitiski, K.B., and Shul'pin, G.B., Zh. Fiz. Khim., 2004, vol. 78, no.3, pp. 453–457.
Ermakov, O.A. and Yanova, N.A., Kinet. Katal., 1975, vol. 16, no.4, pp. 1100–1106.
Sadykhov, O.A., Guseinov, M.M., and Chalabiev, Ch.A., Zh. Org. Khim., 1984, vol. 20, no.8, pp. 1638–1645.
Chalabiev, Ch.A., Sadykhov, O.A., Guseinov, M.M., Kinet. Katal., 1983, vol. 24, no.6, pp. 1400–1405.
Kupysevich, O.Ya. and Pik, Z.G., Zh. Org. Khim., 1996, vol. 32, no.6, pp. 817–819.
Krylov, O.V., Kinet. Katal., 2002, vol. 43, no.2, pp. 310–316.
USSR Inventor's Certificate, no. 1 728 250.
USSR Inventor's Certificate, no. 1 685 932.
Houben-Weyl, Methoden der organischen Chemie. Band 2. Analytische Methoden, Stuttgart: Georg Tieme, 1953
Swern, D., Organic Peroxyacids, New York: Wiley, 1970, vol. 5, no.1.
Toroptseva, A.M., Belogorodskaya, K.V., and Bondarenko, V.M., Laboratornyi praktikum po khimii i tekhnologii vysokomolekulyarnykh soedinenii (Laboratory Course of Chemistry and Technology of Macromolecular Compounds), Leningrad: Khimiya, 1972.
Chalabiev, Ch.A., Agabalaev, Sh.B., and Salakhov, M.S., Zh. Prikl. Khim., 1978, vol. 51, no.3, pp. 577–580.
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Translated from Zhurnal Prikladnoi Khimii, Vol. 78, No. 10, 2005, pp. 1707–1711.
Original Russian Text Copyright © 2005 by Gurbanov, Chalabiev, Mamedov, Efendiev.
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Gurbanov, M.S., Chalabiev, C.A., Mamedov, B.A. et al. Epoxidation of Soybean Oil in the Course of Cooxidation with Hydrogen Peroxide in the Presence of Propanoic Acid and Chlorinated KU-2 × 8 Cation Exchanger. Russ J Appl Chem 78, 1678–1682 (2005). https://doi.org/10.1007/s11167-005-0585-4
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DOI: https://doi.org/10.1007/s11167-005-0585-4