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Sulfonamide-functionalized covalent organic framework (COF-SO3H): an efficient heterogeneous acidic catalyst for the one-pot preparation of polyhydroquinoline and 1,4-dihydropyridine derivatives

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Abstract

Herein, we report the sulfonamide-functionalized covalent organic framework (COF-SO3H) prepared from melamine and terephthalaldehyde and subsequent sulfonation, as an acidic porous catalyst for the one-pot preparation of polyhydroquinoline and 1,4-dihydropyridine derivatives. COF-SO3H was characterized by FT-IR, EDX, TGA, SEM, XRD, and BET. This methodology offers several advantages including high yield, short reaction time, simple workup procedure, solvent-free conditions, ease of separation, and recyclability.

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One-pot preparation of polyhydroquinoline and 1, 4-dihydropyridine derivatives

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Acknowledgements

The financial support of this work by the research council of Islamic Azad University of Ahvaz is greatly acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Islamic Azad University, Ahvaz Branch, Ahvaz, Iran

    Razieh Farsi & Mohammad Kazem Mohammadi

  2. ACECR-Production Technology Research Institute, Ahvaz, Iran

    Seyyed Jafar Saghanezhad

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  1. Razieh Farsi
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  2. Mohammad Kazem Mohammadi
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  3. Seyyed Jafar Saghanezhad
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Correspondence to Mohammad Kazem Mohammadi.

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Farsi, R., Mohammadi, M.K. & Saghanezhad, S.J. Sulfonamide-functionalized covalent organic framework (COF-SO3H): an efficient heterogeneous acidic catalyst for the one-pot preparation of polyhydroquinoline and 1,4-dihydropyridine derivatives. Res Chem Intermed 47, 1161–1179 (2021). https://doi.org/10.1007/s11164-020-04322-5

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