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Preparation, characterization and utilization of a novel dicationic molten salt as catalyst for the synthesis of bis(6-amino-1,3-dimethyluracil-5-yl)methanes

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Abstract

In this research, firstly, preparation and characterization of a novel dicationic molten salt, namely N,N,N′,N′-tetramethylethylenediaminium bisulfate ([TMEDA][HSO4]2), by 1H NMR, 13C NMR, FT-IR, mass, thermogravimetry, derivative thermogravimetry and differential thermal analysis data have been reported. Thereafter, utilization of [TMEDA][HSO4]2 as a recyclable catalyst for the solvent-free synthesis of bis(6-amino-1,3-dimethyluracil-5-yl)methanes via the reaction of 6-amino-1,3-dimethyluracil (2 eq.) and arylaldehydes (1 eq.) has been described.

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Acknowledgements

We thank the Research Council of Payame Noor University for the support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Payame Noor University, PO Box 19395-3697, Tehran, Iran

    Abdolkarim Zare, Aysoda Ghobadpoor & Tayebeh Safdari

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  1. Abdolkarim Zare
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  2. Aysoda Ghobadpoor
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  3. Tayebeh Safdari
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Correspondence to Abdolkarim Zare.

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Zare, A., Ghobadpoor, A. & Safdari, T. Preparation, characterization and utilization of a novel dicationic molten salt as catalyst for the synthesis of bis(6-amino-1,3-dimethyluracil-5-yl)methanes. Res Chem Intermed 46, 1319–1327 (2020). https://doi.org/10.1007/s11164-019-04036-3

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