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Effect of acid on the crystalline phase of TiO2 prepared by hydrothermal treatment and its application in the oxidative steam reforming of methanol

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Abstract

Titania (TiO2) supports with anatase (A), mixed, and rutile (R) crystalline phases were prepared via the hydrothermal treatment of titanium isopropoxide and investigated as a catalyst for the oxidative steam reforming of methanol (OSRM). The different TiO2 phases were synthesized using different types of acid: acetic (HAc), nitric, and a mixture of HAc and hydrochloric acids, and hydrothermal (90 or 200 °C) or calcination (560 or 750 °C) temperatures. X-ray diffraction analysis revealed the crystal structure of successfully synthesized TiO2 with different TiO2-A:TiO2-R ratios. The TiO2-R with (110) and (101) planes showed the highest catalytic activity for OSRM in the temperature range of 200–400 °C.

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Acknowledgements

The authors acknowledge the contributions and financial support from Chulalongkorn University (CU-GES-60-04-63-03), Ratchadaphiseksomphot Endowment Fund. The Center for Advanced Studies in Nanotechnology for Chemical, Food and Agricultural Industries, KU Institute for Advanced Studies, Kasetsart University, Bangkok, Thailand, is acknowledged for technical support of HR-TEM. The authors thank the Thailand Research Fund (TRF) and National Science and Technology Development Agency (PHD/0237/2558) for the PhD scholarship funding of Ms. Srisin Eaimsumang. We also thank Mr. Thanaphat Atjayutpokin for the NH3-TPD measurements.

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Authors and Affiliations

  1. The Petroleum and Petrochemical College, Chulalongkorn University, Bangkok, 10330, Thailand

    Srisin Eaimsumang, Piyachat Prataksanon & Apanee Luengnaruemitchai

  2. Department of Chemical Technology, Faculty of Science, Chulalongkorn University, Pathumwan, Bangkok, 10330, Thailand

    Sangobtip Pongstabodee

  3. Center of Excellence on Petrochemical and Materials Technology, Chulalongkorn University Research Building, Bangkok, 10330, Thailand

    Sangobtip Pongstabodee & Apanee Luengnaruemitchai

  4. Center of Excellence on Catalysis for Bioenergy and Renewable Chemicals (CBRC), Chulalongkorn University, Phayathai Rd., Pathumwan, Bangkok, 10330, Thailand

    Apanee Luengnaruemitchai

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  1. Srisin Eaimsumang
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  2. Piyachat Prataksanon
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Correspondence to Apanee Luengnaruemitchai.

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Eaimsumang, S., Prataksanon, P., Pongstabodee, S. et al. Effect of acid on the crystalline phase of TiO2 prepared by hydrothermal treatment and its application in the oxidative steam reforming of methanol. Res Chem Intermed 46, 1235–1254 (2020). https://doi.org/10.1007/s11164-019-04031-8

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