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Performance and kinetic study on Pd/OMS-2 catalyst for CO catalytic oxidation: effect of preparation method

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Abstract

Manganese oxide octahedral molecular sieves (OMS-2) synthesized from hydrothermal (H-OMS-2), reflux (R-OMS-2), co-precipitation (C-OMS-2), and solid phase (S-OMS-2) methods were impregnated with palladium and used for CO catalytic oxidation. Preparation methods presented an obvious effect on the morphology and catalytic activity of Pd/OMS-2 catalysts for CO oxidation. The hydrothermal synthesized OMS-2 (Pd/H-OMS-2) exhibited more ordered nanorod structure and higher crystallinity than Pd/R-OMS-2, Pd/C-OMS-2, and Pd/S-OMS-2. Further surface analysis indicated that different preparation methods of synthesizing OMS-2 and the impregnation process followed have a significant effect on the chemical states of Mn and O over the final Pd/OMS-2 products. The kinetics studies showed the trend of apparent activation energy (E a) over different catalysts: Pd/H-OMS-2 (18.19 kJ/mol) < Pd/R-OMS-2 (21.56 kJ/mol) < Pd/C-OMS-2 (22.57 kJ/mol) < Pd/S-OMS-2 (29.44 kJ/mol). Over 99 % of the CO conversion was obtained at 35 °C by the optimal Pd/H-OMS-2 catalyst.

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Acknowledgments

This work is supported by the National Natural Science Foundation of China (No. 21307047).

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Authors and Affiliations

  1. Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming, 650500, People’s Republic of China

    Qiulin Zhang, Qixian Liu, Ping Ning, Xin Liu, Lisi Xu, Zhongxian Song, Yankang Duan & Tengfei Zhang

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  1. Qiulin Zhang
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  3. Ping Ning
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Correspondence to Ping Ning.

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Zhang, Q., Liu, Q., Ning, P. et al. Performance and kinetic study on Pd/OMS-2 catalyst for CO catalytic oxidation: effect of preparation method. Res Chem Intermed 43, 2017–2032 (2017). https://doi.org/10.1007/s11164-016-2743-0

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