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Study on methylene dichloride and butanolic extracts of Reutera lutea (Desf.) Maire (Apiaceae) as effective corrosion inhibitions for carbon steel in HCl solution

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Abstract

Methylene dichloride extract (MDE) and n-butanolic extract (BE) of Reutera lutea (Desf.) Maire were investigated as corrosion inhibitors for carbon steel (CS) in 1.0 M HCl using weight loss and potentiodynamic polarization measurements, electrochemical impedance spectroscopy, and scanning electron microscopy techniques. The effect of temperature on the corrosion behavior of CS was studied in the range of 293–323 K. The experimental results show that MDE and BE are good corrosion inhibitors and the protection efficiency increased with increasing concentration of the extracts, but decreased with rise in temperature. The extracts behaved as mixed-type corrosion inhibitors with highest inhibition at 700 and 800 mg L−1 for MDE and BE, respectively. The adsorption of extracts on the CS surface was found to follow the Freundlich isotherm, and the adsorption mode was found to be physisorption. The free energies, enthalpies, and entropies for the adsorption process and the apparent energies, enthalpies, and entropies of the dissolution process are explained in detail.

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Authors and Affiliations

  1. Laboratoire des Molécules Bioactives et Applications, Université de Tébessa, Route de Constantine, 12000, Tébessa, Algérie

    N. Djeddi & M. Benahmed

  2. Laboratoire de Phytochimie et Analyses Physicochimiques et Biologiques, Département de Chimie, Faculté des Sciences Exactes, Université Mentouri Constantine, Route d’Ain el Bey, 25000, Constantine, Algérie

    S. Akkal & E. Makhloufi

  3. Laboratoire de Valorisation des Ressources Naturelles Biologiques, Département de Biologie, Université Ferhat Abbas de Sétif, Setif, Algérie

    H. Laouer

  4. Laboratoire des Ressources Naturelles et Aménagement des Milieux Sensibles, Larbi ben M’Hidi University, Oum Elbouaghi, Algeria

    N. Gherraf

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  1. N. Djeddi
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Correspondence to M. Benahmed.

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Djeddi, N., Benahmed, M., Akkal, S. et al. Study on methylene dichloride and butanolic extracts of Reutera lutea (Desf.) Maire (Apiaceae) as effective corrosion inhibitions for carbon steel in HCl solution. Res Chem Intermed 41, 4595–4616 (2015). https://doi.org/10.1007/s11164-014-1555-3

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