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Schiff base bis(5-nitrosalycilaldehyde)ethylenediamine as colorimetric sensor for fluoride

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Abstract

Schiff bases are widely investigated to develop novel chemosensors for selective identification and determination of anions. In this communication, we have taken an old but novel Schiff base, bis(5-nitrosalycilaldehyde)ethylenediamine (5-NO2-Salen, L), as a receptor to investigate the binding interaction with different anions such as F−, I−, Cl−, and Br− using spectrophotometric and computational approaches. Addition of anions accelerated the tautomerization process of L. The enolimine form of L interacts through the phenolic-OH by intermolecular hydrogen bond that intensified the color of the receptor, and a significant hyperchromic shift was observed due to the fluoride anion.

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Acknowledgments

The authors thank the Director, S V National Institute of Technology, Surat, for encouragement and for providing necessary research facilities.

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Authors and Affiliations

  1. Department of Applied Chemistry, SV National Institute of Technology (SVNIT), Surat, 395007, Gujarat, India

    Nilkanth M. Mattiwala & Suban K. Sahoo

  2. Department of Chemistry, Kurukshetra University, Kurukshetra, Haryana, India

    Raj Kamal

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  1. Nilkanth M. Mattiwala
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  2. Raj Kamal
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  3. Suban K. Sahoo
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Correspondence to Suban K. Sahoo.

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Mattiwala, N.M., Kamal, R. & Sahoo, S.K. Schiff base bis(5-nitrosalycilaldehyde)ethylenediamine as colorimetric sensor for fluoride. Res Chem Intermed 41, 391–400 (2015). https://doi.org/10.1007/s11164-013-1200-6

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  • DOI: https://doi.org/10.1007/s11164-013-1200-6

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