Abstract
Uniform Bi2WO6 spheres with high visible light activity were prepared via a solvothermal route. A variety of techniques including transmission electron micrographs (TEM), X-ray powder diffraction (XRD), N2 adsorption, FT-IR spectra, and UV–Vis spectra were employed to characterize the structure of the Bi2WO6 materials so obtained. The results show that the sphere-like Bi2WO6 samples were successfully prepared. And, under the photocatalytic degradation of Rhodamine B, the samples demonstrated high activity, three times higher than that of a sample from the solid-state method. Moreover, the uniform structure made the sample easy to separate from the reaction solution, providing an intrinsic advantage to the normal Bi2WO6 samples.
Similar content being viewed by others
References
A. Fujishima, T.-N. Rao, D.A. Tryk, J. Photochem. Photobiol. C 1, 1 (2000)
M.R. Hoffmann, S.T. Martin, W.-Y. Chen, D.W. Bahnemannt, Chem. Res. 95, 69 (1995)
J.-C. Yu, J. Yu, W.-K. Ho, Z.-T. Jiang, L.-Z. Zhang, Chem. Mater. 14, 3808 (2002)
A.S. Qaradawi, S.R. Salman, J. Photochem. Photobiol. A 48, 161 (2002)
H.-X. Li, J.-X. Li, Y.-N. Huo, J. Phys. Chem. B 110, 1559 (2006)
R. Asahi, T. Morikawa, T. Ohwaki, K. Aoki, Y. Taga, Science 293, 269 (2001)
J.-C. Yu, W.-K. Ho, J.-G. Yu, H.-Y. Yip, P.-K. Wong, J.-C. Zhao, Environ. Sci. Technol. 39, 1175 (2005)
S. Sakthivel, H. Kisch, Angew. Chem. Int. Ed. 42, 4908 (2003)
J.Y. Kim, I. Chung, J.H. Choy, G.S. Park, Chem. Mater. 13, 2759 (2001)
C. Zhang, Y.-F. Zhu, Chem. Mater. 17, 3537 (2005)
M. Hamada, H. Tabata, T. Kawai, Thin Solid Films 306, 6 (1997)
K. Ishikawa, T. Watanabe, H. Funakubo, Thin Solid Films 392, 128 (2001)
S.-C. Zhang, W.-Q. Yao, Y.-F. Zhu, L.-Y. Shi, Acta Phys. Chim. Sin. 23, 111 (2007)
A. Kudo, S. Hijii, Chem. Lett. 10, 1103 (1999)
J.W. Tang, Z.-G. Zou, J.-H. Ye, Catal. Lett. 92, 53 (2004)
L.-S. Zhang, W.-Z. Wang, L. Zhou, H.-L. Xu, Small 3, 1618 (2007)
H.-X. Li, Z.-F. Bian, J. Zhu, D.-Q. Zhang, G.-S. Li, Y.-N. Huo, H. Li, Y.-F. Lu, J. Am. Chem. Soc. 129, 8406 (2007)
J. Zhu, J. Yang, Z.-F. Bian, J. Ren, Y.-M. Liu, Y. Cao, H.-X. Li, H.-Y. He, K.-N. Fan, Appl. Catal. B 76, 82 (2007)
J.-G. Yu, J.-F. Xiong, B. Cheng, Y. Yu, J.-B. Wang, J. Solid State Chem. 178, 1968 (2005)
A. Kudo, I. Tsuji, H. Kato, Chem. Commun. 1958 (2002)
H.-B. Fu, C.-S. Pan, W.-Q. Yao, Y.-F. Zhu, J. Phys. Chem. B 109, 22432 (2005)
Acknowledgements
This work was supported by Government (2007CG59), Shanghai Normal University (SK200723), and State Key Laboratory Breeding Base of Photocatalysis of Fuzhou University (K-081019).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zhu, J., Wang, JG., Bian, ZF. et al. Solvothermal synthesis of highly active Bi2WO6 visible photocatalyst. Res Chem Intermed 35, 799–806 (2009). https://doi.org/10.1007/s11164-009-0099-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11164-009-0099-4