Advances in BiOX-based ternary photocatalysts for water technology and energy storage applications: Research trends, challenges, solutions, and ways forward

Mengting, Zhu; Kurniawan, Tonni  Agustiono; Duan, Liang; Song, Yonghui; Hermanowicz, Slawomir W.; Othman, Mohd Hafiz Dzarfan

doi:10.1007/s11157-022-09617-0

Advances in BiOX-based ternary photocatalysts for water technology and energy storage applications: Research trends, challenges, solutions, and ways forward

Review paper
Published: 30 April 2022

Volume 21, pages 331–370, (2022)
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Reviews in Environmental Science and Bio/Technology Aims and scope Submit manuscript

Zhu Mengting ORCID: orcid.org/0000-0002-9528-4194^1,3^na1,
Tonni Agustiono Kurniawan²^na1,
Liang Duan^3,4,
Yonghui Song^3,4,
Slawomir W. Hermanowicz^5,6 &
…
Mohd Hafiz Dzarfan Othman⁷

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Abstract

BiOX (bismuth oxyhalides) are a ternary structure (V–VI–VII) of semiconductor materials with tunable band gaps, a low recombination rate, wide light absorption range, electro-magnetical and optical properties due to their unique crystallinity with tetragonal matlockite configuration. This article critically reviews the applicability of BiOX-based photocatalysts for water treatment and/or energy storage applications. To enhance their photocatalytic activities under visible light, a particular focus is given to the formation of heterojunctions, or plasmonic nanoparticles. Their technological strengths and limitations are evaluated and compared. Synthesis techniques such as precipitation, solvothermal, hydrolysis, and doping strategy of self-assembling BiOX including heterojunctions with other semiconductors in enhancing photocatalytic performance are presented. Research direction, challenges, and perspectives of BiOX-based photocatalysts for practical applications are elaborated. It is evident from a literature survey of 227 published articles (1972–2022) that the physico-chemical properties of BiOX-based photocatalysts such as energy band structures and anisotropic layered structure are responsible for UV light-driven photocatalytic performance. The hybridized valence band of O 2p and Bi 6s² orbitals in the Bi(III)-based compounds upshifts their valence band (v_b) that narrows energy bandgap and expands the absorption of visible light range. Among the BiOX, BiOI and BiOCl are the most outstanding photocatalysts under UV Vis irradiation due to their narrow bandgaps (E^o = 2.0 and 3.4 eV, respectively), large surface area, and strong light absorption. It is important to note that technical applicability, target pollutants, and cost-effectiveness represent the key factors in selecting the most appropriate BiOX-based photocatalysts for water treatment and/or energy storage applications.

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Acknowledgements

This work was financially supported by the Major Science and Technology Program for Water Pollution Control and Treatment (Grant No. 2018ZX07601-003) and the Fundamental Research Funds for Central Public Research Institutes of China (Grant No. 2020-YSKY-045). We also gratefully acknowledge the Research Grant No. Q.J130000.21A6.00P14 from the University Teknologi Malaysia (UTM) and the Fellowship for Visiting Experts from the Word Academy of Sciences (2022).

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Zhu Mengting and Tonni Agustiono Kurniawan equally contribute to this work and mutually share the 1st authorship of the work.

Authors and Affiliations

College of Environmental Science and Engineering, Tongji University, Shanghai, 200000, China
Zhu Mengting
College of the Environment and Ecology, Xiamen University, Xiamen, 361102, Fujian, People’s Republic of China
Tonni Agustiono Kurniawan
State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing, 100012, China
Zhu Mengting, Liang Duan & Yonghui Song
State Environmental Protection Key Laboratory of Estuarine and Coastal Environment, Chinese Research Academy of Environmental Sciences, Beijing, 100012, China
Liang Duan & Yonghui Song
Tsinghua-Berkeley Shenzhen Institute, Shenzhen, 518071, China
Slawomir W. Hermanowicz
Department of Civil and Environmental Engineering, University of California, Berkeley, CA, 94720, USA
Slawomir W. Hermanowicz
Advanced Membrane Technology Research Centre (AMTEC), School of Chemical and Energy Engineering, Universiti Teknologi Malaysia, 81310, Skudai, Johor, Malaysia
Mohd Hafiz Dzarfan Othman

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Zhu Mengting
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Tonni Agustiono Kurniawan
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Liang Duan
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Yonghui Song
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Slawomir W. Hermanowicz
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Mohd Hafiz Dzarfan Othman
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Correspondence to Liang Duan.

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Mengting, Z., Kurniawan, T.A., Duan, L. et al. Advances in BiOX-based ternary photocatalysts for water technology and energy storage applications: Research trends, challenges, solutions, and ways forward. Rev Environ Sci Biotechnol 21, 331–370 (2022). https://doi.org/10.1007/s11157-022-09617-0

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Received: 15 February 2022
Accepted: 12 April 2022
Published: 30 April 2022
Issue Date: June 2022
DOI: https://doi.org/10.1007/s11157-022-09617-0

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Advances in BiOX-based ternary photocatalysts for water technology and energy storage applications: Research trends, challenges, solutions, and ways forward