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Influence of solvation on the kinetics of methyl methacrylate oxidation inhibited by aromatic amines

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Abstract

The kinetics of methyl methacrylate oxidation inhibited by aromatic amines in media of different polarities was studied. The complexing parameters in systems “oxidation substrate—aromatic amine—solvent” using IR and NMR spectroscopy were found. The correlations between inhibited oxidation rate constant and the polarity of the medium were obtained using Kirkwood–Onsager equation.

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Acknowledgments

The research was performed with the financial support of RSF Grant No. 14-23-00018. NMR studies were performed at the Centre for Magnetic Resonance, St. Petersburg State University Research Park.

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Authors and Affiliations

  1. P.G. Demidov Yaroslavl State University, 14 Sovetskaya Street, Yaroslavl, 150000, Russia

    S. Lednev, A. Sirick, E. Pliss, A. Rusakov & N. Shvyrkova

  2. St. Petersburg State University, Research Park, 26 Universitetskiy pr., Peterhof, 198504, Russia

    A. Ivanov

Authors
  1. S. Lednev
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  2. A. Sirick
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  3. E. Pliss
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  4. A. Rusakov
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  5. N. Shvyrkova
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  6. A. Ivanov
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Correspondence to S. Lednev.

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Lednev, S., Sirick, A., Pliss, E. et al. Influence of solvation on the kinetics of methyl methacrylate oxidation inhibited by aromatic amines. Reac Kinet Mech Cat 116, 43–50 (2015). https://doi.org/10.1007/s11144-015-0881-9

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  • DOI: https://doi.org/10.1007/s11144-015-0881-9

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