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Comparison of the performances of Pt/HBEA nano dispersed over alumina and Pt/ZSM-22 catalysts in n-hexadecane hydroisomerization

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Abstract

n-Hexadecane hydroisomerization at 220 °C and 30 bar was used as a model reaction for comparing the catalytic performances of a Pt/HBEA sample whose zeolite crystals were germinated on an α alumina surface with those of 1Pt/HZM-22 catalyst well-known for its high isodewaxing selectivity. Similar values of selectivity to isomers were obtained with both catalysts even at high conversions. Moreover, despite its low zeolite content (13 wt%), the Pt/HBEA Al2O3 catalyst had the important advantage to be 4.6 times more active.

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Acknowledgments

Nuno Batalha thanks Fundação para a Ciência e a Tecnologia (FCT) for the financial support (Ref. SFRH/BD/43551/2008).

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Authors and Affiliations

  1. IC2MP, UMR 7285 CNRS–Université de Poitiers, 4 Rue Michel Brunet, 86022, Poitiers Cedex, France

    N. Batalha, L. Pinard, S. Morisset, J. L. Lemberton, Y. Pouilloux & M. Guisnet

  2. IBB, Institute for Biotechnology and Bioengineering, Centre for Biological and Chemical Engineering, Instituto Superior Técnico, Universidade Técnica de Lisboa, Av. Rovisco Pais, 1049-001, Lisbon, Portugal

    N. Batalha, M. Guisnet, F. Lemos & F. R. Ribeiro

Authors
  1. N. Batalha
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  2. L. Pinard
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  3. S. Morisset
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  4. J. L. Lemberton
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  5. Y. Pouilloux
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  6. M. Guisnet
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  7. F. Lemos
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  8. F. R. Ribeiro
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Correspondence to L. Pinard.

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Batalha, N., Pinard, L., Morisset, S. et al. Comparison of the performances of Pt/HBEA nano dispersed over alumina and Pt/ZSM-22 catalysts in n-hexadecane hydroisomerization. Reac Kinet Mech Cat 107, 285–294 (2012). https://doi.org/10.1007/s11144-012-0488-3

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  • DOI: https://doi.org/10.1007/s11144-012-0488-3

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