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Mesoporous MCM-41 supported N-heterocyclic carbene–Pd(II) complex for Suzuki coupling reaction

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Abstract

A nanostructured mesoporous MCM-41 supported N-heterocyclic carbene–Pd (NHC–Pd) complex was prepared through the reaction of an ionic liquid immobilized onto MCM-41 with palladium acetate. The MCM-41-supported NHC–Pd complex could serve as a highly effective catalyst for the Suzuki cross-coupling reaction under aqueous conditions. Furthermore, the Pd(II) catalyst was recovered by a simple filtration from the reaction mixture and reused without a significant loss of its catalytic activity. The heterogeneous catalyst was also air-stable and thermally stable to allow its easy use.

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Acknowledgment

We would like to thank Professor Myung-Jong Jin, Inha University, South Korea for giving us valuable guidelines about this work.

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Authors and Affiliations

  1. Department of Chemistry, School of Physical Sciences, Shahjalal University of Science and Technology, Sylhet, 3114, Bangladesh

    Md. Nazmul Alam

  2. School of Chemical Science and Engineering, Inha University, Incheon, 402-751, Korea

    Shaheen M. Sarkar

Authors
  1. Md. Nazmul Alam
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  2. Shaheen M. Sarkar
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Correspondence to Md. Nazmul Alam.

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Alam, M.N., Sarkar, S.M. Mesoporous MCM-41 supported N-heterocyclic carbene–Pd(II) complex for Suzuki coupling reaction. Reac Kinet Mech Cat 103, 493–500 (2011). https://doi.org/10.1007/s11144-011-0314-3

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  • DOI: https://doi.org/10.1007/s11144-011-0314-3

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