Abstract
NiO-MoO3/γ-Al2O3 catalysts were prepared by the reaction of γ-Al2O3 extrudates with an aqueous slurry of MoO3, followed by the reaction of the MoO3/γ-Al2O3 catalyst with an aqueous slurry of NiO, Ni(OH)2, NiCO3·2Ni(OH)2·xH2O, or 2NiCO3·3Ni(OH)2·4H2O and by subsequent drying. The NiO deposition was examined with electron probe microanalysis. The deposited Ni efficiently increased the activity in benzothiophene hydrodesulfurization.
Similar content being viewed by others
References
Topsøe H, Clausen BS, Massoth FE (1996) In: Anderson JR, Boudart M (eds) Hydrotreating Catalysts, Science and Technology, vol 11. Springer, Berlin
Escobar J, Barrera MC, Toledo JA, Cortés-Jácome MA, Angeles-Chávez C, Núñez S, Santes V, Gómez E, Díaz L, Romero E, Pacheco JG Appl Catal A (in press) doi:10.1016/j.apcatb.2008.10.005
Guevara A, Alvarez A, Vrinat M (2008) Catal Lett 126:268
Carrier X, Marceau E, Che M (2006) Pure Appl Chem 78:1039
Andonova S, Vladov C, Pawelec B, Shtereva I, Tyuliev G, Damyanova S, Petrov L (2007) Appl Catal A 328:201
Srinivasan R, Liu HC, Wehler SW (1979) J Catal 57:87
Goula MA, Kordulis C, Lycourghiotis A (1992) J Catal 133:486
Goula MA, Kordulis C, Lycourghiotis A, Fierro JLG (1992) J Catal 137:285
Hanika J, Janoušek V, Sporka K (1987) Collect Czechoslovak Chem Commun 52:663
Okamoto Y, Umeno S, Arima Y, Nakai K, Takahashi T, Uchikawa K, Inamura K, Akai Y, Chiyoda O, Katada N, Shishido T, Hattori H, Hasegawa S, Yoshida H, Segawa K, Koizumi N, Yamada M, Nishijima A, Kabe T, Ishihara A, Isoda T, Mochida I, Matsumoto H, Niwa M, Uchijima T (1998) Appl Catal A 170:343
Bergwerff JA, Visser T, Leliveld BRG, Rossenaar BD, de Jong KP, Weckhuysen BM (2004) J Am Chem Soc 126:14548
van de Water LGA, Bergwerff JA, Leliveld BRG, Weckhuysen BM, de Jong KP (2005) J Phys Chem B 109:14513
Bergwerff JA, Jansen M, Leliveld BRG, Visser T, de Jong KP, Weckhuysen BM (2006) J Catal 243:292
Bergwerff JA, Visser T, Weckhuysen BM (2008) Catal Today 130:117
Bergwerff JA, van de Water LGA, Visser T, de Peinder P, Leliveld BRG, de Jong KP, Weckhuysen BM (2005) Chem Eur J 11:4591
Beale AM, Jacques SDM, Bergwerff JA, Barnes P, Weckhuysen BM (2007) Angew Chem Int Ed 46:8832
van de Water LGA, Bergwerff JA, Nijhuis TA, de Jong KP, Weckhuysen BM (2005) J Am Chem Soc 127:5024
Lysova AA, Koptyug IV, Sagdeev RZ, Parmon VN, Bergwerff JA, Weckhuysen BM (2005) J Am Chem Soc 127:11916
Kaluža L, Zdražil M (2002) Catal Lett 78:313
Kaluža L, Zdražil M (2007) Top Catal 45:191
Moya SA, Escudey M (1994) J Chem Soc Chem Commun 16:1829
Peter R, Matějec V, Zdražil M (1986) Collect Czechoslovak Chem Commun 51:1195
Bezverzkyy I, Afanasiev P, Lacroix M (2005) J Catal 230:133
Kaluža L, Gulková D, Šolcová O, Žilková N, Čejka J (2008) Appl Catal A 351:93
Farag H, Whitehurst DD, Mochida I (1998) Ind Eng Chem Res 37:3533
Gulková D, Zdražil M (2007) React Kinet Catal Lett 91:379
Afanasiev P (2008) Catal Commun 9:734
Bataille F, Lemberton JL, Michaud P, Pérot G, Vrinat M, Lemaire M, Schulz E, Breysse M, Kasztelan S (2000) J Catal 191:409
Egorova M, Prins R (2004) J Catal 225:417
Acknowledgment
Financial support of the Czech Science Foundation (grant No. 104/09/0751) is gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kaluža, L., Zdražil, M. & Vít, Z. Deposition of NiO onto MoO3/γ-Al2O3 extrudates by slurry impregnation method. React Kinet Catal Lett 97, 307–313 (2009). https://doi.org/10.1007/s11144-009-0031-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11144-009-0031-3