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Immobilization of Ru — TsDPEN catalyst on functionalized MCM — 41

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Abstract

A Ru — TsDPEN (RuCl[(1S,2S)-N-p-tosyl-1,2-diphenylethylendiamine]p-cymene) catalyst of the Noyori type was immobilized in the channels of MCM — 41 molecular sieve functionalized by (3 — aminopropyl)triethoxysilane (APTES). The resulting compound was tested as a catalyst for the hydrogenation of 1-methyl-3,4-dihydroisoquinoline (MIQ) under laboratory conditions using an azeotropic mixture of formic acid and triethylamine (5:2) as the source of hydrogen and compared to the results acquired in the corresponding system.

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Authors and Affiliations

  1. Institute of Chemical Technology, Technická 5, 166 28, Praha 6, Czech Republic

    Helena Šiklová, Eliška Leitmannová, Petr Kačer & Libor Červený

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  1. Helena Šiklová
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  2. Eliška Leitmannová
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  3. Petr Kačer
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  4. Libor Červený
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Correspondence to Libor Červený.

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Šiklová, H., Leitmannová, E., Kačer, P. et al. Immobilization of Ru — TsDPEN catalyst on functionalized MCM — 41. React Kinet Catal Lett 92, 129–136 (2007). https://doi.org/10.1007/s11144-007-5140-2

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  • DOI: https://doi.org/10.1007/s11144-007-5140-2

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