Processing of rice husk into SiC is the most efficient recycling method since it allows both of its constituents to be used: carbon and amorphous silica. Silicon carbide powder is synthesized from hydrothermally carbonized rice husk by nonisothermal heating at a rate of 3–10 °C/min to 1600°C in argon gas.
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References
D. F. Houston, Rice: Chemistry and Technology, Am. Soc. Cereal. Chemists, St. Paul, Minnesota (1972), Chap. 12, p. 301.
S. Yoshida, Y. Ohnishi, and K. Kitaichi, “The chemical forms, mobility, and deposition of silicon in rice plant,” Soil Sci. Plant Nutrition, 8, No. 3, 107–113 (1962).
M. A. Hamad, “Combustion of rice hulls in a static bed,” in: Energy in Agriculture, Vol. 1, 311–315 (1981–1982).
S. B. Hanna, L. M. Farag, and N. A. L. Mansour, “Pyrolysis and combustion of treated and untreated rice hulls,” Thermochem. Acta, 81, 77–86 (1984).
M. Patel, A. Karera, and P. Prasanna, “Effect of thermal and chemical treatment on carbon and silica contents in rice husk,” J. Mater. Sci., 22, 2457–2464 (1987).
Y. Nakata, M. Suzuki, T. Okutani, et al., “Preparation and properties of SiO2 from rice hulls,” J. Ceram. Soc. Jpn., 97, 842–852 (1989).
C. Real, M. Alcala, and J. M. Criado, “Preparation of silica from rice husks,” J. Am. Ceram. Soc., 79, No. 8, 2012–2016 (1996).
T. H. Liou, “Preparation and characterization of nanostructured silica from rice husk,” J. Mat. Sci. Eng. A, 364, 313–323 (2004).
J. I. Martin, The Desilification of Rice Husk and a Study of the Products Obtained: Master Thesis, Lousiana State University, Lousiana, USA (1938), p. 57.
V. P. Della, I. Kühn, and D. Hotza, “Rice husk ash as an alternate source for active silica production,” Mater. Lett., 57, 818–821 (2002).
Y. Shinohara and N. Kohyama, “Quantitative analysis of tridymite and cristobalite crystallized in rice husk ash by heating,” Ind. Health, 42, 277–285 (2004).
E. Natarajan, A. Nordin, and A. N. Rao, “Overview of combustion and gasification of rice husk in fluidized bed reactors,” J. Biomass Bioenergy, 14, Nos. 5–6, 533–546 (1998).
L. Armesto, A. Bahillo, K. Veijonen, et al., “Combustion behavior of rice husk in a bubbling fluidized bed,” J. Biomass Bioenergy, 23, 171–179 (2002).
P. C. Kapur, “Production of reactive bio-silica from the combustion of rice husk in a tube-in-basket (TiB) burner,” J. Powder Technol., 44, 63–67 (1985).
B. M. Jenkins, O. Kitani, and C. W. Hall, “Physical properties of biomass,” in: Biomass Handbook, Gordon & Breach, New York (1989), pp. 860–891.
B. Mahin, Rice Husk Energy Systems, Bioenergy Systems Report, Office of Energy, Agency for International Development, USA (1986), p. 28.
R. Jauberthie, F. Rendell, S. Tamba, et al., “Origin of the pozzolanic effect of rice husks,” J. Construct. Building Mater., 14, 419–423 (2000).
R. H. McDonald, Silica in Nova Scotia, Information Circular ME 14, 2nd ed., Nova Scotia Department of Natural Resources (1991).
D. K. Stephens, C. W. Wellen, J. B. Smith, et al., Precipitated Silicas, Silica Gels with and Free of Deposited Carbon from Caustic Biomass Ash Solutions and Processes, United States Patent 6638354, publ. October 28 (2003).
R. S. Rieber, W. A. Mallow, and J. R. Conner, Production of Soluble Silicates from Biogenic Silica, United States Patent 6524543, publ. February 25 (2003).
Y. Hsieh, Y. Du, F. Jin, et al., “Alkaline pretreatment of rice hulls for hydrothermal production of acetic acid,” J. Chem. Eng. Res. Des., 87, 13–18 (2009).
I. B. Cutler, A Production of Silicon Carbide from Rice Hulls, United States Patent 3754076, publ. August 21 (1973).
L. R. Vishnyakov and S. F. Korablev, “Carbon and carbon composites produced by hydrothermal synthesis (Overview),” Kompoz. Nanostrukt., No. 1, 2–12 (2011).
N. S. Kas’ko and V. P. Kandaurov, “Studying intermolecular interaction of cellulose nitrates with nucleophile reagents,” Khim. Rast. Syr’ya., No. 1, 34–38 (1997).
T. P. Shcherbakova, N. E. Kotel’nikova, and Yu. V. Bykhovtsova, “Comparative study of powder and microcrystalline cellulose of various natural origins. Supermolecular structure and chemical composition of powder samples,” Khim. Rast. Syr’ya., No. 2, 5–14 (2012).
K. Sujrote and P. Leangsuwan, “Silicon carbide formation from pretreated rice husks,” J. Mater. Sci., 38, 4739–4744 (2003).
S. N. Shamin, V. R. Galakhov, V. I. Aksenova, et al., “X-ray and infrared spectroscopy of layers deposited by co-sputtering of spaced SiO2 and Si sources,” Fiz. Tekh. Polyprov., 44, Issue 4, 550–555 (2010).
D. M. Wolfe, B. J. Hinds, F. Wang, et al., “Thermochemical stability of silicon–oxygen–carbon alloy thin films: a model system for chemical and structural relaxation at SiC–SiO2 interfaces,” J. Vac. Sci. Technol. A, 17, No. 4, 2170–2177 (1999).
V. N. Bykov, V. G. Korinevskii, V. E. Eremyashev, et al., “Water in ‘chancharite’ glasses: infrared spectroscopy,” Ural. Mineralog. Sbor., Issue 6, 134–142 (1996).
H. Preiss, L. M. Berger, and M. Braun, “Formation of black glasses and silicon carbide from binary carbonaceous/silica hydrogels,” Carbon, 33, No. 12, 1739–1746 (1995).
J. L. Nieto, “Infrared determination of quartz, kaolin, corundum, silicon carbide, and orthoclase in respirable dust from grinding wheels,” Analyst, 103, 128–133 (1978).
R. G. Zhbankov, A. A. Konkin, and S. G. Bychkova, “Infrared spectroscopy for studying the structure and chemical transformations of natural cellulose during heat treatment,” Khim. Volokna, No. 4, 51–53 (1976).
V. E. Eremyashev, Water Behavior in Model and Natural Aluminosilicate Glasses According to Oscillation Spectroscopy [in Russian], Author’s Abstract of ScD Thesis, Chelyabinsk (2008), p. 47.
D. K. Basa and F. W. Smith, “Annealing and crystallization processes in a hydrogenated amorphous SiC alloy film,” Thin Sol. Films, 192, Issue 1, 121–133 (1990).
I. Pastorova, R. E. Botto, P. W. Arisz, et al., “Cellulose char structure: a combined analytical Py-GC-MS, FTIR, and NMR study,” Carbohydr. Res., 262, No. 1, 27–47 (1994).
D. Fengel, “Structural changes of cellulose and their effects on the OH/CH2 valency vibration range in FTIR spectra,” in: Cellulose and Cellulose Derivatives: Physico-chemical Aspects and Industrial Applications “Cellucon ’93,” Lund (1993), 75–84.
A. L. Smith and D. R. Anderson, “Vibrational spectra of Me2SiCl2, Me3SiCl, Me3SiOSiMe3, (Me2SiO)3, (Me2SiO)4, (Me2SiO)x and their deuterated analogs,” Appl. Spectrosc., 38, 822–834 (1984).
M. Falk and S. Karunanithy, “Determination of SiO2 in SiC whiskers by infrared absorption spectroscopy,” Mater. Sci. Eng. A, 114, 209–221 (1989).
G. Lucovsky, J. Yang, S. S. Chao, et al., “Oxygen-bonding environments in glow-discharge-deposited amorphous silicon–hydrogen alloy films,” Phys. Rev. B (Condens. Matter), 28, Issue 6, 3225–3233 (1983).
S. N. Lakiza and Yu. P. Dyban, “Preparation of silicon carbide from rice husk,” Powder Metall. Met. Ceram., 21, No. 2, 117–121 (1982).
N. K. Sharma, W. S. Williams, and A. Zangvil, “Formation and structure of silicon carbide whiskers from rice hulls,” J. Am. Ceram. Soc., 67, No. 11, 715–720 (1984).
R. V. Krishnarao, M. M. Godkhindi, M. Chakraborty, et al., “Formation of SiC whiskers from compacts of raw rice husks,” J. Mater. Sci., 29, 2741–2744 (1994).
B. B. Nayak, B. C. Mohanty, and S. K. Singh, “Synthesis of silicon carbide from rice husk in a dc arc plasma reactor,” J. Am. Ceram. Soc., 79, No. 5, 1197–1200 (1996).
K. M. Knowles and M. V. Ravichandrdan, “Structural analysis of inclusions in β-silicon carbide whiskers grown from rice hulls,” J. Am. Ceram. Soc., 80, No. 5, 1165–1173 (1997).
E. P. Gorzkowski, S. B. Qadri, B. B. Rath, et al., “Formation of nanodimensional 3C–SiC structures from rice husks,” J. Electron. Mater., 42, No. 5, 799–804 (2013).
M. Sarangi, B. Mallick, S. C. Mishra, et al., “High-vacuum synthesis of SiC from rice husk: a novel method,” J. Phys. D: Appl. Phys., 46, No. 34, 345306 (2013).
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Translated from Poroshkovaya Metallurgiya, Vol. 54, Nos. 1–2 (501), pp. 130–140, 2015.
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Korablev, S.F., Korablev, D.S. Physicochemical Features in the Nonisothermal Synthesis of Nanostructured SiC from Hydrothermally Carbonized Rice Husk. I. Nonisothermal Synthesis. Powder Metall Met Ceram 54, 106–114 (2015). https://doi.org/10.1007/s11106-015-9686-7
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DOI: https://doi.org/10.1007/s11106-015-9686-7