Skip to main content

Advertisement

Log in

Synthesis and Properties of Si-Modified Biogenic Hydroxyapatite Ceramics

  • Published:
Powder Metallurgy and Metal Ceramics Aims and scope

The paper examines the production of Si-modified biogenic hydroxyapatite ceramics. The introduction of methylsilicic acid hydrogel in amounts converted to 2 and 5 wt.% Si and subsequent sintering at 600°C increase the specific surface area by 10 times, from 6.1 to 59.8 m2/g. The porosity of ceramics increases from 43.0 to 62.3% when the modifying addition reaches up to 5 wt.%, the compressive strength being equal to 27–33 MPa. The modifying addition also influences the structure and reduces the minimum grain size of the material from 0.65 to 0.1μm

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Atta-ur-Rahman (ed.), Studies in Natural Products Chemistry, Elsevier (2008), p. 954.

  2. C. Exley, “Silicon in life: a bioinorganic solution to bioorganic essentiality,” J. Inorg. Biochem., 69, No. 3, 139–144 (1998).

    Article  Google Scholar 

  3. E. Emanuel, “Silicon,” Annu. Rev. Plant Physiol. Plant Mol. Biol., 50, 641–664 (1999).

    Article  Google Scholar 

  4. J. Loeper and M. Fragny, The Physiological Role of the Silicon and its Antiatheromatous Action, Plenum Press, New York–London (1978), p. 589

    Google Scholar 

  5. Q. H. M. Shawket Zaman, A. Takeuchi, C. Tanira Zaman, et al., “Fabrication of Si-substituted hydroxyapatite foam using calcium silicates,” J. Ceram. Soc. Japan, 116, No. 1349, 88–91 (2008).

    Article  Google Scholar 

  6. X. W. Li, H. Y. Yasuda, and Y. Umakoshi, “Bioactive ceramic composites sintered from hydroxyapatite and silica at 1200°C: preparation, microstructures, and in vitro bone-like layer growth,” J. Mater. Sci.: Mater. Med., 17, 573–581 (2006)

    Google Scholar 

  7. C. Q. Ning, J. Mehta, and A. El-Ghannam, “Effects of silica on the bioactivity of calcium phosphate composites in vitro,” J. Mater. Sci.: Mater. Med., 16, 355–360 (2005)

    Google Scholar 

  8. G. Mestres, C. Le Van, and M.-P. Ginebra, “Silicon-stabilized α-tricalcium phosphate and its use in a calcium phosphate cement: characterization and cell response,” Acta Biomater., 8, No. 3, 1169–1179 (2012).

    Article  Google Scholar 

  9. L. A. Ivanchenko, T. I. Fal’kovska, N. V. Danilenko, et al., “Structure and properties of a high-porosity glass ceramic containing biological hydroxyapatite,” Powder Metall. Met. Ceram., 38, No. 9–10, 448–453 (1999).

    Article  Google Scholar 

  10. O. Sych, N. Pinchuk, A. Parkhomey, et al., “Morphology structure and properties of new porous biocomposites based on biogenic hydroxyapatite and synthetic calcium phosphates,” Funct. Mater., 14, No. 4, 430–435 (2007).

    Google Scholar 

  11. E. E. Sych, N. D. Pinchuk, and L. A. Ivanchenko, “Effect of sintering temperature on the properties of biogenic hydroxyapatite–glass composites,” Powder Metall. Met. Ceram., 49, No. 3–4, 153–158 (2010).

    Article  Google Scholar 

  12. E. P. Podrushnyak, L. A. Ivanchenko, T. I. Fal’kovska, et al., “New biocomposites based on bone hydroxyapatite and their potential applications in biology and medicine,” Probl. Osteol., 1, No. 2–3, 98–100 (1998).

    Google Scholar 

  13. V. I. Luzin, S. V. Petrosyants, Yu. S. Plyaskova, et al., “Chemical composition of various sections of long cortical bones after implantation of biogenic hydroxyapatite,” Travma, 10, No. 3, 346–350 (2009)

    Google Scholar 

  14. D. V. Ivchenko, “Tactics of treating pathological fractures of extremities of patients with tumor diseases and benign tumors,” Ortoped., Travmatol., Protezir., No. 4, 12–15 (2006).

  15. V. I. Luzin and A. A. Lubenets, “Growth, structurization, and shaping of skeletal bone in implantation of biogenic hydroxyapatite doped with manganese in different concentrations into the tibia,” Ukrain. Morfol. Al’manakh, 9, No. 3, 116–117 (2011).

    Google Scholar 

  16. E. P. Podrushnyak, L. A. Ivanchenko, V. L. Ivanchenko, and N. D. Pinchuk, Hydroxyapatite and Methods for Its Production (Options) [in Ukrainian], Ukrainian Patent 61938, IPC A61K35/32, A61K33/00, A61K6/02, A61P19/00; E. P. Podrushnyak, L. A. Ivanchenko, V. L. Ivanchenko (applicants and patent holders), No. 99095233; appl. September 21, 1999; publ. December 15 (2003), Bulletin No. 12, p. 7.

  17. http://siams.com/products/photolab/siams_photolab.htm.

  18. S. A. Goldstein, “The mechanical properties of trabecular bone: dependence on anatomic location and function,” J. Biomech., 20, No. 11–12, 1055–1061 (1987).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to E. E. Sych.

Additional information

Translated from Poroshkovaya Metallurgiya, Vol. 54, Nos. 1–2 (501), pp. 83–90, 2015.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sych, E.E., Pinchuk, N.D., Klimenko, V.P. et al. Synthesis and Properties of Si-Modified Biogenic Hydroxyapatite Ceramics. Powder Metall Met Ceram 54, 67–73 (2015). https://doi.org/10.1007/s11106-015-9681-z

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11106-015-9681-z

Keywords

Navigation