Titanium nitride and silicon nitride nanopowders are subjected to microwave treatment to stimulate reduction and nitration reactions. It is established that oxygen content of the nanopowders after microwave treatment is 30–60% lower than that of the starting powders. It is also studied how the efficiency of thermochemical treatment and the particle-size distribution depend on the amount of the phase that absorbs microwave energy.
Similar content being viewed by others
References
Joel D. Houmes and Hans-Conrad zur Loye, “Microwave synthesis of ternary nitride materials,” J. Solid State Chem., No. 130, 266–271 (1997).
H. M. Kingston and L. B. Jassie, Introduction to Microwave Sample Preparation: Theory and Practice, American Chemical Society, Washington DC (1988).
S. S. Berdonosov, D. G. Berdonosova, and I. V. Znamenskaya, “Microwaves in chemical practices,” Chim. Tekhnol., No. 3, 2–8 (2000).
S. S. Berdonosov, M. A. Prokof’ev, V. Ya. Lebedev, et al., “Microwave annealing of defects in inorganic crystalline hydrates,” Neorg. Mater., 33, No. 10, 1257–1262 (1997).
D. E. Clark, D. C. Folz, C. Folgar, et al., Microwave Solutions for Ceramic Engineers, American Ceramic Society, Westerville, Ohio (2005), p. 350.
D. E. Clark, “Microwave processing of materials,” Annu. Rev. Mater. Sci., 26, 299–331 (1994).
D. E. Clark, W. R. Tinga, J. R. Laia, et al., Microwaves: Theory and Applications in Materials Processing II, American Ceramic Society, Westerville, OH (1993).
S. Gedevanishvili, K. Cherian, D. Agrawal, and R. Roy, “Synthesis of silicon nitride whiskers by microwave heating,” Mat. Res. Soc. Symp. Proc., 547, 413–415 (1999).
R. A. Andrievskii, “Silicon nitride—synthesis and properties,” Usp. Khim., 64, No. 4, 311–329 (1995).
Yu. Yu. Bachernikov, R. V. Konakova, A. N. Kocherov, et al., “Effect of microwave annealing on silicon dioxide–silicon carbide structures,” Zh. Tekh. Fiz., 73, No. 5, 75–78 (2003).
O. B. Zgalat-Lozinskii, A. V. Ragulya, V. V. Skorokhod, et al. “Sintering of refractory compound nanocrystalline powders. I. Storage and preliminary heat treatment of titanium nitride nanocrystalline powders,” Powder Metall. Met. Ceram., 40, No. 9–10, 471–477 (2001).
ASTM Diffraction Data Card Files, JCPDS, Philadelphia (1977).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Poroshkovaya Metallurgiya, Vol. 52, No. 3–4 (490), pp. 27–35, 2013.
Rights and permissions
About this article
Cite this article
Zgalat-Lozinskii, O.B., Kolesnichenko, V.G., Zamula, M.V. et al. Thermochemical microwave treatment of refractory nanopowders. Powder Metall Met Ceram 52, 137–143 (2013). https://doi.org/10.1007/s11106-013-9506-x
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11106-013-9506-x