Skip to main content
Log in

Al2O3–HfO2–Y2O3 phase diagram. I. Isothermal sections at 1250 and 1650°C

  • PHYSICOCHEMICAL MATERIALS RESEARCH
  • Published:
Powder Metallurgy and Metal Ceramics Aims and scope

Isothermal sections at 1250 and 1650°C in the Al2O3–HfO2–Y2O3 phase diagram are plotted for the first time. Phase equilibria are established at these temperatures. No ternary compounds and appreciable solid solution regions based on binary compounds are found in the ternary system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. L. M. Lopato, A. V. Shevchenko, A. A. Frolov, and V. P. Red’ko, “Fusion and dispersion of oxide materials in a “cold” crucible and in furnaces with concentrated radiant heating,” Powder Metall. Met. Ceram., 44, No. 7–8, 335–340 (2005).

    Article  CAS  Google Scholar 

  2. Y. Waku, S. Sakata, A. Mitani, and K. Shimizu, “A novel oxide composite reinforced with a ductile phase for very high temperature structural materials,” Mat. Res. Innovat., 2, No. 2, 94–100 (2001).

    Google Scholar 

  3. Y. Waku, S. Sakata, A. Mitani, et al., “Temperature dependence of flexural strength and microstructure of Al2O3/Y3Al5O12/ZrO2 ternary melt growth composites,” J. Mater. Sci., 37, No. 14, 2975–2982 (2002).

    Article  CAS  Google Scholar 

  4. Y. Murayama, S. Hanada, J. H. Lee, et al., “High-temperature strength of directionally solidified Al2O3/YAG/ZrO2 eutectic composite,” Mater. Sci. Forum, 475–479, 1295–1300 (2005).

    Article  Google Scholar 

  5. V. P. Red’ko, Physical and Chemical Research of M 4 Zr(Hf) 3 O 12 Compounds in ZrO 2 (HfO 2 )–REM Oxides [in Russian], Author’s Abstract of PhD Thesis, Kiev (1990), p. 20.

  6. L. M. Lopato, A. V. Shevchenko, and G. I. Gerasimyuk, “System HfO2–Al2O3,” Izv. AN SSSR, Neorg. Mater., 12, No. 9, 1623–1626 (1976).

    CAS  Google Scholar 

  7. N. A. Toropov, I. A. Bondar’, F. Ya. Galakhov, et al., “Phase equilibria in the yttria–alumina system,” Izv. AN SSSR, Ser. Khim., No. 7, 1158–1164 (1964).

  8. D. Viehnicki and F. Schmidt, “Eutectic solidification in the system Al2O3/Y3Al5O12,” J. Mater. Sci., 4, No. 1, 84–88 (1969).

    Article  ADS  Google Scholar 

  9. J. L. Caslavsky and D. J. Viechnicki, “Melting behavior and metastability of yttrium aluminum garnet (YAG) and YAlO3 determined by optical differential thermal analysis,” J. Mater. Sci., 15, No. 474, 1709–1718 (1980).

    Article  ADS  CAS  Google Scholar 

  10. I. A. Bodnar’, L. N. Koroleva, and E. T. Bezruk, “Physical and chemical properties of yttrium aluminates and gallates,” Izv. AN SSSR, Neorg. Mater., 20, No. 2, 257–261 (1984).

    Google Scholar 

  11. B. Cocayne, “The uses and enigmas of the Al2O3–Y2O3 phase system,” J. Less-Common Met., 114, No. 1, 199–206 (1985).

    Article  Google Scholar 

  12. T. Mah and D. Petry, “Eutectic composition in the pseudobinary Y4Al2O9 and Y2O3,” J. Am. Ceram. Soc., 75, No. 7, 2006–2009 (1992).

    Article  CAS  Google Scholar 

  13. S. N. Lakiza, L. M. Lopato, L. V. Nazarenko, and Z. A. Zaitseva, “The liquidus surface in the Al2O3–ZrO2–Y2O3 phase diagram,” Powder Metall. Met. Ceram., 33, No. 11–12, 595–598 (1994).

    Google Scholar 

  14. R. S. Hay, “Kinetics and deformation during the reaction of yttrium-aluminum perovskite and alumina to yttrium-aluminum garnet,” J. Am. Ceram. Soc., 77, No. 6, 1473–1485 (1994).

    Article  Google Scholar 

  15. M. Gervais and A. Douy, “Solid phase transformation and melting of the compounds Ln4Al2O9 (Ln = Gd, Dy, Y),” Mater. Sci. Eng., B38, No. 1–2, 118–121 (1996).

    Article  CAS  Google Scholar 

  16. M. Shimada and H. Yamane, “Martensitic transformation of Y4Al2O9,” Ceram. Eng. Sci. Proc., 21, No. 4, 455–460 (2000).

    Article  CAS  Google Scholar 

  17. O. Fabrichnaya, H. J. Seifert, T. Ludwig, et al., “The assessment of thermodynamic parameters in the Al2O3–Y2O3 system and phase relations in the Y–Al–O system,” Scand. J. Met., 30, No. 3, 175–183 (2001).

    Article  CAS  Google Scholar 

  18. Y. Mizutani, H. Yasuda, N. Maeda, and Y. Waku, “Coupled growth of the Al2O3–YAG eutectic system in the undercooled melt,” J. Jap Inst. Met., 66, No. 1, 9–15 (2002).

    CAS  Google Scholar 

  19. F. N. Spiridonov, L. N. Komissarova, L. G. Kogarov, and V. N. Spitsin, “System HfO2–Y2O3,” Zh. Neorg. Khim., 14, No. 9, 2535–2540 (1969).

    CAS  Google Scholar 

  20. D. W. Stacy and D. R. Wilder, “The yttria–hafnia system,” J. Am. Ceram. Soc., 58, No. 7–8, 285–288 (1975).

    Article  CAS  Google Scholar 

  21. A. V. Shevchenko, L. M. Lopato, and I. E. Kir’yakova, “Interaction of HfO2 with Y2O3, Ho2O3, Er2O3, Tm2O3, Yb2O3, and Lu2O3 at high temperatures,” Izv. AN SSSR, Neorg. Mater., 20, No. 12, 1991–1994 (1984).

    CAS  Google Scholar 

  22. S. G. Popov, M. V. Paromova, Z. Ya. Kulikova, et al., “Phase equilibria in the pseudoternary system HfO2–Y2O3–Al2O3,” Izv. AN SSSR, Neorg. Mater., 26, No. 5, 1002–1006 (1990).

    CAS  Google Scholar 

  23. O. Fabrichnaya and C. Mercer, “Phase relations in the HfO2–Y2O3–Al2O3 system,” Comp. Coupl. Phase Diagr. Thermochem., 29, 239–246 (2005).

    CAS  Google Scholar 

  24. O. Fabrichnaya and F. Aldinger, “Assessment of thermodynamic parameters in the system Al2O3–Y2O3–ZrO2, Z. Metallkunde, 95, No. 1, 27–39 (2004).

    CAS  Google Scholar 

  25. S. M. Lakiza and L. M. Lopato, “Stable and metastable phase relations in the system alumina–zirconia–yttria,” J. Am. Ceram. Soc., 80, No. 4, 893–902 (1997).

    Article  CAS  Google Scholar 

  26. S. N. Lakiza, L. M. Lopato, and A. V. Shevchenko, “Interactions in the Al2O3–ZrO2–Y2O3 system,” Powder Metall. Met. Ceram., 33, No. 9–10, 486–490 (1994).

    Google Scholar 

  27. L. M. Lopato, L. V. Nazarenko, G. I. Gerasimyuk, and A. V. Shevchenko, “Interaction in the ZrO2–Y2O3–Al2O3 system at 1650°C,” Neorg. Mater., 26, No. 4, 834–838 (1990).

    CAS  Google Scholar 

  28. L. M. Lopato, L. V. Nazarenko, G. I. Gerasimyuk, and A. V. Shevchenko, “Isothermal section of the ZrO2–Y2O3–Al2O3 phase diagram at 1250°C,” Neorg. Mater., 28, No. 4, 835–839 (1992).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. M. Lakiza.

Additional information

Translated from Poroshkovaya Metallurgiya, Vol. 48, No. 3–4 (466), pp. 131–140, 2009.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lakiza, S.M., Tishchenko, Y.S., Red’ko, V.P. et al. Al2O3–HfO2–Y2O3 phase diagram. I. Isothermal sections at 1250 and 1650°C. Powder Metall Met Ceram 48, 225–233 (2009). https://doi.org/10.1007/s11106-009-9106-y

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11106-009-9106-y

Keywords

Navigation