Abstract
Within this study, the application area of the cellular automata model for the prediction of internal corrosion during high-temperature applications has been extended to intergranular oxidation. Besides a significant mass transport by diffusion, chemical reactions and phase transformations have to be accounted for in a modeling framework for internal corrosion. In addition, grain boundaries play an important role as they are acting as fast diffusing paths where the transport of matter is by orders of magnitudes higher than inside the grain. Here, a numerical model is presented to describe intergranular oxidation attack. The model is applied to the nickel-based superalloy 80a and the low-Cr steel X60. It is shown that experimental and simulated results are in good agreement.
Similar content being viewed by others
References
H. J. Grabke, and M. Schütze (eds.), “Corrosion by Carbon and Nitrogen” in EFC Publications No. 41 (Woodhead Publishing, Cambridge, 2007).
J. L. Meijering, “Internal Oxidation in Alloys” in Advances in Materials Science, eds. H. Hermann, Vol. 1 (Wiley, New York, 1971).
U. Krupp, “Nitridation of Alloys”, chapter in Shreir’s Handbook of Corrosion, eds. T. Richardson et al. Vol. 1 (Elsevier, 2010), p. 304.
P. S. Gupton, The Heat Treatment Source Book, (ASTM, Metals Park, 2001).
V. B. Trindade, U. Krupp, Ph. E.-G. Wagenhuber and H.-J. Christ, Materials and Corrosion 6, (1), 2005 (785).
V. B. Trindade, Hochtemperaturoxidation chromlegierter Stähle und von Nickel-Basislegierungen: Experimentelle Untersuchung und Computersimulation, (Shaker Verlag, Aachen, 2006).
C. Wagner, Zeitschrift für Elektrochemie 63, 1959 (722).
K. Jahns, M. Landwehr, J. Wübbelmann and U. Krupp, Oxidation of Metals 70, 2013 (107).
K. Jahns, M. Landwehr, J. Wübbelmann and U. Krupp, Materials and Corrosion 65, (3), 2014 (305).
K. Jahns, K. Balinski, M. Landwehr, J. Wübbelmann and U. Krupp, Materials and Corrosion, accepted.
S. G. R. Brown and N. B. Bruce, Scripta Metallurgica et Materialia 32, 1995 (241).
M. F. Zhu and C. P. Hong, ISIJ International 42, 2002 (52).
J. Kroc: “Application of Cellular Automata Simulations to Modelling of Dynamic Recrystallization”, in Lecture Notes in Computer Science ICCS, 773 (2002).
S. Kundu, M. Dutta, S. Ganguly and S. Chandra, Scripta Materialia 50, 2004 (891).
L. Zhou and X. Wei, Scripta Materialia 37, 1997 (1483).
L. Zhou and X. Wei, Scripta Materialia 40, 1999 (365).
U. Buschmann, “Modellierung und Simulation von Hoch-Temperatur-Korrosionsprozessen”, PhD Thesis, Universität Siegen, 2007.
H. Mehrer, Diffusion in Solids, (Springer, Heidelberg, 2007).
J. C. Fisher, Journal of Applied Physics 22, (1), 1951 (74).
I. Kaur, Y. Mishin and W. Gust, Fundamentals of Grain and Interphase Boundary Diffusion, (Wiley, Chichester, 1995).
G. B. Gibbs, Grain boundary impurity diffusion. Physica Status Solidi B 16, (1), 1966 (K27–K29).
B. Chopard and M. Droz, Cellular Automata modelling of Physical Systems, (Cambridge University Press, Cambridge, 1998).
J.-W. Park and C. J. Altstetter, Metallurgical and Materials Transactions A 18, 1987 (43).
Acknowledgements
The financial support by the German Ministry of Education and Research (BMBF) and the European Fonds for Regional Development (EFRE) is gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Jahns, K., Balinski, K., Landwehr, M. et al. Modeling of Intergranular Oxidation by the Cellular Automata Approach. Oxid Met 87, 285–295 (2017). https://doi.org/10.1007/s11085-017-9732-6
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11085-017-9732-6