Skip to main content
Log in

Production of cyclo-hafnium metal–organic thin film using a specific method

  • Published:
Optical and Quantum Electronics Aims and scope Submit manuscript

Abstract

Cyclo-hafnium metal–organic thin film was successfully synthesized and deposited on amorphous glass using a specific method, where amorphous substrate was used for synthesis and coating. Then, the film was annealed at 300 °C in an oven (ambient conditions). Optical and structural properties of the films were also investigated within the study. The structure of the film was analyzed using the mid-infrared spectrum. Optical properties were investigated via the UV–Vis spectroscopic technique. Film thickness was measured with AFM (tapping mode). Surface properties and elemental ratio of the films were examined and measured with SEM and EDX analysis. The highest transmittance and lowest reflectance values within the visible range were identified. The characteristic triethanolamine and hafnium-oxide peaks were observed in the infrared spectrum. FIR spectra of the films were found to be in accordance with the literature. SEM images of the films revealed that the surface of the films is fragile. EDX analysis of hafnium, organic parts of the compound and some minerals of amorphous glass were shown.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  • Al-Kuhaili, M.F.: Optical properties of hafnium oxide thin films and their application in energy-efficient windows. Opt. Mater. 27, 383–387 (2004)

    Article  ADS  Google Scholar 

  • Barreca, D., Garon, S., Zanella, P., Tondello, E.: In: Proceedings of the Twelfth European Conference on Chemical Vapour Deposition, (PR8) 9, 667 (1999)

  • Blodgett, K.B.: Films built by depositing successive monomolecular layers on a solid surface. J. Am. Chem. Soc. 57, 1007–1022 (1935)

    Article  Google Scholar 

  • Erdik, E.: Organik Kimyada Spektroskopik Yöntemler, pp. 127–214. Ankara, Gazi Kitabevi (2005)

    Google Scholar 

  • Frank, M.M., Sayan, S., Dörmann, S., Emge, T.J., Wielunski, L.S., Garfunkel, E., Chabal, Y.J.: Hafnium oxide gate dielectrics grown from an alkoxide precursor: structure and defects. Mater. Sci. Eng., B 109, 6–10 (2004)

    Article  Google Scholar 

  • Hardya, A., Adelmann, C., Van Elshocht, S., Van den Rul, H., Van Bael, M.K., De Gendt, S., D’Olieslaeger, M., Heyns, M., Kittl, J.A., Mullens, J.: Study of interfacial reactions and phase stabilization of mixed Sc, Dy, Hf high-k oxides by attenuated total reflectance infrared spectroscopy. Appl. Surf. Sci. 255, 7812–7817 (2009)

    Article  ADS  Google Scholar 

  • Hoogeveen, N.G., Stuart, M.A.C., Fleer, G.J., Bohmer, M.R.: Formation and stability of multilayers of polyelectrolytes. Langmuir 12, 3675–3681 (1996)

    Article  Google Scholar 

  • Kariper, İ.A., Özpozan, T.: Cobalt xanthate thin film with chemical bath deposition. J. NanoMater. 2013, 1 (2013)

    Article  Google Scholar 

  • Kariper, İ.A., Özpozan, T.: Optical and electrical properties of nickel xanthate thin films. Bull. Mater. Sci. 37, 553–561 (2014)

    Article  Google Scholar 

  • Kasap, S., Capper, P.: Springer Handbook of Electronic and Photonic Materials, pp. 19–44. Springer, Berlin (2006)

    Book  Google Scholar 

  • Kaul, A.R., Gorbenko, O.Y., Botev, A.N., Burova, L.I.: MOCVD of pure and Ga-doped epitaxial ZnO. Superlattices Microstruct. 38, 272–282 (2005)

    Article  ADS  Google Scholar 

  • Kozlovskaya, V., Yakovlev, S., Libera, M., Sukhishvili, S.A.: Surface priming and the self-assembly of hydrogen-bonded multilayer capsules and films. Macromol 38, 4828–4836 (2005)

    Article  ADS  Google Scholar 

  • Martínez, F.L., Toledano-Luque, M., Gandía, J.J., Cárabe, J., Bohne, W., Röhrich, J., Strub, E., Mártil, I.: Optical properties and structure of HfO2 thin films grown by high pressure reactive sputtering. J. Phys. D Appl. Phys. 40, 5256 (2007)

    Article  ADS  Google Scholar 

  • Migalska-Zalas, A., Luc, J., Sahraoui, B., Kityk, I.V.: Kinetics of third-order nonlinear optical susceptibilities in alkynyl ruthenium complexes. Opt. Mater. 28, 1147–1151 (2006)

    Article  ADS  Google Scholar 

  • Pankove, J.I.: Optical Processes in Semiconductors, pp. 91–95. Dover Publications Inc., New York (1975)

    Google Scholar 

  • Pervak, V., Krausz, F., Apolonski, A.: Hafnium oxide thin films deposited by reactive middle-frequency dual-magnetron sputtering. Thin Solid Films 515, 7984–7989 (2007)

    Article  ADS  Google Scholar 

  • Plyler, E.K., Blaine, L.R.: Optical and structural properties of chromium telluride (Cr2Te3) thin film produced via chemical bath deposition. J. Res. Nat. Bur. Stand. C 64(1), 55–56 (1959)

    Google Scholar 

  • Springer, J., Recha, B., Reetz, W., Müller, J., Vanecek, M.: Light trapping and optical losses in microcrystalline silicon pin solar cells deposited on surface-textured glass/ZnO substrates. Sol. Energy Mater. Sol. Cells 85, 1–11 (2005)

    Google Scholar 

  • Znaidi, L.: Sol–gel-deposited ZnO thin films: a review. Mater. Sci. Eng. B 174, 18–30 (2010)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to İshak Afşin Kariper.

Additional information

This article is part of the Topical Collection on Optics in Materials, Energy and Related Technologies 2018.

Guest Edited by Yen-Hsun Su, Songnan Qu, Yiting Yu, Wei Zhang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kariper, İ.A. Production of cyclo-hafnium metal–organic thin film using a specific method. Opt Quant Electron 51, 18 (2019). https://doi.org/10.1007/s11082-018-1729-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11082-018-1729-0

Keywords

Navigation