Abstract
MnO2/carbon nanotube composite electrodes for Li-ion battery application were directly coated with ultrathin thicknesses of aluminum oxide film by atomic layer deposition (ALD). The non-reactive Al2O3 layer not only provides a stable film to protect the manganese oxide and carbon nanotubes from undesirable reaction with the electrolyte but also restrains the volume change strain of manganese oxide during cycling. The first cycle Coulombic efficiency of coated samples was increased to different extents depending on the coating thickness. In the following cycles, the coated electrodes denote high specific capacity, good capacity retention ability, and perfect rate charge/discharge performance.
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Abraham DP, Spila T, Furczon MM, Sammann E (2008) Evidence of transition-metal accumulation on aged graphite anodes by SIMS. Electrochem Solid-State Lett 11:A226–A228. https://doi.org/10.1149/1.2987680
Ahn D, Xiao X (2011) Extended lithium titanate cycling potential window with near zero capacity loss. Electrochem Commun 13:796–799. https://doi.org/10.1016/j.elecom.2011.05.005
Brousse T, Defives D, Pasquereau L, Lee SM, Herterich U, Schleich DM (1997) Metal oxide anodes for Li-ion batteries. Ionics 3:332–337. https://doi.org/10.1007/bf02375707
Cen Y, Yao Y, Xu Q, Xia Z, Sisson RD, Liang J (2016) Fabrication of TiO2-graphene composite for the enhanced performance of lithium batteries. RSC Adv 6:66971–66977. https://doi.org/10.1039/C6RA08144D
Chen H, Zhang Q, Wang J, Xu D, Li X, Yang Y, Zhang K (2014a) Improved lithium ion battery performance by mesoporous Co3O4 nanosheets grown on self-standing NiSix nanowires on nickel foam. J Mater Chem A 2:8483–8490. https://doi.org/10.1039/C4TA00967C
Chen J, Wang Y, He X, Xu S, Fang M, Zhao X, Shang Y (2014b) Electrochemical properties of MnO2 nanorods as anode materials for lithium ion batteries. Electrochim Acta 142:152–156. https://doi.org/10.1016/j.electacta.2014.07.089
Dubarry M, Liaw BY (2009) Identify capacity fading mechanism in a commercial LiFePO4 cell. J Power Sources 194:541–549. https://doi.org/10.1016/j.jpowsour.2009.05.036
Dubarry M, Liaw BY, Chen M-S, Chyan S-S, Han K-C, Sie W-T, Wu S-H (2011) Identifying battery aging mechanisms in large format Li ion cells. J Power Sources 196:3420–3425. https://doi.org/10.1016/j.jpowsour.2010.07.029
Etacheri V, Marom R, Elazari R, Salitra G, Aurbach D (2011) Challenges in the development of advanced Li-ion batteries: a review. Energy Environ Sci 4:3243–3262. https://doi.org/10.1039/C1EE01598B
Fang X, Lu X, Guo X, Mao Y, Hu YS, Wang J, Wang Z, Wu F, Liu H, Chen L (2010) Electrode reactions of manganese oxides for secondary lithium batteries. Electrochem Commun 12:1520–1523. https://doi.org/10.1016/j.elecom.2010.08.023
Feng X, Zhang Y, Song J, Chen N, Zhou J, Huang Z, Ma Y, Zhang L, Wang L (2015) MnO2/graphene nanocomposites for nonenzymatic electrochemical detection of hydrogen peroxide. Electroanalysis 27:353–359. https://doi.org/10.1002/elan.201400481
George SM (2010) Atomic layer deposition: an overview. Chem Rev 110:111–131. https://doi.org/10.1021/cr900056b
Goodenough JB, Kim Y (2010) Challenges for rechargeable Li batteries. Chem Mater 22:587–603. https://doi.org/10.1021/cm901452z
Gowda SR, Gallagher KG, Croy JR, Bettge M, Thackeray MM, Balasubramanian M (2014) Oxidation state of cross-over manganese species on the graphite electrode of lithium-ion cells. Phys Chem Chem Phys 16:6898–6902. https://doi.org/10.1039/C4CP00764F
Guo J, Liu Q, Wang C, Zachariah MR (2012) Interdispersed amorphous MnOx–carbon nanocomposites with superior electrochemical performance as lithium-storage material. Adv Funct Mater 22:803–811. https://doi.org/10.1002/adfm.201102137
Guo X, Han J, Zhang L, Liu P, Hirata A, Chen L, Fujita T, Chen M (2015) A nanoporous metal recuperated MnO2 anode for lithium ion batteries. Nanoscale 7:15111–15116. https://doi.org/10.1039/C5NR05011A
He Y, Yu X, Wang Y, Li H, Huang X (2011) Alumina-coated patterned amorphous silicon as the anode for a lithium-ion battery with high coulombic efficiency. Adv Mater 23:4938–4941. https://doi.org/10.1002/adma.201102568
Huang Y, Lin Z, Zheng M, Wang T, Yang J, Yuan F, Lu X, Liu L, Sun D (2016) Amorphous Fe2O3 nanoshells coated on carbonized bacterial cellulose nanofibers as a flexible anode for high-performance lithium ion batteries. J Power Sources 307:649–656. https://doi.org/10.1016/j.jpowsour.2016.01.026
Jung YS, Cavanagh AS, Riley LA, Kang SH, Dillon AC, Groner MD, George SM, Lee SH (2010) Ultrathin direct atomic layer deposition on composite electrodes for highly durable and safe Li-ion batteries. Adv Mater 22:2172–2176. https://doi.org/10.1002/adma.200903951
Kuksenko SP (2013) Aluminum foil as anode material of lithium-ion batteries: effect of electrolyte compositions on cycling parameters. Russ J Electrochem 49:67–75. https://doi.org/10.1134/s1023193512110080
Kurttepeli M et al (2017) Heterogeneous TiO2/V2O5/carbon nanotube electrodes for lithium-ion batteries. ACS Appl Mater Interfaces:8055–8064. https://doi.org/10.1021/acsami.6b12759
Lahiri I, Oh SM, Hwang JY, Kang C, Choi M, Jeon H, Banerjee R, Sun YK, Choi W (2011) Ultrathin alumina-coated carbon nanotubes as an anode for high capacity Li-ion batteries. J Mater Chem 21:13621–13626. https://doi.org/10.1039/C1JM11474C
Li H, Balaya P, Maier J (2004) Li-storage via heterogeneous reaction in selected binary metal fluorides and oxides. J Electrochem Soc 151:A1878–A1885. https://doi.org/10.1149/1.1801451
Li J, Xiao H, Lin X, Zhao Y (2011) An efficient closed-form solution of synchronization and channel estimation in UWB. In: 2011 Seventh International Conference on Computational Intelligence and Security. pp 698–702. https://doi.org/10.1109/CIS.2011.159
Li L, Raji A-RO, Tour JM (2013) Graphene-wrapped MnO2–graphene nanoribbons as anode materials for high-performance lithium ion batteries. Adv Mater 25:6298–6302. https://doi.org/10.1002/adma.201302915
Li L, Hu ZA, An N, Yang YY, Li ZM, Wu HY (2014) Facile synthesis of MnO2/CNTs composite for supercapacitor electrodes with long cycle stability. J Phys Chem C 118:22865–22872. https://doi.org/10.1021/jp505744p
Liu X, Sun Q, Ng AMC, Djurišić AB, Xie M, Dai B, Tang J, Surya C, Liao C, Shih K (2015) An alumina stabilized graphene oxide wrapped SnO2 hollow sphere LIB anode with improved lithium storage. RSC Adv 5:100783–100789. https://doi.org/10.1039/C5RA22482A
Luo S, Xu S, Zhang Y, Liu J, Wang S, He P (2016) Preparation of MnO2 and MnO2/carbon nanotubes nanocomposites with improved electrochemical performance for lithium ion batteries. J Solid State Electrochem 20:2045–2053. https://doi.org/10.1007/s10008-016-3208-5
Marichy C, Tessonnier J-P, Ferro MC, Lee K-H, Schlogl R, Pinna N, Willinger M-G (2012) Labeling and monitoring the distribution of anchoring sites on functionalized CNTs by atomic layer deposition. J Mater Chem 22:7323–7330. https://doi.org/10.1039/C2JM00088A
Moffatt WG, Research GEC, Operation DCTM (1981) The handbook of binary phase diagrams. vol 4. General Electric Company, Corporate Research and Development, Technology Marketing Operation,
Oh Y, Ahn D, Nam S, Park B (2010) The effect of Al2O3-coating coverage on the electrochemical properties in LiCoO2 thin films. J Solid State Electrochem 14:1235–1240. https://doi.org/10.1007/s10008-009-0946-7
Poizot P, Laruelle S, Grugeon S, Dupont L, Tarascon JM (2000) Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature 407:496–499. https://doi.org/10.1038/35035045
Puurunen RL (2005) Surface chemistry of atomic layer deposition: a case study for the trimethylaluminum/water process. J Appl Phys 97:121301. https://doi.org/10.1063/1.1940727
Riley LA, Cavanagh AS, George SM, Lee S-H, Dillon AC (2011) Improved mechanical integrity of ALD-coated composite electrodes for Li-ion batteries. Electrochem Solid-State Lett 14:A29–A31. https://doi.org/10.1149/1.3529367
Smith AJ, Dahn JR (2012) Delta differential capacity analysis. J Electrochem Soc 159:A290–A293. https://doi.org/10.1149/2.076203jes
Sun B, Chen Z, Kim H-S, Ahn H, Wang G (2011) MnO/C core–shell nanorods as high capacity anode materials for lithium-ion batteries. J Power Sources 196:3346–3349. https://doi.org/10.1016/j.jpowsour.2010.11.090
Sun S, Zhao X, Yang M, Wu L, Wen Z, Shen X (2016) Hierarchically ordered mesoporous Co3O4 materials for high performance Li-ion batteries. Sci Rep 6:19564. https://doi.org/10.1038/srep19564
Thackeray MM, Wolverton C, Isaacs ED (2012) Electrical energy storage for transportation-approaching the limits of, and going beyond, lithium-ion batteries. Energy Environ Sci 5:7854–7863. https://doi.org/10.1039/C2EE21892E
Wohlfahrt-Mehrens M, Vogler C, Garche J (2004) Aging mechanisms of lithium cathode materials. J Power Sources 127:58–64. https://doi.org/10.1016/j.jpowsour.2003.09.034
Wu M-S, Chiang P-CJ, Lee J-T, Lin J-C (2005) Synthesis of manganese oxide electrodes with interconnected nanowire structure as an anode material for rechargeable lithium ion batteries. J Phys Chem B 109:23279–23284. https://doi.org/10.1021/jp054740b
Xia H, Lai M, Lu L (2010) Nanoflaky MnO2/carbon nanotube nanocomposites as anode materials for lithium-ion batteries. J Mater Chem 20:6896–6902. https://doi.org/10.1039/C0JM00759E
Xia H, Wang Y, Lin J, Lu L (2012) Hydrothermal synthesis of MnO2/CNT nanocomposite with a CNT Core/porous MnO2 sheath hierarchy architecture for supercapacitors. Nanoscale Res Lett 7:33. https://doi.org/10.1186/1556-276x-7-33
Xiao X, Lu P, Ahn D (2011) Ultrathin multifunctional oxide coatings for lithium ion batteries. Adv Mater 23:3911–3915. https://doi.org/10.1002/adma.201101915
Xu S, Hessel CM, Ren H, Yu R, Jin Q, Yang M, Zhao H, Wang D (2014) α-Fe2O3 multi-shelled hollow microspheres for lithium ion battery anodes with superior capacity and charge retention. Energy Environ Sci 7:632–637. https://doi.org/10.1039/C3EE43319F
Yan J, Fan Z, Wei T, Cheng J, Shao B, Wang K, Song L, Zhang M (2009) Carbon nanotube/MnO2 composites synthesized by microwave-assisted method for supercapacitors with high power and energy densities. J Power Sources 194:1202–1207. https://doi.org/10.1016/j.jpowsour.2009.06.006
Zheng H, Sun Q, Liu G, Song X, Battaglia VS (2012) Correlation between dissolution behavior and electrochemical cycling performance for LiNi1/3Co1/3Mn1/3O2-based cells. J Power Sources 207:134–140. https://doi.org/10.1016/j.jpowsour.2012.01.122
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Fan, Y., Clavel, G. & Pinna, N. Effect of passivating Al2O3 thin films on MnO2/carbon nanotube composite lithium-ion battery anodes. J Nanopart Res 20, 216 (2018). https://doi.org/10.1007/s11051-018-4315-2
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DOI: https://doi.org/10.1007/s11051-018-4315-2