Abstract
A Co3O4/ordered mesoporous carbon (OMC) nanocomposite, in which Co3O4 nanoparticles (NPs), with an average size of about 10 nm homogeneously embedded in the OMC framework, are prepared for use as an anode material in Li-ion batteries. The composite is prepared by a one-pot synthesis based on the solvent evaporation-induced co-self-assembly of a phenolic resol, a triblock copolymer F127, and Co(NO3)2·6H2O, followed by carbonization and oxidation. The resulting material has a high reversible capacity of ~1,025 mA h g−1 after 100 cycles at a current density of 0.1 A g−1. The enhanced cycling stability and rate capability of the composite can be attributed to the combined mesoporous nanostructure which provides efficient pathways for Li-ion transport and the homogeneous distribution of the Co3O4 NPs in the pore wall of the OMC, which prevents aggregation. These findings suggest that the OMC has promise for use as a carbon metric for metals and metal oxides as an anode material in high performance Li-ion batteries.
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Bard AJ, Faulkner LR (2001) Electrochemical methods: fundamentals and applications, Chapter.6, 2nd edn. Wiley, New York, pp 231–233
Bhargava G, Gouzman I, Chun CM, Ramanarayanan TA, Bernasek SL (2007) Characterization of the “native” surface thin film on pure polycrystalline iron: a high resolution XPS and TEM study. Appl Surf Sci 253:4322–4329
Bruce PG, Scrosati B, Tarascon JM (2008) Nanomaterials for rechargeable lithium batteries. Angew Chem Int Ed 47:2930–2946
Çelik Ö, Dag Ö (2001) A new lyotropic liquid crystalline system: oligo(ethylene oxide) surfactants with [M(H(2)O)(n)]X(m) transition metal complexes. Angew Chem Int Ed 40:3799–3803
Chen QS, Wang Y (2010) Microwave-assisted synthesis of a Co3O4–graphene sheet-on-sheet nanocomposite as a superior anode material for Li-ion batteries. J Mater Chem 20:9735–9739
Dollé M, Poizot P, Dupont L, Tarascon JM (2002) Experimental evidence for electrolyte involvement in the reversible reactivity of CoO toward compounds at low potential. Electrochem Solid-State Lett 5:A18–A21
Grugeon S, Laruelle S, Grugeon S, Dupont L, Poizot P, Tarascon JM (2001) Particle size effects on the electrochemical performance of copper oxides toward lithium. J Electrochem Soc 148:A285–A292
Guo YG, Hu JS, Wan LJ (2008) Nanostructured materials for electrochemical energy conversion and storage devices. Adv Mater 20:2878–2887
Kang YM, Kim KT, Lee KY, Lee SJ, Jung JH, Lee JY (2003) Improvement of initial coulombic efficiency of Co3O4 by ball milling using Ni as an additive. J Electrochem Soc 150:A1538–A1543
Kim GP, Nam I, Kim ND, Park J, Park S, Yi J (2012) A synthesis of graphene/Co3O4 thin films for lithium ion battery anodes by coelectrodeposition. Electrochem Commun 22:93–96
Larcher D, Sudant G, Leriche JB, Chabre Y, Tarascon JM (2002) The electrochemical reduction of Co3O4 in a lithium cell. J Electrochem Soc 149:A234–A241
Laruelle S, Grugeon S, Poizot P, Dolle M, Dupont L, Tarascon JM (2002) On the origin of the extra electrochemical capacity displayed by MO/Li cells at low potential. J Electrochem Soc 149:A627–A634
Liu HC, Yen SK (2007) Characterization of electrolytic Co3O4 thin films as anodes for lithium ion batteries. J Power Sour 166:478–484
Liu HJ, Bo SH, Cui WJ, Li F, Wang CX, Xia YY (2008a) Nano-sized cobalt oxide/mesoporous carbon sphere composites as negative electrode material for lithium-ion batteries. Electrochim Acta 53:6497–6503
Liu Y, Mi C, Su L, Zhang X (2008b) Hydrothermal synthesis of Co3O4 microspheres as anode material for lithium-ion batteries. Electrochim Acta 53:2507–2513
McCafferty E, Wightman JP (1998) Determination of the concentration of surface hydroxyl groups on metal oxide films by a quantitative XPS method. Surf Interface Anal 26:549–564
Meng Y, Gu D, Zhang F, Shi Y, Cheng L, Feng D, Wu Z, Chen Z, Wan Y, Stein A, Zhao D (2006) A family of highly ordered mesoporous polymer resin and carbon structures from organic–organic self-assembly. Chem Mater 18:4447–4464
Petitto SC, Marsh EM, Carson GA, Langell MA (2008) Cobalt oxide surface chemistry: the interaction of CoO(100), Co3O4(110) and Co3O4(111) with oxygen and water. J Mol Catal A-Chem 281:49–58
Poizot P, Laruelle S, Grugeon S, Dupont L, Tarascon JM (2000) Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature 407:496–499
Qiao H, Xiao L, Zheng Z, Liu H, Jia F, Zhang L (2008) One-pot synthesis of CoO/C hybrid microspheres as anode materials for lithium-ion batteries. J Power Sour 185:486–491
Shaju KM, Jiao F, De′bart A, Bruce PG (2007) Mesoporous and nanowire Co3O4 as negative electrodes for rechargeable lithium batteries. Phys Chem Chem Phys 9:1837–1842
Shi Z, Lian Y, Liao F, Zhou X, Gu Z, Zhang Y, Iijima S (1999) Purification of single-wall carbon nanotubes. Solid State Commun 112:35–37
Sietsma JRA, Meeldijk JD, den Breejen JP, Versluijs-Helder M, van Dillen AJ, de Jongh PE, de Jong KP (2007) The preparation of supported NiO and Co3O4 nanoparticles by the nitric oxide controlled thermal decomposition of nitrates. Angew Chem Int Ed 46:4547–4549
Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J, Siemieniewska T (1985) Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure Appl Chem 57:603–619
Thackeray MM, Baker SD, Adendorff KT (1985) Lithium insertion into Co3O4: a preliminary investigation. Solid State Ionics 17:175–181
Wang G, Shen X, Yao J, Wexler D, Ahn J (2009) Hydrothermal synthesis of carbon nanotube/cobalt oxide core–shell one–dimensional nanocomposite and application as an anode material for lithium-ion batteries. Electrochem Commun 11:546–549
Wang Y, Zhang HJ, Lu L, Stubbs LP, Wong CC, Lin J (2010) Designed functional systems from peapod-like Co@Carbon to Co3O4@Carbon nanocomposites. ACS Nano 4:4753–4761
Wang J, Xue C, Lv Y, Zhang F, Tu B, Zhao D (2011a) Kilogram-scale synthesis of ordered mesoporous carbons and their electrochemical performance. Carbon 49:4580–4588
Wang W, Wang H, Wei W, Xiao ZG, Wan Y (2011b) Self-assembling and size-selective synthesis of Ni and NiO nanoparticles embedded in ordered mesoporous carbon and polymer frameworks. Chem Eur J 17:13461–13472
Wu ZS, Ren W, Wen L, Gao L, Zhao J, Chen Z, Zhou G, Li F (2010) Cheng HM, Graphene anchored with Co3O4 nanoparticles as anode of lithium ion batteries with enhanced reversible capacity and cyclic performance. ACS Nano 4:3187–3194
Yang H, Yan Y, Liu Y, Zhang F, Zhang R, Li M, Meng Y, Zhao D (2004) A simple melt impregnation method to synthesize ordered mesoporous carbon and carbon nanofiber bundles with graphitized structure from pitches. J Phys Chem B 108:17320–17328
Yang S, Feng X, Ivanovici S, Müllen K (2010) Fabrication of graphene-encapsulated oxide nanoparticles: towards high-performance anode materials for lithium storage. Angew Chem Int Ed 49:8408–8411
Yao W, Yang J, Wang JL, Nuli Y (2008) Multilayered cobalt oxide platelets for negative electrode material of a lithium-ion battery. J Electrochem Soc 155:A903–A908
Yu Y, Chen CH, Shui JL, Xie S (2005) The design of a LiFePO4/carbon nanocomposite with a core–shell structure and its synthesis by an in situ polymerization restriction method. Angew Chem Int Ed 44:7085–7089
Yu T, Deng Y, Wang L, Liu R, Zhang L, Tu B, Zhao D (2007) Ordered mesoporous nanocrystalline titanium-carbide/carbon composites from in situ carbothermal reduction. Adv Mater 19:2301–2306
Yuan Z, Huang F, Feng C, Sun J, Zhou Y (2003) Synthesis and electrochemical performance of nanosized Co3O4. Mater Chem Phys 79:1–4
Zhang H, Tao H, Jiang Y, Jiao Z, Wu M, Zhao B (2010) Ordered CoO/CMK-3 nanocomposites as the anode materials for lithium-ion batteries. J Power Sour 195:2950–2955
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This subject was supported by WCU (World Class University) program through the National Research Foundation of Korea funded by the Ministry of Education, Science and Technology (R31-10013).
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Park, J., Kim, GP., Umh, H.N. et al. Co3O4 nanoparticles embedded in ordered mesoporous carbon with enhanced performance as an anode material for Li-ion batteries. J Nanopart Res 15, 1943 (2013). https://doi.org/10.1007/s11051-013-1943-4
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DOI: https://doi.org/10.1007/s11051-013-1943-4