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Synthesis of CdS nanocrystals in poly(3-hexylthiophene) polymer matrix: optical and structural studies

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Abstract

CdS nanocrystals (NCs) were directly synthesized in P3HT matrix by decomposition of single-molecule precursor compound. In this process, a molecular precursor solution was mixed with the polymeric solution. On heating the solution to the decomposition temperature of the precursor compound, NCs were formed in situ at temperatures as low as 120 °C. The effects of the precursor concentration on the optical properties of the composite were studied. The results showed evidence of charge transfer and size variation depending on NCs concentration. CdS phase can be formed using this process at 120 °C temperature as was evident from the X-ray diffraction studies. Transmission electron microscope results confirm formation of monodispersed CdS nanoparticles of average size 4 nm. A possible mechanism of the CdS film formation was also investigated. UV–Vis measurements show that these CdS composites possess a direct band gap energy higher than 2.45 eV depending on the concentration of P3HT, indicating that the nano size can be controlled by the concentration of polymer additive in the composite. A higher concentration of P3HT showed more blue shift.

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References

  • Beek WJE, Wienk MM, Janssen RAJ (2006) Hybrid solar cells from regio-regular polythiophene and ZnO nanoparticles. Adv Funct Mater 16:1112–1116

    Article  CAS  Google Scholar 

  • Borriello C, Masala S, Bizzarro V, Nenna G, Re M, Pesce E, Minarini C, Di luccio t (2011) electroluminescence properties of poly(3-hexylthiophene)-cadmium sulfide nanoparticles grown in situ. J Appl Polym Sci 3624–3629

  • Coates NE, Zhou H, Kramer S, Li L, Moses D (2010) Solution based in situ synthesis and fabrication of ultrasensitive CdSe photoconductors. Adv Mater 22:5366–5369

    Article  CAS  Google Scholar 

  • Dayal S, Kopidakis N, Olson DC, Ginley DS, Rumbles G (2009) Direct synthesis of CdSe nanoparticles in poly(3-hexylthiophene). J Am Chem Soc 131:17726–17727

    Article  CAS  Google Scholar 

  • Dayal S, Kopidakis N, Olson DC, Ginley DS, Rumbles G (2010) Photovoltaic devices with a low bandgap polymer and CdSe nanostructures exceeding 3 % efficiency. Nano Lett 10:239–242

    Article  CAS  Google Scholar 

  • Di Luccio T, Laera AM, Tapfer L, Kempter S, Kraus R, Nickel B (2006) Controlled nucleation and growth of CdS nanoparticles in a polymer matrix. J Phys Chem B 110:12603–12609

    Article  Google Scholar 

  • Dowland S, Lutz T, Ward A, King SP, Sudlow A, Hill MS, Molloy KC, Haque SA (2011) Direct growth of metal sulfide nanoparticle networks in solid state polymer films for hybrid inorganic–organic solar cells. Adv Mater 23:2739–2744

    Article  CAS  Google Scholar 

  • Greaney MJ, Das S, Webber DH, Bradforth SE, Brutchey RL (2012) Improving open circuit potential in hybrid P3HT:CdS bulk heterojunction solar cells via colloidal tert-butyl thiol ligand exchange. ACS Nano 6:4222–4230

    Article  CAS  Google Scholar 

  • Greenham NC, Peng X, Alivisatos AP (1996) Charge separation and transport in conjugated polymer/semiconductor nanocrystal composites studied by photoluminescence quenching and photoconductivity. Phys Rev B 54:17628–17637

    Article  CAS  Google Scholar 

  • Habas SE, Platt HAS, Maikel FAM, Van H, Ginley DS (2010) Low cost inorganic solar cells, from inks to printed device. Chem Rev 11:6571–6594

    Article  Google Scholar 

  • Han Z, Zhang J, Yang X, Cao W (2011) Synthesis and applications in solar cell of poly(3-octyl thiophene)/cadmium sulfide nanocomposite. Sol Energ Mat Sol C 95:483–490

    Article  CAS  Google Scholar 

  • Hoppe H, Sariciftci NS (2004) Organic solar cells: an overview. J Mater Res 19:1924–1945

    Article  CAS  Google Scholar 

  • Huynh WU, Dittmer JJ, Alivisatos AP (2002) Hybrid nanorod-polymer solar cells. Science 295:2425–2427

    Article  CAS  Google Scholar 

  • Jeltsch KF, Schadel M, Bonekamp JB, Niyamakom P, Rauscher F, Lademann HWA, Dumsch I, Allard S, Scherf U, Meerholz K (2012) Efficiency enhanced hybrid solar cells using a blend of quantum dots and nanorods. Adv Funct Mater 22:397–404

    Article  CAS  Google Scholar 

  • Khan MT, Kaur A, Dhawan SK, Chand S (2011) In situ growth of cadmium telluride nanocrystals in poly(3-hexylthiophene) matrix for photovoltaic applications. J Appl Phys 110:044509-1-044509-7

    Google Scholar 

  • Laera AM, Resta V, Ferrara MC, Schioppa M, Piscopiello E, Tapfer L (2011) Synthesis of hybrid organic-inorganic nanocomposite materials based on CdS nanocrystals for energy conversion applications. Nanopart Res 13:5705–5717

    Article  CAS  Google Scholar 

  • Leventis HC, King SP, Sudlow A, Hill MS, Molloy KC, Haque SA (2010) Nanostructured hybrid polymer-inorganic solar cell active layers formed by controllable in situ growth of semiconducting sulfide networks. Nano Lett 10:1253–1258

    Article  CAS  Google Scholar 

  • Li Y, Ye M, Yang C, Li X, Li Y (2005) Composition and shape controlled synthesis and optical properties of Zn x Cd1−x S alloyed nanocrystals. Adv Funct Mater 15:433–441

    Article  CAS  Google Scholar 

  • Liao HC, Chen SY, Liu DM (2009) In situ growing CdS single crystal nanorods via P3HT polymer as a soft template for enhancing photovoltaic performance. Macromolecules 42:6558–6563

    Article  CAS  Google Scholar 

  • Liao HC, Lin CC, Chen YW, Liu TC, Chen SY (2010) Improvement in photovoltaic performance for hybrid P3HT/elongated CdS nanocrystals solar cells with F-doped SnO2 arrays. J Mater Chem 20:5429–5435

    Article  CAS  Google Scholar 

  • Liao HC, Chantarat N, Chen SY, Peng CH (2011) Annealing effect on photovoltaic performance of hybrid P3HT/in-situ grown CdS nanocrystal solar cell. J Electrochem Soc 158(7):E67–E72

    Article  CAS  Google Scholar 

  • Liu W (2006) Low temperature synthesis of hexagonal phase ZnS nanocrystals by thermolysis of an air stable single source molecular precursor in air. Mater Lett 60:551–554

    Article  CAS  Google Scholar 

  • Liu J, Wang W, Yu H, Wu Z, Peng J, Cao Y (2008) Surface ligand effect in MEHPPV/TiO2 hybrid solar cells. Sol Energy Mater Sol C 92:1403–1409

    Article  CAS  Google Scholar 

  • Maier E, Rath T, Hass W, Werzer O, Saf R, Hofer F, Meissner D, Volobujeva O, Bereznev S, Mellikov E, Amenitsch H, Resel R, Trimmel G (2011) CuInS2-poly(3-ethyl-4-butanoate)thiophene nanocomposite solar cells: preparation by an in situ formation route, performance and stability issues. Sol Energy Mater Sol C 95:1354–1361

    Article  CAS  Google Scholar 

  • Masala S, Gobbo SD, Borriello C, Bizzarro V, Ferrara VL, Pesce E, Minarini C, Crescenzi MD, Di Luccio T (2011) Hybrid polymer–CdS solar cell active layers formed by in situ growth of CdS nanoparticles. J Nanopart Res 13:6537–6544

    Article  CAS  Google Scholar 

  • Mayukh M, Jung IH, He F, Yu L (2012) Incremental optimization in donor polymers for bulk heterojunction organic solar cells exhibiting high performance. J Polym Sci 50:1057–1070

    Article  CAS  Google Scholar 

  • Moule AJ, Chang L, Thambidurai C, Vidu R, Stroeve P (2012) Hybrid solar cells, basic principles and role of ligands. J Mater Chem 22:2351–2368

    Article  CAS  Google Scholar 

  • Nair PS, Radhakrishnan T, Revaprasadu N, Kolawole GA, Brien PO (2002) A novel single source precursor for the preparation of CdS nanoparticles. J Mater Chem 12:2722–2725

    Article  CAS  Google Scholar 

  • Nair PS, Radhakrishna T, Revaprasadu N, Kolawole GA, Luyt AS, Djokovic VJ (2005) Preparation and characterization of polystyrene films containing PbS nanoparticles. Mater Sci 40:4407–4409

    Article  CAS  Google Scholar 

  • Plante IJL, Zeid TW, Yang P, Mokari T (2010) Synthesis of metal sulfide nanomaterials via thermal decomposition of single source precursors. J Mater Chem 20:6612–6617

    Article  Google Scholar 

  • Pradhan N, Katz B, Efrima S (2003) Synthesis of high-quality metal sulfide nanoparticles from alkyl xanthate single precursors in alkylamine solvents. J Phys Chem B107:13843–13854

    Google Scholar 

  • Reiss P, Couderc E, Girolamo JD, Pron A (2010) Confined polymers/semiconductor nanocrystals hybrid materials-preparation, electrical transport properties and applications. Nanoscale 3:446–489

    Article  Google Scholar 

  • Ren S, Chang LY, Lim SK, Zhao J, Smith M, Ni Z, Bulovic V, Bawendi M, Gradecak S (2011) Inorganic–organic hybrid solar cell: bridging quantum dots to conjugated polymer nanowires. Nano Lett 11:3998–4002

    Article  CAS  Google Scholar 

  • Resta V, Laera AM, Piscopiello E, Schioppa M, Tapfer L (2010) Highly efficient precursors for direct synthesis of tailored CdS nanocrystals in organic polymers. J Phys Chem C 114:17311–17317

    Article  CAS  Google Scholar 

  • Saunders BR, Turner ML (2008) Nanoparticle–polymer photovoltaic cell. Adv Colloid Interface Sci 138:1–23

    Article  CAS  Google Scholar 

  • Shen S, Zhang Y, Peng L, Xu B, Du Y, Deng M, Xu H, Wang Q (2011) Generalized synthesis of metal sulfide nanocrystals from single source precursors: size, shape and chemical composition control and their properties. Crys Eng Commun 13:4572–4579

    Article  CAS  Google Scholar 

  • Stavrinadis A, Beal R, Smith JM, Assender HE, Watt AAR (2008) Direct formation of PbS nanorods in a conjugated polymer. Adv Mater 20:3105–3109

    Article  CAS  Google Scholar 

  • Talapin DV, Lee JS, Kovalenko MV, Shevchenko EV (2010) Prospects of colloidal nanocrystals for electronic and optoelectronic applications. Chem Rev 110:389–458

    Article  CAS  Google Scholar 

  • Verma D, Rao AR, Dutta V (2009) Surfactant free CdTe nanoparticles mixed MEHPP hybrid solar cell deposited by spin coating technique. Sol Energy Mater Sol C 93(9):1482–1487

    Article  CAS  Google Scholar 

  • Wang Z, Qu S, Zeng X, Zhang C, Shi M, Tan F, Wang Z, Liu J, Hou Y, Teng F, Feng Z (2008) Synthesis of MDMO-PPV capped PbS quantum dots and their application to solar cells, polymer. Polymer 49(21):4647–4651

    Article  CAS  Google Scholar 

  • Wang Y, Wei W, Liu X, Gu Y (2012) Research progress on polymer heterojunction solar cells, solar energy materials and solar cells. Sol Energy Mater Sol C 98:129–145

    Article  CAS  Google Scholar 

  • Warner JH, Watt AAA (2006) Monodisperse PbS nanocrystals synthesized in a conducting polymer. Mater Lett 60:2375–2379

    Article  CAS  Google Scholar 

  • Zhou Y, Eck M, Kruger M (2010) Bulk-heterojunction hybrid solar cells based on colloidal nanocrystals and conjugated polymers. Energy Environ Sci 3:1851–1864

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors are thankful to TAPSUN (Technologies and Products for Solar Energy Utilization through Networks) program (NWP-54 project) from CSIR for financial support. The authors declare no competing financial interest.

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Authors and Affiliations

  1. Organic and Hybrid Solar Cell Group, National Physical Laboratory, Dr. K. S. Krishnan Road, New Delhi, 110 012, India

    Kiran Jain & S. Chand

  2. Department of Physics, Delhi Technological University, New Delhi, 110042, India

    Leena Arora

  3. CSIR-SRF, Organic and Hybrid Solar Cell Group, National Physical Laboratory, Dr. K. S. Krishnan Road, New Delhi, 110 012, India

    Vikash Agrawal

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  1. Vikash Agrawal
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  4. S. Chand
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Correspondence to Kiran Jain.

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Agrawal, V., Jain, K., Arora, L. et al. Synthesis of CdS nanocrystals in poly(3-hexylthiophene) polymer matrix: optical and structural studies. J Nanopart Res 15, 1697 (2013). https://doi.org/10.1007/s11051-013-1697-z

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