Abstract
Hematite nanoparticle-coated magnetic composite fiber was prepared in supercritical carbon dioxide (scCO2). With the help of scCO2, cellulose did not need to be dissolved and regenerated and it could be in any form (e.g., cotton wool, filter paper, textile, etc.). The penetrating and swelling effect of scCO2, the slowing reaction rate of weak alkalis, and the template effect of cellulose fibers were discovered to be the key factors for the fabrication of ordered cellulose/Fe2O3 composite fibers. The structures of the composite fibers as well as the layers of Fe2O3 particles were characterized by means of scanning/transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and Raman investigation. It was found that α-Fe2O3 granules which ranged from 30 to 85 nm with average diameter around 55 nm would be generated on the surface of cellulose fibers via potassium acetate, while irregular square prisms (ranged from 200 to 600 nm) which were composed of smaller nanoparticles (~10 nm) would be fabricated via urea. And, the obtained composite was highly water repellent with superparamagnetic or ferromagnetic properties.
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References
Aronniemi M, Lahtinen J, Hautojärvi P (2004) Characterization of iron oxide thin films. Surf Interface Anal 36:1004–1006
Bayer IS, Fragouli D, Attanasio A, Sorce B, Bertoni G, Brescia R et al (2011) Water-repellent cellulose fiber networks with multifunctional properties. ACS Appl Mater Interfaces 3:4024–4031
Calvo S, Arias NP, Giraldo O et al (2012) Thermal and magnetic behavior of Angustifolia Kunth bamboo fibers covered with Fe3O4 particles. Physica B Condens Matter 407:3267–3270
Cansell F, Aymonier C (2009) Design of functional nanostructured materials using supercritical fluids. J Supercrit Fluids 47:508–516
Deb P, Biswas T, Sen D, Basumallick A, Mazumder S (2002) Characteristics of Fe2O3 nanoparticles prepared by heat treatment of a nonaqueous powder precipitate. J Nanopart Res 4:91–97
deFaria DLA, Silva SV, deOliveira MT (1997) Raman microspectroscopy of some iron oxides and oxyhydroxides. J Raman Spectrosc 28:873–878
Grasso D, Smets BF, Strevett KA et al (1996) Impact of physiological state on surface thermodynamics and adhesion of Pseudomonas aeruginosa. Environ Sci Technol 30:3604–3608
Gupta AK, Gupta M (2005) Synthesis and surface engineering of iron oxide nanoparticles for biomedical applications. Biomaterials 26:3995–4021
Hu JS, Zhong LS, Song WG, Wan LJ (2008) Synthesis of hierarchically structured metal oxides and their application in heavy metal ion removal. Adv Mater 20:2977–2982
Huang MR, Li XG (1998) Thermal degradation of cellulose and cellulose esters. J Appl Polym Sci 68:293–304
Jiang JZ, Goya GF, Rechenberg HR (1999) Magnetic properties of nanostructured CuFe2O4. J Phys: Condens Matter 11:4063–4078
Kawamoto H, Saka S (2006) Heterogeneity in cellulose pyrolysis indicated from the pyrolysis in sulfolane. J Anal Appl Pyrolysis 76:280–284
Kim J, Yun S, Ounaies Z (2006) Discovery of cellulose as a smart material. Macromolecules 39:4202–4206
Klemm D, Heublein B, Fink HP, Bohn A (2005) Cellulose: fascinating biopolymer and sustainable raw material. Angew Chem Int Edit 44:3358–3393
Kulak AN, Iddon P, Li YT, Armes SP, Colfen H, Paris O et al (2007) Continuous structural evolution of calcium carbonate particles: a unifying model of copolymer-mediated crystallization. J Am Chem Soc 129:3729–3736
Kwok DY, Neumann AW (1999) Contact angle measurement and contact angle interpretation. Adv Colloid Interface 81:167–249
Li W, Wu PY (2009) Biomimetic synthesis of monodisperse rosette-like calcite mesocrystals regulated by carboxymethyl cellulose and the proposed mechanism: an unconventional rhombohedra-stacking route. CrystEngComm 11:2466–2474
Li SM, Jia N, Ma MG, Zhang Z, Liu QH, Sun RC (2011) Cellulose-silver nanocomposites: microwave-assisted synthesis, characterization, their thermal stability, and antimicrobial property. Carbohydr Polym 86:441–447
Lian JB, Duan XC, Ma JM, Peng P, Kim TI, Zheng WJ (2009) Hematite (α-Fe2O3) with various morphologies: ionic liquid-assisted synthesis, formation mechanism, and properties. ACS Nano 3:3749–3761
Liu SL, Zhang LN, Zhou JP, Wu RX (2008a) Structure and properties of cellulose/Fe2O3 nanocomposite fibers spun via an effective pathway. J Phys Chem C 112:4538–4544
Liu SL, Zhang LN, Zhou JP, Xiang JF, Sun JT, Guan JG (2008b) Fiberlike Fe2O3 macroporous nanomaterials fabricated by calcinating regenerate cellulose composite fibers. Chem Mat 20:3623–3628
Liu SL, Zhou JP, Zhang LN (2011) In situ synthesis of plate-like Fe2O3 nanoparticles in porous cellulose films with obvious magnetic anisotropy. Cellulose 18:663–673
Mahadeva SK, Kim J (2011) Hybrid nanocomposite based on cellulose and tin oxide: growth, structure, tensile and electrical characteristics. Sci Technol Adv Mater 12. doi:10.1088/1468-6996/12/5/055006
Mao Y, Zhou JP, Cai J, Zhang LN (2006) Effects of coagulants on porous structure of membranes prepared from cellulose in NaOH/urea aqueous solution. J Membr Sci 279:246–255
McIntyre NS, Zetaruk DG (1977) X-ray photoelectron spectroscopic studies of iron-oxides. Anal Chem 49:1521–1529
Mdarhri A, Brosseau C, Carmona F (2007) Microwave dielectric properties of carbon black filled polymers under uniaxial tension. J Appl Phys 101. doi:10.1063/1.2718867
Muruganandham M, Amutha R, Ahmmad B, Repo E, Sillanpaa M (2010) Self-assembled fabrication of superparamagnetic highly stable mesoporous amorphous iron oxides. J Phys Chem C 114:22493–22501
Nadagouda MN, Varma RS (2007) Synthesis of thermally stable carboxymethyl cellulose/metal biodegradable nanocomposites for potential biological applications. Biomacromolecules 8:2762–2767
Nieuwoudt MK, Comins JD, Cukrowski I (2011) The growth of the passive film on iron in 0.05 M NaOH studied in situ by Raman microspectroscopy and electrochemical polarization. Part II: in situ Raman spectra of the passive film surface during growth by electrochemical polarization. J Raman Spectrosc 42:1353–1365
Niu T, Gu YQ, Huang JG (2011) Luminescent cellulose sheet fabricated by facile self-assembly of cadmium selenide nanoparticles on cellulose nanofibres. J Mater Chem 21:651–656
Ocaña M, Morales MP, Serna CJ (1999) Homogeneous precipitation of uniform α-Fe2O3 particles from iron salts solutions in the presence of urea. J Colloid Interface Sci 212:317–323
Orfao JJM, Antunes FJA, Figueiredo JL (1999) Pyrolysis kinetics of lignocellulosic materials-three independent reactions model. Fuel 78:349–358
Pradhan GK, Parida KM (2011) Fabrication, growth mechanism, and characterization of α-Fe2O3 nanorods. ACS Appl Mater Interfaces 3:317–323
Qu X, Kobayashi N, Komatsu T (2010) Solid nanotubes comprising α-Fe2O3 nanoparticles prepared from ferritin protein. ACS Nano 4:1732–1738
Shekhah O, Ranke W, Schule A, Kolios G, Schlogl R (2003) Styrene synthesis: high conversion over unpromoted iron oxide catalysts under practical working conditions. Angew Chem-Int Edit 42:5760–5763
Si S, Kotal A, Mandal TK, Giri S, Nakamura H, Kohara T (2004) Size-controlled synthesis of magnetite nanoparticles in the presence of polyelectrolytes. Chem Mat 16:3489–3496
Sun N, Swatloski RP, Maxim ML, Rahman M, Harland AG, Haque A et al (2008) Magnetite-embedded cellulose fibers prepared from ionic liquid. J Mater Chem 18:283–290
Terris BD, Thomson T (2005) Nanofabricated and self-assembled magnetic structures as data storage media. J Phys D Appl Phys 38:R199–R222
Tomasko DL, Li HB, Liu DH, Han XM, Wingert MJ, Lee LJ et al (2003) A review of CO2 applications in the processing of polymers. Ind Eng Chem Res 42:6431–6456
Van Oss CJ (2002) Use of the combined Lifshitz-van der Waals and Lewis acid-base approaches in determining the apolar and polar contributions to surface and interfacial tensions and free energies. J Adhes Sci Technol 16:669–677
Wang SB, Min YL, Yu SH (2007a) Synthesis and magnetic properties of uniform hematite nanocubes. J Phys Chem C 111:3551–3554
Wang WW, Zhu YJ, Ruan ML (2007b) Microwave-assisted synthesis and magnetic property of magnetite and hematite nanoparticles. J Nanopart Res 9:419–426
Wang LL, Fei T, Lou Z, Zhang T (2011) Three-dimensional hierarchical flowerlike α-Fe2O3 nanostructures: synthesis and ethanol-sensing properties. ACS Appl Mater Interfaces 3:4689–4694
Xuan S, Wang F, Lai JMY, Sham KWY, Wang Y-XJ, Lee S-F et al (2011) Synthesis of biocompatible, mesoporous Fe3O4 nano/microspheres with large surface area for magnetic resonance imaging and therapeutic applications. ACS Appl Mater Interfaces 3:237–244
Yu QS, Wu PY, Xu P, Li L, Liu T, Zhao L (2008) Synthesis of cellulose/titanium dioxide hybrids in supercritical carbon dioxide. Green Chem 10:1061–1067
Zeng H, Sun SH (2008) Syntheses, properties, and potential applications of multicomponent magnetic nanoparticles. Adv Funct Mater 18:391–400
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We gratefully acknowledge the financial support from the National Science Foundation of China (NSFC) (20934002, 20774022) and the National Basic Research Program of China (No. 2009CB930000).
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Xu, S., Shen, D. & Wu, P. Fabrication of water-repellent cellulose fiber coated with magnetic nanoparticles under supercritical carbon dioxide. J Nanopart Res 15, 1577 (2013). https://doi.org/10.1007/s11051-013-1577-6
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DOI: https://doi.org/10.1007/s11051-013-1577-6