Abstract
Image processing algorithms have been developed to extract fringe length, tortuosity and separation from high resolution transmission electron microscopy images. To validate the separation algorithm, a comparison is made between the image-based fringe separation and that obtained by analysis of X-ray diffraction data for a progressively heat-treated carbon black. Agreement is favorable. To illustrate the utility of the analysis parameters for a range of carbon nanostructures, analysis is applied to a series of pyrolytically prepared carbon soots – qualitatively described as containing amorphous, graphitic or fullerenic nanostructure. For all processing, the intermediate image, in the form of a skeletonized binary image of the original high resolution transmission electron micrograph, is shown and found to accurately reflect the nanostructural organization within the carbon as visually observed. Statistical results for each analysis parameter, extracted from the binary images, are presented in the form of histograms and quantitatively distinguish the different carbon nanostructures.
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References
L.L. Ban P.C. Vegvari W.M. Hess (1972) Norelco Rep 20 1–7
Burchell T.D., 1999. In: Burchell T.D. ed. Carbon materials for advanced technologies, Pergamon Press Inc., New York.
P.R. Buseck H. Bo-Jun L.P. Keller (1987) Energ. Fuel. 1 105–110
X. Chen M. Farber Y. Gao I. Kulaots E.M. Suuberg R.H. Hurt (2003) Carbon 41 1489–1500
J.R. Dennison M. Holtz G. Swain (1996) Spectroscopy 11 38–45
T.J. Frankcombe S.K. Bhatia S.C. Smith (2002) Carbon 40 2341–2349
R.E. Franklin (1950) Acta Crystallogr 3 107–121
H. Fujimoto (2003) Carbon 41 1585–1592
A. Galvez N. Herlin-Boime C. Reynaud C. Clinard J.-N. Rouzard (2002) Carbon 40 2775–2789
Goel A.P. Hebgen J.B. Sande ParticleVander J.B. Howard (2002) Carbon 40 177–182
W.J. Grieco J.B. Howard L.C. Rainey J.B. Sande ParticleVander (2000) Carbon 38 597–614
P.J.F. Harris S.C. Tsang (1997) Philos. Mag. A 76 667–677
P. Hebgen A. Goel J.B. Howard L.C. Rainey J.B. Sande ParticleVander (2000) The Twenty-Eighth Symposium on Combustion The Combustion Institute Pittsburgh 1397–1404
R.D. Heidenreich W.M. Hess L.L. Ban (1968) J. Appl. Crystl. 1 1–19
Henning G.R., 1966. In: Walker P.L. Jr., ed. Chemistry and Physics of Carbon, Vol. 2, p.1.
W.M. Hess L.L. Ban F.J. Eckert V. Chirico (1968) Rubber Chem Technol 43 358–372
D.S. Knight W. B. White (1989) J. Mater. Sci. 4 385–393
M. Levy P. Wong (1964) J. Electrochem. Soc. 11 1088–1091
J. Ma C. Park N.M. Rodriguez R.T.K. Baker (2001) J. Phys. Chem. B 105 11994–12002
C.L. Marotta R.T.K. Baker (2003) Chem. Mater. 15 1140–1146
H. Marsh (1989) Introduction to Carbon Science Butterworths London 107–152
P.A. Marsh S. Voet T.J. Mullens L.D. Price (1970) Rubber Chem. Technol. 43 470–481
P.A. Marsh A. Voet T.J. Mullens L.D. Price (1971) Carbon 9 797–805
InstitutionalAuthorNameMedia Cybernetics L.P (1999) Optimas Silver Springs MD
Millward G.R. & Jefferson D.A. 1970. In: Walker P.L. and Thrower P.A. eds The Chemistry and Physics of Carbon, Vol. 14. Marcel Dekker Inc. New York. Chapter. 1.
R.J. Nemanich S.A. Solin (1979) Phys. Rev. B 20 393–401
Park C., E.S. Engel, A. Crowe, T.R. Gilbert & N.M. Rodriguez, 2000. 16, 8050–8056.
X. Peng Y. Li Z. Luan Z. Di H. Wang B. Tian Z. Jia (2003) Chem. Phys. Lett. 6 154–158
C.J. Pope J.A. Marr J.B. Howard (1993) J. Phys. Chem. 97 11001–11013
N.M. Rodriquez M.-S. Kim R.T.K. Baker (1994) J. Phys. Chem. 98 13108
D.E. Rosner H.D. Allendorf (1968) AIAA J 6 650–654
H.-S. Shim R.H. Hurt N.Y.C. Yang (2000) Carbon 38 29–45
W.R. Smith M.H. Polley (1956) J. Chem. Phys. 52 689–694
E.S. Steigerwalt G.A. Deluga C.M. Lukehart (2002) J. Phys. Chem. B 106 760–766
Thomas J.M., 1965. In: Walker P.L. Jr., ed. The Chemistry and Physics of Carbon, Vol. 1, p.121.
E. Tuinstra J. Koenig (1970) J. Chem. Phys. 53 1126 Occurrence Handle10.1063/1.1674108
R.L. Vander Wal A.J. Tomasek (2003) Combust. Flame 134 1–9
R.L. VanderWal A.J. Tomasek K. Street D.R. Hull W.K. Thompson (2004) Appl. Spectrosc. 58 230–237
F.J. Yang R.T. Yang (2002) Carbon 40 437–444
X. Zhang A. Dukhan I.I. Kantorovich E. Bar-Ziv A. Kandas A.F. Sarofim (1996) The Twenty-Sixth Symposium on Combustion The Combustion Institute Pittsburgh 3111–3118
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Vander Wal, R.L., Tomasek, A.J., Pamphlet, M.I. et al. Analysis of HRTEM images for carbon nanostructure quantification. J Nanopart Res 6, 555–568 (2004). https://doi.org/10.1007/s11051-004-3724-6
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DOI: https://doi.org/10.1007/s11051-004-3724-6