Results of a study of the interaction between iron impurity and manganese and aluminum alloying elements during formation of phase composition in alloys of the Mg – Mn, Mg – Al, Mg – Al – Mn, and Mg – Al – Zn – Mn systems are presented. It is proved that this interaction results in introduction of Fe into the intermetallic phase. The phase compositions of model magnesium alloys and commercial alloys MA2-1 and MA5 are studied. It is shown that both manganese and aluminum may bind the iron impurity into phases. Composite Fe-containing intermetallic phases of different compositions influence differently the corrosion resistance of magnesium alloys.
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Notes
The phase compositions of the alloys were studied in cooperation with G. I. Morozova.
The electrochemical properties of the alloys were studied in cooperation with the co-authors of [15].
Here and below in the paper the content of elements is given in weight percent.
References
E. N. Kablov, “Materials and chemical technologies for aircraft engineering,” Vest. Ross. Akad. Nauk, 82(6), 520 – 530 (2012).
E. N. Kablov, “Innovation developments of FGUP “VIAM” GNTs RF aimed at implementation of the “Strategic Directions of Development of Materials and Processes of their Conversion for the Period until 2030,” Aviats. Mater. Tekhnol., 1(34), 3 – 33 (2015).
E. F. Kablov, “Advanced deformable alloys and composite materials based on magnesium,” Metalloved. Term. Obrab. Met., No. 11, 5 – 9 (2006).
I. S. Kornysheva, E. F. Volkova, E. S. Goncharenko, et al., “Prospects of application of magnesium and castable aluminum alloys,” Aviats. Mater. Tekhnol., No. S, 212 – 222 (2012).
E. N. Kablov, “Structural and functional materials – a base for economic and scientific and engineering development of Russia,” Vopr. Materialoved., No. 1, 64 – 6 (2006).
E. N. Kablov, O. G. Ovchinnikova, and A. K. Vershkov, “Rare metals and rare-earth elements: materials for recent and future high technologies,” Trudy VIAM, No. 2, Art. 01 (2013) (viam-works.ru).
V. A. Duyunova, E. S. Goncharenko, E. F. Volkova, et al., “Recent studies of magnesium and castable aluminum alloys at VIAM,” Tsvetn. Met., No. 9, 71 – 81 (2013).
E. F. Volkova, S. L. Sinebryukhov, S. V. Gnedenkov, and S. Ya. Betsofen, “Effect of deformation and heat treatment on the structure and properties of magnesium alloy MA5,” Metalloved. Term. Obrab. Met., No. 10, 55 – 59 (2012).
S. Ya. Betsofen, Yu. R. Kolobov, E. F. Volkova, et al., “Quantitative methods for estimation of the anisotropy of strength properties and phase composition of alloys of the Mg – Al system,” Deform. Razrush. Mater., No. 2, 2 – 9 (2014).
S. V. Gnedenkov, V. V. Antipov, E. F. Volkova, et al., “Structure and properties of coatings deposited by the method of plasma electrolytic oxidizing on aircraft magnesium alloys,” Aviats. Mater. Tekhnol., No. 2, 36 – 46 (2013).
M. A. Timonova, Protection of Magnesium Alloys from Corrosion [in Russian], Metallurgiya, Moscow (1977), pp. 5 – 46.
E. F. Volkova, “Microstructural & mechanical characterization of magnesium base alloy MA14 (ZK60A) under deformation & heat treatment,” in: Proc. 2014 Int. Conf. on High Performance and Optimum Design of Structures and Materials, WIT Press (2014), pp. 17 – 25.
E. F. Volkova, V. V. Antipov, and G. I. Morozova, “Special features of formation of structure and phase composition of deformable semiproducts from commercial alloy MA14,” Aviats. Mater. Tekhnol., No. 3, 8 – 15 (2011).
E. F. Volkova, “Some laws of formation of phase composition of a magnesium alloy of the Mg – Zn – Zr – Y system,” Metalloved. Term. Obrab. Met., No. 9, 22 – 28 (2013).
S. L. Sinebryukhov, M. V. Sidorova, R. F. Volkova, et al., “Protective oxide coatings on magnesium alloys of the Mg – Mn – Ce,Mg – Zn – Zr,Mg – Al – Zn – Mn,Mg – Zn – Zr – Y and Mg – Zr – Nd systems,” Fizikokhim. Poverkh. Zashch. Met., 48(6), 579 – 588 (2012).
M. B. Altman, M. E. Drits, M. A. Timonova, and M. V. Chukhrov (eds.), Magnesium Alloys, A Handbook, Part 1, Physical Metallurgy of Magnesium and its Alloys. Fields of Application [in Russian], Metallurgiya, Moscow (1978), pp. 23 – 112.
Phase Diagrams of Metallic Systems Based on Aluminum and Magnesium, A Handbook [in Russian], Nauka, Moscow (1977), pp. 138 – 139.
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Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 3, pp. 23 – 29, March, 2017.
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Volkova, E.F. Effect of Iron Impurity on the Phase Composition, Structure and Properties of Magnesium Alloys Containing Manganese and Aluminum. Met Sci Heat Treat 59, 154–160 (2017). https://doi.org/10.1007/s11041-017-0120-2
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DOI: https://doi.org/10.1007/s11041-017-0120-2