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Mesoporous epoxidized soybean oil-supported copper-based magnetic nanocatalyst and amberlite-supported azide as a green and efficient catalytic system for 1,2,3-triazole synthesis

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Abstract

A new green mesoporous magnetically heterogeneous catalyst was prepared by the copper immobilization onto magnetic epoxidized soybean oil as a nano bio-support and was utilized for the synthesis of 1,4-disubstituted-1,2,3-triazole derivatives in the presence of amberlite supported azide. A great range of triazole derivatives were synthesized from benzyl halides or epoxides halides in high yields at the room temperature. The catalyst was characterized by various techniques such as FT-IR, XRD, VSM, FE-SEM, EDX, TEM, BET, TGA, and ICP analysis. This catalytic system can be reused for five times without any significant decrease in the catalytic activity.

Graphical abstract

Fe3O4@SiO-ESBO/CuO nanocatalyst and amberlite supported azide as a green catalytic system has been used for the regioselective synthesis of triazole derivatives in water. A large range of triazole derivatives were synthesized from benzyl halides or epoxides in high yields.

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Acknowledgements

The authors would like to appreciate the research council of Shahrekord and Yazd University for their supports in accomplishment of this research.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Yazd University, Yazd, Iran

    S. Saeid Saei Dehkordi & Abbas Ali Jafari

  2. Department of Chemistry, Faculty of Science, Shahrekord University, Shahrekord, Iran

    Jalal Albadi & Heshmat Allah Samimi

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  1. S. Saeid Saei Dehkordi
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  2. Abbas Ali Jafari
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  3. Jalal Albadi
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Correspondence to Abbas Ali Jafari or Jalal Albadi.

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Dehkordi, S.S.S., Jafari, A.A., Albadi, J. et al. Mesoporous epoxidized soybean oil-supported copper-based magnetic nanocatalyst and amberlite-supported azide as a green and efficient catalytic system for 1,2,3-triazole synthesis. Mol Divers 27, 177–192 (2023). https://doi.org/10.1007/s11030-022-10408-6

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