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Thermodynamic Properties of R1233zd(E) Refrigerant: Method for Constructing the Fundamental Equation of State and Tabulated Data

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Abstract

The use of environmentally friendly refrigerants, such as R1233zd(E), in low-temperature technology as an alternative to the currently used refrigerants R245fa, R134a, R123 is considered. Substance R1233zd(E) - trans-1-chloro-3,3,3-trifluoro-1-propene - refers to fluorinated hydrocarbon compounds. To calculate the equilibrium characteristics (density, entropy, etc.) of this substance, a unified fundamental equation of state is proposed that satisfies a number of requirements: the asymmetric nature of the behavior of a real fluid relative to the critical isochore is taken into account in accordance with modern physics of critical phenomena; the transition of this equation to the virial equation of state in the rarefied gas region is realized; in a wide vicinity of the critical point is consistent with the Berestov scaling equation. Based on the proposed equation of state in the temperature range 195.15–450 K and pressure 0.1–100 MPa for R1233zd(E), thermodynamic tables of standard reference data were calculated in the single-phase region and on the saturation line, including density, entropy and enthalpy, sound speed , isochoric and isobaric heat capacities, as well as the heat of vaporization. In accordance with GOST 34100.3-2017/ISO/IEC Guide 98-3:2008 and the international methodology recommended for assessing the uncertainty of tabulated data, the uncertainties of the characteristic values in the specified standard tables were evaluated. A comparative analysis of the characteristics of R1233zd(E) calculated from the proposed equation of state with experimental and published data is performed.

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Authors and Affiliations

  1. All-Russian Research Institute of Metrological Service (VNIIMS), Moscow, Russia

    V. A. Kolobaev, P. V. Popov & A. D. Kozlov

  2. National Research University of Information Technologies, Mechanics, and Optics (ITMO University), St. Petersburg, Russia

    S. V. Rykov, I. V. Kudryavtseva & V. A. Rykov

  3. National Research University – Moscow Power Engineering Institute (MPEI), Moscow, Russia

    E. E. Ustyuzhanin

Authors
  1. V. A. Kolobaev
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  2. S. V. Rykov
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  3. I. V. Kudryavtseva
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  4. E. E. Ustyuzhanin
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  5. P. V. Popov
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  6. V. A. Rykov
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  7. A. D. Kozlov
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Correspondence to V. A. Kolobaev.

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Translated from Izmerit. Tekhn., No. 5, pp. 22-28, May, 2022.

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Kolobaev, V.A., Rykov, S.V., Kudryavtseva, I.V. et al. Thermodynamic Properties of R1233zd(E) Refrigerant: Method for Constructing the Fundamental Equation of State and Tabulated Data. Meas Tech 65, 330–338 (2022). https://doi.org/10.1007/s11018-022-02084-7

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