Skip to main content
Log in

Review of boundary lubrication mechanisms of DLC coatings used in mechanical applications

  • Published:
Meccanica Aims and scope Submit manuscript

Abstract

In the last ten years significant progress has been made on development and understanding of diamond-like carbon coatings (DLC), which enabled them to become one of the most promising types of protective coatings for various mechanical applications. Their main advantages are low friction, good anti-wear properties, and adhesive protection. However, due to their low surface energy their reactivity with conventional oils and additives is limited, which makes achieving effective boundary lubrication a complex task. For a qualitative step-change that would improve the performance and allow effective optimizing and tailoring of these boundary-lubricated tribological systems, it is necessary to understand the mechanisms of why, how, under which conditions, and with which materials and lubricants, the actual boundary lubrication is possible—if at all. The current results on boundary lubrication of DLC coatings are not many, and are due to the different types of coatings, lubricants and additives used in these studies, often difficult to compare and sometimes even contradictive. However, a recent great demand in different industries to apply the DLC coatings to lubricated systems requires a better understanding of these phenomena and overall performance. Therefore, if we wish to see a more effective continuation of the research and a better understanding of the scattered results, an overview of today’s state-of-the-art of lubricated DLC contacts is needed. In this paper we analyse the behaviors and suggested mechanisms from already-published studies and we summarize the present understanding of the boundary lubrication of DLC coatings. We focus on the DLC-lubricant interaction, thus we analyse only self-mated DLC/DLC contacts in order to avoid the inevitable effects from interactions with other counter materials such as steel.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Erdemir A (2004) Diamond-like carbon films. In: Vižintin J, Kalin M, Dohda K, Jahanmir S (eds) Tribology of mechanical systems: a guide to present and future technologies. ASME, New York, pp 139–156

    Google Scholar 

  2. Grill A (1999) Diamond-like carbon: state of the art. Diam Relat Mater 8:428–434

    Article  Google Scholar 

  3. Donnet C, Grill A (1997) Friction control of diamond-like carbon coatings. Surf Coat Technol 94–95:456–462

    Article  Google Scholar 

  4. Matthews A, Leyland A, Holmberg K, Ronkainen H (1998) Design aspects for advanced tribological surface coatings. Surf Coat Technol 100–101:1–6

    Article  Google Scholar 

  5. Erdemir A, Fenske GR, Terry J, Wilbur P (1997) Effect of source gas and deposition method on friction and wear performance of diamondlike carbon films. Surf Coat Technol 94–95:525–530

    Article  Google Scholar 

  6. Fontaine J, Donnet C, Grill A, Mogne TL (2001) Tribochemistry between hydrogen and diamond-like carbon films. Surf Coat Technol 146–147:286–291

    Article  Google Scholar 

  7. Andersson J, Erck RA, Erdemir A (2003) Friction of diamond-like carbon films in different atmospheres. Wear 254:1070–1075

    Article  Google Scholar 

  8. Franta D, Buršíková V, Nečas D, Zajíčková L (2008) Modeling of optical constants of diamond-like carbon. Diam Relat Mater 17:705–708

    Article  Google Scholar 

  9. Ronkainen H, Laukkanen A, Holmberg K (2007) Friction in a coated surface deformed by a sliding sphere. Wear 263:1315–1323

    Article  Google Scholar 

  10. Pantano A, Cappello F (2008) Numerical model for composite material with polymer matrix reinforced by carbon nanotubes. Meccanica 43:263–270

    Article  MATH  Google Scholar 

  11. Marannano G, Virzì Mariotti G (2008) Structural optimization and experimental analysis of composite material panels for naval use. Meccanica 43:251–262

    Article  MATH  Google Scholar 

  12. Robertson J (1999) Deposition and properties of diamond-like carbon. Mater Res Soc Symp Proc 555:12

    Google Scholar 

  13. Erdemir A (2001) The role of hydrogen in tribological properties of diamond-like carbon films. Surf Coat Technol 146–147:292–297

    Article  Google Scholar 

  14. Neuville S, Matthews A (2007) A perspective on the optimisation of hard carbon and related coatings for engineering applications. Thin Solid Films 515:6619–6653

    Article  ADS  Google Scholar 

  15. Ronkainen H, Varjus S, Koskinenm J, Holmberg K (2001) Differentiating the tribological performance of hydrogenated and hydrogen-free DLC coatings. Wear 249:260–266

    Article  Google Scholar 

  16. Kano M, Tanimoto I (1991) Wear mechanism of high wear-resistant materials for automotive valve trains. Wear 151:229–243

    Article  Google Scholar 

  17. Cruz R, Rao J, Rose T, Lawson K, Nicholls JR (2006) DLC-ceramic multilayers for automotive applications. Diam Relat Mater 15:2055–2060

    Article  Google Scholar 

  18. Franklin SE, Baranowska J (2007) Conditions affecting the sliding tribological performance of selected coatings for high vacuum bearing applications. Wear 263:1300–1305

    Article  Google Scholar 

  19. Vanhulsel A, Velasco F, Jacobs R, Eersels L, Havermans D, Roberts EW, Sherrington I, Anderson MJ, Gaillard L (2007) DLC solid lubricant coatings on ball bearings for space applications. Tribol Int 40:1186–1194

    Article  Google Scholar 

  20. Jiang JC, Meng WJ, Evans AG, Cooper CV (2003) Structure and mechanics of W-DLC coated spur gears. Surf Coat Technol 176:50–56

    Article  Google Scholar 

  21. Kalin M, Vižintin J (2005) The tribological performance of DLC-coated gears lubricated with biodegradable oil in various pinion/gear material combinations. Wear 259:1270–1280

    Article  Google Scholar 

  22. Tung SC, Gao H (2003) Tribological characteristics and surface interaction between piston ring coatings and a blend of energy-conserving oils and ethanol fuels. Wear 255:1276–1285

    Article  Google Scholar 

  23. Etsion I, Halperin G, Becker E (2006) The effect of various surface treatments on piston pin scuffing resistance. Wear 261:785–791

    Article  Google Scholar 

  24. Kano M (2006) Super low friction of DLC applied to engine cam follower lubricated with ester-containing oil. Tribol Int 39:1682–1685

    Article  Google Scholar 

  25. Hershberger J, Ozturk O, Ajayi JB, Woodford JB, Erdemir A, Erck RA, Fenske GR (2004) Evaluation of DLC coatings for spark-ignited direct-injected fuel systems. Surf Coat Technol 179:237–244

    Article  Google Scholar 

  26. Dai M, Zhou K, Yuan Z, Ding Q, Fu Z (2000) The cutting performance of diamond and DLC-coated cutting tools. Diam Relat Mater 9:1753–1757

    Article  Google Scholar 

  27. Sato T, Besshi T, Tsutsui I, Morimoto T (2000) Anti-galling property of a diamond-like carbon coated tool in aluminium sheet forming. J Mater Process Technol 104:21–24

    Article  Google Scholar 

  28. Sheeja D, Tay BK, Nung LN (2004) Feasibility of diamond-like carbon coatings for orthopaedic applications. Diam Relat Mater 13:184–190

    Article  Google Scholar 

  29. Shi B, Ajayi OO, Fenske G, Erdemir A, Liang H (2003) Tribological performance of some alternative bearing materials for artificial joints. Wear 255:1015–1021

    Article  Google Scholar 

  30. Tan AH (2007) Corrosion and tribological properties of ultra-thin DLC films with different nitrogen contents in magnetic recording media. Diam Relat Mater 16:467–472

    Article  Google Scholar 

  31. Zhao X, Bhushan B (2000) Comparison studies on degradation mechanisms of perfluoropolyether lubricants and model lubricants. Tribol Int 9:187–197

    Google Scholar 

  32. Gatzen HH, Beck M (2003) Tribological investigations on micromachined silicon sliders. Tribol Int 36:279–283

    Article  Google Scholar 

  33. Numata T, Nanao H, Mori S, Miyake S (2003) Chemical analysis of wear tracks on magnetic disks by TOF-SIMS. Tribol Int 36:305–309

    Article  Google Scholar 

  34. Gahlin R, Larsson M, Hedenqvist P (2001) ME-C:H coatings in motor vehicles. Wear 249:302–309

    Article  Google Scholar 

  35. Haque T, Morina A, Neville A, Kapadia R, Arrowsmith S (2007) Non-ferrous coating/lubricant interactions in tribological contacts: assessment of tribofilms. Tribol Int 40:1603–1612

    Article  Google Scholar 

  36. Dahotre NB, Nayak S (2005) Nanocoatings for engine application. Surf Coat Technol 194:58–67

    Article  Google Scholar 

  37. Erdemir A (2005) Review of engineered tribological interfaces for improved boundary lubrication. Tribol Int 38:249–256

    Article  Google Scholar 

  38. Hsu SM, Gates RS (2005) Boundary lubricating films: formation and lubrication mechanism. Tribol Int 38:305–312

    Article  Google Scholar 

  39. Sanchez-Lopez JC, Erdemir A, Donnet C, Rojas TC (2003) Friction-induced structural transformations of diamondlike carbon coatings under various atmospheres. Surf Coat Technol 163–164:444–450

    Article  Google Scholar 

  40. Grischke M, Hieke A, Morgenweck F, Dimigen H (1998) Variation of the wettability of DLC-coatings by network modification using silicon and oxygen. Diam Relat Mater 7:454–458

    Article  Google Scholar 

  41. Mortier RM, Orszulik ST (1993) Chemistry and technology of lubricants, 2nd edn. Blackie Academic Professional, Glasgow

    Google Scholar 

  42. Dorinson A, Ludema KC (1985) Mechanics and chemistry in lubrication. Tribology series, vol. 9. Elsevier, Amsterdam

    Book  Google Scholar 

  43. Pawlak Z (2003) Tribochemistry of lubricating oils. Tribology and interface engineering series, vol. 45. Elsevier, Amsterdam

    Google Scholar 

  44. De Barros’Bouchet MI, Martin JM, Le-Mogne T, Vacher B (2005) Boundary lubrication mechanisms of carbon coatings by MoDTC and ZDDP additives. Tribol Int 38:257–264

    Article  Google Scholar 

  45. De Barros’Bouchet MI, Le Mogne T, Martin JM, Vacher B (2006) Lubrication of carbon coatings with MoS2 single sheet formed by MoDTC and ZDDP lubricants. Lubr Sci 18:141–149

    Article  Google Scholar 

  46. Kano M, Yasuda Y, Okamoto Y, Mabuchi Y, Hamada T, Ueno T, Ye J, Konishi S, Takeshima S, Martin JM, De Barros Bouchet MI, Le Mogne T (2005) Ultralow friction of DLC in presence of glycerol mono-oleate (GMO). Tribol Lett 18:245–251

    Article  Google Scholar 

  47. Kalin M, Roman E, Vižintin J (2007) The effect of temperature on the tribological mechanisms and reactivity of hydrogenated, amorphous diamond-like carbon coatings under oil-lubricated conditions. Thin Solid Films 515:3644–3652

    Article  ADS  Google Scholar 

  48. Velkavrh I, Kalin M, Vižintin J (2008) The performance and mechanisms of DLC-coated surfaces in contact with steel in boundary-lubrication conditions—a review. J Mech Eng 54(3):189–206

    Google Scholar 

  49. Kalin M, Vižintin J (2006) A comparison of the tribological behavior of steel/steel, steel/DLC and DLC/DLC contacts when lubricated with mineral and biodegradable oils. Wear 261:22–31

    Article  Google Scholar 

  50. Barriga J, Kalin M, Van Acker K, Vercammen K, Ortega A, Leiaristi L (2006) Tribological performance of titanium doped and pure DLC coatings combined with a synthetic bio-lubricant. Wear 261:9–14

    Article  Google Scholar 

  51. Kalin M, Vižintin J, Barriga J, Vercammen K, Van Acker K, Arnšek A (2004) The effect of doping elements and oil additives on the tribological performance of boundary-lubricated DLC/DLC contacts. Tribol Lett 17:679–688

    Article  Google Scholar 

  52. Kalin M, Vižintin J, Vercammen K, Barriga J, Arnšek A (2006) The lubrication of DLC coatings with mineral and biodegradable oils having different polar and saturation characteristics. Surf Coat Technol 200:4515–4522

    Article  Google Scholar 

  53. Kalin M, Vižintin J (2006) The tribological performance of DLC coatings under oil-lubricated fretting conditions. Tribol Int 39:1060–1067

    Article  Google Scholar 

  54. Equey S, Roos S, Mueller U, Hauert R, Spencer ND, Crockett R (2007) Tribofilm formation from ZnDTP on diamond-like carbon. Wear 264(3–4):316–321

    Google Scholar 

  55. Podgornik B, Hren D, Vižintin J (2005) Low-friction behavior of boundary-lubricated diamond carbon coatings containing tungsten. Thin Solid Films 476:92–100

    Article  ADS  Google Scholar 

  56. Podgornik B, Hren D, Vižintin J, Jacobson S, Stavlid N, Hogmark S (2006) Combination of DLC coatings and EP additives for improved tribological behavior of boundary lubricated surfaces. Wear 261:32–40

    Article  Google Scholar 

  57. Matthews A, Rickerby DS (1991) Advanced surface coatings: a handbook of surface engineering. Blackie, Glasgow

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Kalin.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kalin, M., Velkavrh, I., Vižintin, J. et al. Review of boundary lubrication mechanisms of DLC coatings used in mechanical applications. Meccanica 43, 623–637 (2008). https://doi.org/10.1007/s11012-008-9149-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11012-008-9149-z

Keywords

Navigation