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Excess molar enthalpies of binary and ternary liquid mixtures

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Abstract

Excess molar enthalpies, \( H_{123}^{\text{E}} \) of ternary 1-ethyl-3-methylimidazolium tetrafluoroborate (1) + 2-methyl aniline (2) + aniline or N-methyl aniline (3); 1-ethyl-3-methylimidazolium tetrafluoroborate (1) + water (2) + formamide or N,N-dimethyl formamide (3) and H E of 2-methyl aniline (1) + aniline or N-methyl aniline (2); 1-ethyl-3-methylimidazolium tetrafluoroborate (1) + formamide (2) mixtures, have been measured at 298.15 K. The excess molar enthalpies, \( H_{123}^{\text{E}} \), are negative for 1-ethyl-3-methylimidazolium tetrafluoroborate (1) + 2-methyl aniline (2) + aniline or N-methyl aniline (3) mixtures and are positive for 1-ethyl-3-methylimidazolium tetrafluoroborate (1) + water (2) + formamide (3) mixture over entire composition of (1) and (2) components. However, the magnitude and sign of \( H_{123}^{\text{E}} \) value for 1-ethyl-3-methylimidazolium tetrafluoroborate (1) + water (2) + N,N-dimethyl formamide (3) mixture vary by the relative composition of the constituent molecules. The \( H_{123}^{\text{E}} \) and H E data have also been tested in terms of Graph and Prigogine–Flory–Patterson theories.

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References

  1. Du C, Cai D, Qin M, Zheng P, Hao Z, Yin T, Zhao J, Shen W. Thermodynamics of mixed surfactant solutions of N,N-bis(dimethyldodecyl)-1,2-ethanediammonium dibromide with 1-dodecyl-3-methylimidazolium bromide. J Phys Chem B. 2014;118:1168–79.

    Article  CAS  Google Scholar 

  2. Liu H, Yamashita T, Kamiyama T, Fujisawa M, Kimura T. Excess enthalpies of binary mixtures of ortho-, meta- and para-structural isomers. J Therm Anal Calorim. 2010;99:95–103.

    Article  CAS  Google Scholar 

  3. Wang YH, Gao H, Yan WD. Excess molar enthalpies of diethyl malonate + (methanol, + ethanol, +1-propanol, and +2-propanol) at T = (288.2, 298.2, 313.2, and 328.2) K and p = 101.3 kPa. J Chem Eng Data. 2010;55:381–4.

    Article  CAS  Google Scholar 

  4. Paduszyński K, Królikowski M, Domańska U. Excess enthalpies of mixing of piperidinium ionic liquids with short-chain alcohols: measurements and PC-SAFT modeling. J Phys Chem B. 2013;117:3884–91.

    Article  Google Scholar 

  5. Sharma VK, Kataria J, Bhagour S. Thermodynamic investigations of 1-ethyl-3-methylimidazolium tetrafluoroborate and cycloalkanone mixtures. J Therm Anal Calorim. 2014;118:431–47.

    Article  CAS  Google Scholar 

  6. Rebelo LPN, Najdanovic-Visak V, Visak ZP, Nunes da Ponte M, Szydlowski J, Cerdeiriña CA, Troncoso J, Romaní L, Esperança JMSS, Guedes HJR, de Sousa HCA. Detailed thermodynamic analysis of (C4mim)(BF4) + water as a case study to model ionic liquid aqueous solutions. Green Chem. 2004;6:369–81.

    Article  CAS  Google Scholar 

  7. Sharma VK, Solanki S. Topological investigations of binary mixtures containing 1-ethyl-3-methyl imidazolium tetrafluoroborate and anilines. J Mol Liq. 2013;177:133–44.

    Article  CAS  Google Scholar 

  8. Sharma VK, Solanki S, Bhagour S, Sharma D. Topological investigations of thermodynamic properties of ionic liquid mixtures: excess molar volumes and excess isentropic compressibilities. J Mol Liq. 2013;188:258–71.

    Article  CAS  Google Scholar 

  9. Sharma VK, Bhagour S. Molecular interactions in 1-ethyl-3-methyl imidazolium tetrafluoroborate + amide mixtures: excess molar volumes and excess isentropic compressibilities and excess molar enthalpies. J Solut Chem. 2013;42:800–22.

    Article  CAS  Google Scholar 

  10. Sharma VK, Bhagour S, Solanki S, Sharma D. Thermodynamic properties of ternary mixtures of 1-ethyl-3-methyl imidazolium tetrafluoroborate with 1-methyl pyrrolidin-2-one or pyrrolidin-2-one + water. Thermochim Acta. 2013;563:72–81.

    Article  CAS  Google Scholar 

  11. Zhang X, Chang R, Zhao Z. Measurement and prediction of excess molar enthalpies of ternary working solutions 1-butyl-3-methylimidazolium dibutylphosphate + methanol/ethanol + water. Huagong Xuebao/CIESC J. 2013;64:1520–5.

    CAS  Google Scholar 

  12. Zang XD, Yu J. Measurement and correlation of excess mole enthalpy of ternary working solutions l-ethyl-3-methylimidazolium dimethylphosphate + methanol/or ethanol + water. J Eng Thermophys. 2013;34:1004–7.

    Google Scholar 

  13. Sharma VK, Solanki S, Bhagour S, Sharma D. Excess molar enthalpies of ternary mixtures containing 1-ethyl-3-methylimidazolium tetrafluoroborate and organic solvents. Thermochim Acta. 2013;569:36–41.

    Article  CAS  Google Scholar 

  14. Sharma VK, Bhagour S, Solanki S, Sheetal S, Jangra SK. Excess molar enthalpies for [emim][BF4] + pyrrolidin-2-one or 1-methylpyrrolidin-2-one + pyridine or water mixtures. J Chem Thermodyn. 2014;68:235–43.

    Article  CAS  Google Scholar 

  15. Scholz E. Karl Fischer titration. Berlin: Springer-Verlag; 1984.

    Google Scholar 

  16. Riddick JA, Bunger WB, Sakano TK. Organic solvents physical properties and methods of purification. 4th ed. New York: Wiley; 1986.

    Google Scholar 

  17. Vogel AI. A text book of practical organic chemistry. 5th ed. London: English Book Society and Longman Group; 2003.

    Google Scholar 

  18. Saini N, Yadav JS, Jangra SK, Sharma D, Sharma VK. Thermodynamic studies of molecular interactions in mixtures of o-toulidine with pyridine and picolines: excess molar volumes, excess molar enthalpies, and excess isentropic compressibilities. J Chem Thermodyn. 2011;43:782–95.

    Article  CAS  Google Scholar 

  19. Dubey GP, Sharma M. Temperature and composition dependence of the densities, viscosities, and speeds of sound of binary liquid mixtures of 1-butanol with hexadecane and squalane. J Chem Eng Data. 2008;53:1032–8.

    Article  CAS  Google Scholar 

  20. Navia P, Troncoso J, Romani L. Excess magnitudes for ionic liquid binary mixtures with a common ion. J Chem Eng Data. 2007;52:1369–74.

    Article  CAS  Google Scholar 

  21. Stoppa A, Zech O, Kunz W, Buchner R. The conductivity of imidazolium based ionic liquids from (−35 to 195) °C. A variation of cation’s alkyl chain. J Chem Eng Data. 2010;55:1768–73.

    Article  CAS  Google Scholar 

  22. Neeti SK, Jangra SK, Yadav JS, Dimple N, Sharma VK. Thermodynamic investigations of ternary o-toluidine + tetrahydropyran + N,N-dimethyl formamide mixture and its binaries at 298.15, 303.15 and 308.15 K. J Mol Liq. 2011;163:36–45.

    Article  CAS  Google Scholar 

  23. Alonso I, Mozo I, Fuente IGDL, González JA, Cobos JC. Thermodynamics of ketone + amine mixtures. Part III. Volumetric and speed of sound data at (293.15, 298.15, and 303.15) K for 2-butanone +aniline, +N-methylaniline, or +pyridine systems. J Chem Eng Data. 2010;55:5400–5.

    Article  CAS  Google Scholar 

  24. Nakanishi K, Touhara H. Excess molar enthalpies of (methanol + aniline), (methanol + N-methylaniline), and (methanol + N,N-dimethylaniline). J Chem Thermodyn. 1986;18:657–60.

    Article  CAS  Google Scholar 

  25. Sharma VK, Kumar S. Excess isentropic compressibilities for 1,3-dioxolane or 1,4-dioxane + water + formamide or N,N-dimethyl formamide ternary mixtures at 308.15 K. J Solut Chem. 2005;34:713–30.

    Article  CAS  Google Scholar 

  26. García B, Alcalde R, Leal JM, Matos JS. Solute–solvent interactions in amide-water mixed solvents. J Phys Chem B. 1997;101:7991–7.

    Article  Google Scholar 

  27. Papamatthaiakis D, Aroni F, Havredaki V. Isentropic compressibilities of (amide + water) mixtures: a comparative study. J Chem Thermodyn. 2008;40:107–18.

    Article  CAS  Google Scholar 

  28. Murthy NM, Siva Kumar KV, Rajagopal E, Subrahmanyam SV. Excess thermodynamic and water-N,N-dimethylformamide. Acustica. 1981;48:341–5.

    CAS  Google Scholar 

  29. Sabbah R, Xu-wu An, Chickos JS, Leitão MLP, Roux MV, Torres LA. Reference materials for calorimetry and differential thermal analysis. Thermochim Acta. 1999;331:137.

    Google Scholar 

  30. Singh PP, Sharma PK, Maken S. Topology and thermodynamic investigations of molecular interactions in some lower amides + water mixtures. Indian J Chem. 1992;31A:619–25.

    CAS  Google Scholar 

  31. Huggins ML. The thermodynamic properties of liquids included solutions: Part 1. Intermolecular energies in mono atomic liquids and their mixtures. J Phys Chem. 1970;74:371–8.

    Article  CAS  Google Scholar 

  32. Huggins ML. The thermodynamic properties of liquids included solutions: Part 2. Polymer solutions considered as diatomic system. Polymer. 1971;12:389–99.

    Article  CAS  Google Scholar 

  33. Singh PP, Bhatia M. Energetic of molecular interactions in binary mixtures of non-electrolytes containing a salt. J Chem Soc Faraday Trans I. 1989;85:3807–12.

    Article  CAS  Google Scholar 

  34. Singh PP, Nigam RK, Singh KC, Sharma VK. Topological aspects of the thermodynamics of binary mixtures of non-electrolytes. Thermochim Acta. 1981;46:175–90.

    Article  CAS  Google Scholar 

  35. Yadav JS, Sharma D, Sharma VK. Topological investigations of thermodynamic properties of binary mixtures containing 2-pyrrolidinone. Thermochim Acta. 2009;489:45–52.

    Article  CAS  Google Scholar 

  36. Sharma VK, Siwach RK, Dimple S. Excess molar volumes, excess molar enthalpies, and excess isentropic compressibilities of tetrahydropyran with aromatic hydrocarbons tetrahydropyran with aromatic hydrocarbons. J Chem Thermodyn. 2011;43:39–46.

    Article  CAS  Google Scholar 

  37. Singh PP. Topological aspects of the effect of temperature and pressure on the thermodynamics of binary mixtures of non-electrolytes. Thermochim Acta. 1983;66:37–73.

    Article  CAS  Google Scholar 

  38. Kier LB, Yalkowasky SH, Sinkula AA, Valvan, SC. Physico-chemical properties of drugs (chap. 9). New York: Mercel Dekker; 1980, (a) p. 282, (b) p. 295.

  39. Van HT, Patterson D. Volume of mixing and P* effect: Part 1. Hexane isomers with normal and branched hexadecane. J Solut Chem. 1982;11:793–805.

    Article  Google Scholar 

  40. Flory PJ. The statistical thermodynamic of liquid mixtures. J Am Chem Soc. 1965;87:1833–8.

    Article  CAS  Google Scholar 

  41. Flory PJ. The thermodynamic properties of mixture of small non-polar molecules. J Am Chem Soc. 1965;87:1838–46.

    Article  Google Scholar 

  42. Sharma VK, Dua R. Topological and thermodynamic investigations of mixtures containing o-chlorotoluene and lower amides. J Chem Thermodyn. 2014;71:182–95.

    Article  CAS  Google Scholar 

  43. Hildebrand JH, Prausnitz JM, Scot RL. Regular and related solutions: the solubility of gases, liquids, and solids. New York: Van Nonstand Reinhelds; 1971.

    Google Scholar 

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Acknowledgements

Subhash Solanki is grateful to CSIR, New Delhi, India for the award of SRF. The authors are also grateful to the Head of Chemistry Department and authorities of M. D. University, Rohtak, for providing research facilities.

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  1. Department of Chemistry, M. D. University, Rohtak, 124001, Haryana, India

    V. K. Sharma, S. Solanki & S. Bhagour

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Correspondence to V. K. Sharma.

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Sharma, V.K., Solanki, S. & Bhagour, S. Excess molar enthalpies of binary and ternary liquid mixtures. J Therm Anal Calorim 119, 1293–1302 (2015). https://doi.org/10.1007/s10973-014-4286-1

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