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Dissolution properties of ammonium dinitramide in N-methyl pyrrolidone

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Abstract

The dissolution properties of ammonium dinitramide (ADN) in N-methyl pyrrolidone (NMP) were studied with a RD496-2000 Calvet microcalorimeter at four different temperatures under atmospheric pressure. The heat effects were determined for ADN in NMP. The molar enthalpies and the differential molar enthalpies for ADN in NMP were also obtained at the same time. The corresponding kinetic equations that describe the four dissolution processes are discussed.

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References

  1. Korobeinichev OP, Paletsky AA, Tereschenko AG, Volkov EN. Combustion of ammonium dinitramide/polycaprolactone propellants. Proc Combust Inst. 2002;29:2955–65.

    Article  CAS  Google Scholar 

  2. Venkatachalam S, Santosh G, Ninan K. An overview on the synthetic routes and properties of ammonium dinitramide (ADN) and other dinitramide salts. Propell Explos Pyrotech. 2004;3:178–87.

    Article  Google Scholar 

  3. Nagamachi MY, Oliveira JIS, Kawamoto AM, Dutra RCL. ADN—The new oxidizer around the corner for an environmentally friendly smokeless propellant. J Aerosp Technol Manag. 2009;1:153–60.

    Article  CAS  Google Scholar 

  4. Ostmark H, Bemm U, Bergman H, Langlet A. N-Guanylurea-dinitramide: a new energetic material with low sensitivity for propellants and explosives applications. Thermochim Acta. 2002;384:253–9.

    Article  CAS  Google Scholar 

  5. Pang WQ, Fan XZ, Zhang W, Xu HX, Wu SX, Liu FL, Xie WX, Yan N. Effect of ammonium dinitramide (ADN) on the characteristics of hydroxyl terminated polybutadiene (HTPB) based composite solid propellant. J Chem Sci Technol. 2013;2:53–60.

    Google Scholar 

  6. Zhao FQ, Yang D, Cai BY, Li SW. Advances in study of thermal decomposition of ammonium dinitramide and combustion of AND propellants. Chin J Energy Mater. 1999;7:149–51.

    CAS  Google Scholar 

  7. Amrousse R, Hori K, Fetimi W, Farhat K. HAN and ADN as liquid ionic monopropellants: thermal and catalytic decomposition processes. Appl Catal B. 2012;12:121–8.

    Article  Google Scholar 

  8. Tompa AS. Thermal analysis of ammonium dinitramide (ADN). Thermochim Acta. 2000;357–358:177–93.

    Article  Google Scholar 

  9. Sinditskii VP, Egorshev VY, Serushkin VV, Levshenkov AI, Berezin MV, Filatov SA, Smirnov SP. Evaluation of decomposition kinetics of energetic materials in the combustion wave. Thermochim Acta. 2009;496:1–12.

    Article  CAS  Google Scholar 

  10. Vyazovkin S, Wight CA. Model-free and model-fitting approaches to kinetic analysis of isothermal and nonisothermal data. Thermochim Acta. 1999;340–341:53–68.

    Article  Google Scholar 

  11. Zhu RS, Chen HL, Lin MC. Mechanism and kinetics for ammonium dinitramide (ADN) sublimation: a first-principles study. J Phys Chem A. 2012;116:10836–41.

    Article  CAS  Google Scholar 

  12. Nazeri GH, Mastour R, Fayaznia M, Keyghobadi P. Synthesis of ammonium dinitramide by nitration of potassium and ammonium sulfamate The effect of sulfamate conterion on ADN purity. Iran J Chem Chem Eng. 2008;27:85–9.

    CAS  Google Scholar 

  13. Mishraa IB, Russellb TP. Thermal stability of ammonium dinitramide. Thermochim Acta. 2002;384:47–56.

    Article  Google Scholar 

  14. Cui JH, Han JY, Wan JG, Huang R. Study on the crystal structure and hygroscopicity of ammonium dinitramide. J Chem Eng Data. 2010;55:3229–34.

    Article  CAS  Google Scholar 

  15. Santhosh G, Ghee AH. Synthesis and kinetic analysis of isothermal and non-isothermal decomposition of ammonium dinitramide prills. J Therm Anal Calorim. 2008;94:263–70.

    Article  CAS  Google Scholar 

  16. Brill TB, Brush PJ, Patil DG. Thermal decomposition of energetic materials chemistry of ammonium nitrate and ammonium dinitramide near the burning surface temperature. Combust Flame. 1993;92:178–86.

    Article  CAS  Google Scholar 

  17. Ostmark H, Bemm U, Langlet A, Sanden R, Wingborg N. The properties of ammonium dinitramide (ADN): part 1, basic properties and spectroscopic data. J Energy Mater. 2000;18:123–4.

    Article  CAS  Google Scholar 

  18. Venkatachalam S, Santhosh G, Ninan KN. An overview on the synthetic routes and properties of ammonium dinitramide (ADN) and other dinitramide salts. Propell Explos Pyrotech. 2004;29:178–87.

    Article  CAS  Google Scholar 

  19. Marthada VK. The enthalpy of solution of SRM 1655 (KCl) in H2O. J Res Nat Bur Stand. 1980;85:467–81.

    Article  Google Scholar 

  20. Xiao LB, Zhao FQ, Xing XL, Zhou ZM, Huang HF, Xu SY, Gao HX, Yao EG, Pei P. Thermochemical properties of hydrazinium dipicrylamine in N-methyl pyrrolidone and dimethyl sulfoxide. J Therm Anal Calorim. 2013;114:85–90.

    Article  CAS  Google Scholar 

  21. Xiao LB, Xing XL, Fan XZ, Zhao FQ, Zhou ZM, Huang HF, An T, Hao HX, Pei Q. Thermochemical properties of di(N,N-di(2,4,6-trinitrophenyl)amino)-ethylenediamine in dimethyl sulfoxide and N-methyl pyrrolidone. J Therm Anal Calorim. 2012;110:1431–6.

    Article  CAS  Google Scholar 

  22. Xue L, Zhao FQ, Xing XL, Zhou ZM, Wang K, Gao HX, Yi JH, Hu RZ. Dissolution of 3,4,5-triamino-1,2,4-triazole dinitramide in N-methyl pyrrolidone. J Chin Chem Soc. 2010;57:338–42.

    CAS  Google Scholar 

  23. Xing XL, Xue L, Zhao FQ, Gao HX, Hu RZ. Dissolution properties of 1,1-diamino-2,2-didinitrorthylene (FOX-7) in dimethyl sulfoxide (DMSO). Thermochim Acta. 2009;32:53–7.

    Google Scholar 

  24. Xiao LB, Xing XL, Zhao FQ, Xu KZ, Yao EG, Tan Y, Hao HX. Dissolution properties of 2(didinitromethylene)-5-methyl-1,3-diazacyclopentane in dimethyl sulfoxide and N-methyl pyrrolidone. Chem Res Chin Univ. 2012;28:743–6.

    CAS  Google Scholar 

  25. Xing XL, Xue L, Zhao FQ, Yi JH, Gao HX, Xu SY, Pei Q, Hao HX, Hu RZ. Dissolution properties of the CL-20 in ethyl acetate and acetone. J Therm Anal Calorim. 2010;99:703–7.

    Article  CAS  Google Scholar 

  26. Zhao FQ, Heng SY, Hu RZ, Gao HX, Han F. A study of kinetic behaviours of the effective centralite/stabilizer consumption reaction of propellants using a multi-temperature artificial accelerated aging test. J Hazard Mater. 2007;145:45–50.

    Article  CAS  Google Scholar 

  27. Blaine RL, Kissinger HE. Kissinger equation versus glass transition phenomenology. J Therm Anal Calorim. 2013;114:285–93.

    Article  Google Scholar 

  28. Xing XL, Zhao FQ, Ma SN, Xu SY, Xiao LB, Gao HX, Hu RZ. Thermal decomposition behavior, kinetics and thermal hazard evaluation of CMDB propellant containing CL-20 by microcalorimetry. J Therm Anal Calorim. 2012;110:1451–5.

    Article  CAS  Google Scholar 

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Acknowledgements

This work was financially supported by the Science and Technology Foundation of the Science and Technology on Combustion and Explosion Laboratory in China.

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Correspondence to Li-Bai Xiao.

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Xiao, LB., Zhao, FQ., Luo, Y. et al. Dissolution properties of ammonium dinitramide in N-methyl pyrrolidone. J Therm Anal Calorim 117, 517–521 (2014). https://doi.org/10.1007/s10973-014-3715-5

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  • DOI: https://doi.org/10.1007/s10973-014-3715-5

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