Abstract
Single crystal of l-asparagine monohydrate (LAM), organic nonlinear optical material has been grown by slow evaporation solution growth technique. Single crystal X-ray diffraction analysis was employed to identify the cell parameters. FT-IR analysis was used to estimate the qualitative presence of the amino acids in the grown crystal. Anisotropy properties like thermal and dielectric properties were studied on the grown crystal. The sample was thermally stable up to 125 °C. Also various thermodynamic properties were calculated and reported for the first time. Optical properties such as optical absorption, second harmonic generation, photoluminescence and photoconductivity analysis were also studied on the grown crystal. Optical absorption studies showed a lower UV cut-off of 225 nm. The SHG efficiency of the sample was seven times higher than that of KDP. Photoluminescence study confirms the suitability of the material for the generation of blue radiation. Multilayer plate-like pattern of growth was observed by scanning electron microscopy. The photoconductivity study confirms that the LAM crystal has negative photoconducting nature.
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Meredith GR. Nonlinear optical properties of organic and polymer materials. In: D. J. Williams editor. ACS Symposium Series. 1982;233:27.
Marder SR, Sohn JE, Stucky GD. Materials for nonlinear optics-chemical perspectives. Washington: American Chemical Society; 1991.
Nicoud JF, Twieg RJ. In: Chemla DS, Zyss J, editors. Nonlinear optical properties of organic molecules and crystals. London: Academic press; 1987.
Delfino M. A comprehensive optical second harmonic generation study of the non-centrosymmetric character of biological structures. Mol Cryst Liq Cryst. 1979;52:271–4.
Lund P. Nitrogen Metabolism in Mammalian. Appl Sci., Barking, 1981.
Rieckhoff KE, Peticolas WL. Optical second-harmonic generation in crystalline amino acids. Science. 1965;147:610–1.
Misoguti L, Varela AT, Nunes FD, Bagnato VS, Melo FEA, Zilio SC, Mendes Filho. Optical properties of l-alanine organic crystals. Opt Mater. 1996;6:147–52.
Ramesh Kumar G, Gokul Raj S, Mohan R, Jayavel R. influence of isoelectric ph on the growth, linear and nonlinear optical and dielectric properties of l-threonine single crystals. Cryst Growth Des. 2005;6:1308.
Aruna S, Bhagavannarayana G, Palanisamy M, Thomas PC, Varghese B, Sagayaraj P. Growth, morphological, mechanical and dielectric studies of semi organic NLO single crystal: L-argininium perchlorate. J Cryst Growth. 2007;300:403–8.
Yogam F, Vetha Potheher I, Vimalan M, Jeyasekaran R, Rajesh Kumar T, Sagayaraj P. Growth and physicochemical properties of L-phenylalaninium maleate: a novel nonlinear optical crystal. Spectrochim Acta, Part A. 2012;95:369–73.
Alosious Gonsago C, Albert Helen Merina, Umamaheswari R, Joseph Arul Pragasam A. Spectral, optical, and thermal studies of pure and Zn(II)-doped l-histidine hydrochloride monohydrate (LHHC) crystals. J Therm Anal Calorim. 2012;110:839–45.
Suriya Kumar K, Gokul Raj S, Ramesh Kumar G, Mohan R. Determination of second order nonlinear optical entities for l-alanine single crystals using semi-classical anharmonic oscillator model. Optik. 2011;122:63–4.
Malliga P, Alosious Gonsago C, Sagayaraj P, Joseph Arul Pragasam A. Crystal growth, spectral, optical, and thermal characterization of glycyl-l-alanine hydrochloride (GLAH) single crystal. J Therm Anal Calorim. 2012;110:873–8.
Yariv A. Quantum electronics. 3rd ed. New York: Wiley; 1989.
Kelly JF, Gallagher A. Efficient electro-optic modulator for optical pumping of Na beams. Rev Sci Instrum. 1987;58:563–6.
Ramanadham M, Sikka SK, Chidambaram R. Structure of l-asparagine Monohydrate by neutron diffraction. Acta Crystallogr. 1972;B28:3000–5.
Verbist Jaques J, Lehmann Mogens S, Koetzle Thomas F, Hamilton Walter C. Precision neutron diffraction structure determination of protein and nucleic acid components VI. The crystal and molecular structure of the amino acid l-asparagine monohydrate. Acta Crystallogr B. 1972;28:3006–13.
Neacsu A, Contineanu I, Popa VT, Contineanu M. Dehydration of irradiated and non-irradiated L-α-asparagine monohydrate. J Therm Anal Calorim. 2008;94:405.
Kurtz SK, Perry TT. A powder technique for the evaluation of nonlinear optical materials. J Appl Phys. 1968;39:3798–4013.
Shakir Mohd, Riscob B, Maurya KK, Ganesh V, Wahab MA, Bhagavannarayana G. Unidirectional growth of l-asparagine monohydrate single crystal: first time observation of NLO nature and other studies of crystalline perfection, optical, mechanical and dielectric properties. J Cryst Growth. 2010;312:3171–7.
Ishwar Bhat S, Mohan Rao P, Upadyaya V, Nagaraja HS. Growth and characterization of a new nonlinear optical mixed borate crystal. J Cryst Growth. 2002;236:2–318.
Balarew C, Dushlew R. Application of the hard and soft acids and bases concept to explain ligand coordination in double salt structures. J Solid State Chem. 1984;55:1.
Rao KV, Smakula A. Dielectric properties of cobalt oxide, nickel oxide and their mixed crystals. J Appl Phys. 1965;36:2031–8.
Pathinettam Padiyan D, John Ethilton S, Paulraj K. Protonic conductivity and photoconductivity studies on H3PW12O40·21H2O single crystals. Cryst Res Technol. 2000;35:4–87.
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Yogam, F., Vetha Potheher, I., Jeyasekaran, R. et al. Growth, thermal, and optical properties of l-asparagine monohydrate NLO single crystal. J Therm Anal Calorim 114, 1153–1159 (2013). https://doi.org/10.1007/s10973-013-3138-8
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DOI: https://doi.org/10.1007/s10973-013-3138-8