Abstract
In this study, a theoretical work on magnetocaloric properties of ceramic and sol–gel La0.67Ca0.33MnO3 samples was presented. The value of the magnetocaloric effect has been determined from theoretical work on magnetization as a function of temperature. It is showed that ceramic sample shows better magnetocaloric properties than the sol–gel one. Though the maximum magnetic entropy change ∆S M of ceramic sample upon 5 kOe applied field variation which is about 76 % of that of a pure Gd metal upon 5 kOe, ∆S M distribution of the La0.67Ca0.33MnO3 is much more uniform than that of Gd. This feature is desirable for an Ericson-cycle magnetic refrigerator.
Similar content being viewed by others
References
Oliveira NA, Ranke PJ. Theoretical aspects of the magnetocaloric effect. Phys Rep. 2010;489:89.
Gschneidner KA, Pecharsky VK, Tsoko AO. Recent developments in magnetocaloric materials. Rep Prog Phys. 2005;68:1479.
Hamad MA. Magnetocaloric effect in polycrystalline Gd1-xCaxBaCo2O5.5. Mater Lett. 2012. doi:10.1016/j.matlet.2012.05.088.
Hamad MA. Calculation on electrocaloric properties of ferroelectric SrBi2Ta2O9. Phase Transition. 2012;85:159–68.
Mischenko AS, Zhang Q, Scott JF, Whatmore RW, Marhur ND. Giant electrocaloric effect in thin-film PbZr0. 95Ti0. 05O3. Science. 2006;311:1270.
Hamad MA. Investigations on electrocaloric properties of [111]-oriented 0.955PbZn1/3Nb2/3O3–0.045PbTiO3 single crystals. Phase Transitions. 2012. doi:10.1080/01411594.2012.674527.
Hamad MA. Detecting giant electrocaloric effect in Sr x Ba1−x Nb2O6 single crystals. Appl Phys Lett. 2012;100:192908.
Tocado L, Palacios E, Burriel R. Adiabatic measurement of the giant magnetocaloric effect in MnAs. J Therm Anal Calorim. 2006;84:213–7.
Zimm C, Jastrab A, Sternberg A, Pecharsky VK, Gschneidner KA, Osborne M, Anderson I. Description and performance of a near-room temperature magnetic refrigerator. Adv Cryog Eng. 1998;43:1759.
Hamad MA. Prediction of energy loss of Ni0.58Zn0.42Fe2O4 nanocrystalline and Fe3O4 nanowire arrays. Jpn J Appl Phys. 2010;49:085004.
Manoharan SS, Kumar D, Hegde MS, Satyalakshmi KM, Prasad V, Subramanyam SV. Giant magnetoresistance in self-doped La1−x MnO3−δ thin films. J Solid State Chem. 1995;117:420.
Banerjee S, Kumar A, Devi PS. Preparation of nanoparticles of oxides by the citrate–nitrate process. J Therm Anal Calorim. 2011;104:859–67.
Hamad MA. Prediction of thermomagnetic properties of La0.67Ca0.33MnO3 and La0.67Sr0.33MnO3. Phase Transition. 2012;85:106–12.
Phan MH, Yu SC. Review of the magnetocaloric effect in manganite materials. J Magn Magn Mater. 2007;308:325–40.
Jacob KT, Attaluri M. Refinement of thermodynamic data for LaMnO3. J Mater Chem. 2003;13:934–42.
Gupta A, McGuire TR, Duncombe PR, Rupp M, Sun JZ, Gallagher WJ, Xiao G. Growth and giant magnetoresistance properties of La-deficient LaMnO (0.67 ≤ x ≤ 1) films. Appl Phys Lett. 1995;67:3494.
Dan’kov SY, Tishin AM, Pecharsky VK, Gschneidner KA. Magnetic phase transitions and the magnetothermal properties of gadolinium. Phys Rev B. 1998;57:3478.
Pecharsky VK, Gschneidner KA. Magnetocaloric effect and magnetic refrigeration. J Magn Magn Mater. 1999;200:44.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Hamad, M.A. Theoretical work on magnetocaloric effect in ceramic and sol–gel La0.67Ca0.33MnO3 . J Therm Anal Calorim 111, 1251–1254 (2013). https://doi.org/10.1007/s10973-012-2505-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10973-012-2505-1