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Physical–chemical and catalytic properties of deposited MoO3 and V2O5

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Abstract

The deposition of molybdenum and vanadium oxides onto fumed silica, titania, and alumina as supports through dry milling has been carried out. The structure of prepared compositions has been investigated by means of XRD, DTA–TG, FTIR, and UV–Vis spectroscopy, nitrogen adsorption. The deposited crystal phases are sufficiently uniformly distributed on support surface. The supported oxides are subjected to dispersion in process of milling to the state of oligomeric or isolated species. Milled bulk and deposited MoO3 (first of all, on alumina) possesses improved catalytic performance in process of epoxidation of 1-octene. Vanadium pentoxide also has higher activity in this process.

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Acknowledgements

This paper (work) was supported by the European Community under a Marie Curie International Research Staff Exchange Scheme (IRSES), Project No 230790

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Authors and Affiliations

  1. Institute for Sorption and Problems of Endoecology NAS of Ukraine, 13 Naumov Str., 03164, Kyiv, Ukraine

    V. Sydorchuk, S. Khalameida & V. Zazhigalov

  2. Institute of Chemistry and Chemical Technologies, L’viv National Polytechnic University, 12 Stepan Bandera Str., 79013, L’viv, Ukraine

    O. Makota & L. Bulgakova

  3. Faculty of Chemistry, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Sq. 3, 20-031, Lublin, Poland

    J. Skubiszewska-Zięba & R. Leboda

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  1. V. Sydorchuk
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  2. O. Makota
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  3. S. Khalameida
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  4. L. Bulgakova
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  5. J. Skubiszewska-Zięba
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  6. R. Leboda
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  7. V. Zazhigalov
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Correspondence to V. Sydorchuk.

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Sydorchuk, V., Makota, O., Khalameida, S. et al. Physical–chemical and catalytic properties of deposited MoO3 and V2O5 . J Therm Anal Calorim 108, 1001–1008 (2012). https://doi.org/10.1007/s10973-011-1895-9

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  • DOI: https://doi.org/10.1007/s10973-011-1895-9

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