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Stabilization effect of potential antioxidants on the thermooxidative stability of styrene–butadiene rubber

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Abstract

Effects of several heterocyclic compounds containing nitrogen, trisubstituted amines and diamines and molecules based on N,N,N′,N′,N′′,N′′-substituted-[1,3,5]triazine-2,4,6-triamine in preventing thermooxidative degradation of styrene–butadiene rubber (SBR) have been studied using non-isothermal DSC measurements. The aim of this study was to determine and compare the stabilizing effect of individual compounds and to select the structures with the best antioxidative properties. In order to compare the stabilizing effect of the compounds, induction periods and protection factors have been calculated. The treatment of the experimental data was carried out using a method based on a non-Arrhenian temperature function. The results show that better antioxidative properties can be assigned to heterocyclic compounds. On the other hand, molecules containing triazine structures exhibited only negligible stabilizing effect on SBR at lower temperatures and even destabilizing effect at higher temperatures.

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Acknowledgements

This study was supported by the Slovak Research and Development Agency under the contract No. APVV-0446-07.

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Authors and Affiliations

  1. Faculty of Chemical and Food Technology, Institute of Physical Chemistry and Chemical Physics, Slovak University of Technology, Radlinského 9, 812 37, Bratislava, Slovak Republic

    Zuzana Cibulková, Andrea Černá & Peter Šimon

  2. Research Institute of Chemical Technology (VUCHT a.s.), Nobelova 34, 836 03, Bratislava, Slovak Republic

    Ján Uhlár, Karol Kosár & Peter Lehocký

Authors
  1. Zuzana Cibulková
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  2. Andrea Černá
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  3. Peter Šimon
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  4. Ján Uhlár
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  5. Karol Kosár
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  6. Peter Lehocký
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Correspondence to Zuzana Cibulková.

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Cibulková, Z., Černá, A., Šimon, P. et al. Stabilization effect of potential antioxidants on the thermooxidative stability of styrene–butadiene rubber. J Therm Anal Calorim 105, 607–613 (2011). https://doi.org/10.1007/s10973-011-1322-2

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  • DOI: https://doi.org/10.1007/s10973-011-1322-2

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