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Heat capacities and thermodynamic properties of MgNDC

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Abstract

One-three-dimensional metal-organic frameworks Mg1.5(C12H6O4)1.5(C3H7NO)2 (MgNDC) has been synthesized solvothermally and characterized by single crystal XRD, powder XRD, FT-IR spectra. The low-temperature molar heat capacities of MgNDC were measured by temperature modulated differential scanning calorimetry (TMDSC) over the temperature range from 205 to 470 K for the first time. No phase transition or thermal anomaly was observed in the experimental temperature range. The thermodynamic parameters of MgNDC such as entropy and enthalpy relative to reference temperature of 298.15 K were derived based on the above molar heat capacities data. Moreover, the thermal stability and decomposition of MgNDC was further investigated through thermogravimetry (TG)–mass spectrometer (MS). Three stages of mass loss were observed in the TG curve. TG–MS curve indicated that the oxidative degradation products of MgNDC are mainly H2O, CO2, NO, and NO2.

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Acknowledgements

The authors gratefully acknowledge the financial support for this work from the National Natural Science Foundation of China (No. 20833009, 20873148, 20903095, 50901070 and U0734005), the National Basic Research Program (973 program) of China (2010CB631303), IUPAC (Project No. 2008-006-3-100), and the State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology (Grant No. KFJJ10-1Z).

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Authors and Affiliations

  1. Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian, 116023, People’s Republic of China

    Li-Fang Song, Cheng-Li Jiao, Chun-Hong Jiang, Jian Zhang & Li-Xian Sun

  2. Graduate School of the Chinese Academy of Sciences, Beijing, 100049, People’s Republic of China

    Li-Fang Song, Cheng-Li Jiao, Chun-Hong Jiang & Fen Li

  3. Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, People’s Republic of China

    Fen Xu, Qing-Zhu Jiao & Yong-Heng Xing

  4. State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing, 100081, People’s Republic of China

    F. L. Huang

  5. State Key Laboratory of Powder Metallurgy, Central South University, Changsha, 410083, People’s Republic of China

    Yong Du

  6. College of Chemistry and Biological Engineering, Changsha University of Science and Technology, Changsha, 410076, People’s Republic of China

    Zhong Cao

  7. Laboratory of Materials Modification by Laser, Electron, and Ion Beams, Dalian University of Technology, Dalian, 116024, China

    Jijun Zhao

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  1. Li-Fang Song
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  2. Cheng-Li Jiao
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  3. Chun-Hong Jiang
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  4. Jian Zhang
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  5. Li-Xian Sun
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  6. Fen Xu
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  7. Qing-Zhu Jiao
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  8. Yong-Heng Xing
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  9. F. L. Huang
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  10. Yong Du
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  11. Zhong Cao
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  12. Fen Li
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  13. Jijun Zhao
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Correspondence to Li-Xian Sun or Fen Xu.

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Song, LF., Jiao, CL., Jiang, CH. et al. Heat capacities and thermodynamic properties of MgNDC. J Therm Anal Calorim 103, 365–372 (2011). https://doi.org/10.1007/s10973-010-0777-x

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  • DOI: https://doi.org/10.1007/s10973-010-0777-x

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