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Synthesis of cobalt nickel ferrite nanoparticles via autocatalytic decomposition of the precursor

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Abstract

The chemistry, structure, and properties of spinel ferrites are largely governed by the method of preparation. The metal carboxylato-hydrazinate precursors are known to yield nanosized oxides at a comparatively lower temperature. In this study, we are reporting the synthesis of one such precursor, cobalt nickel ferrous fumarato-hydrazinate which decomposes autocatalytically to give cobalt nickel ferrite nanoparticles. The XRD study of this decomposed product confirms the formation of single-phase spinel, i.e., Co0.5Ni0.5Fe2O4. The thermal decomposition of the precursor has been studied by isothermal, thermogravimetric (TG), and differential scanning calorimetric (DSC) analysis. The precursor has also been characterized by FTIR, EDX, and chemical analysis, and its chemical composition has been determined as Co0.5Ni0.5Fe2(C4H2O4)3·6N2H4.

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References

  1. Patil KC, Hegde MS, Rattan T, Aruna ST. Chemistry of nanocrystalline oxide materials: combustion synthesis, properties and applications. Singapore: World Scientific; 2008.

    Book  Google Scholar 

  2. Maensiri S, Masingboon C, Boonchom B, Seraphin S. Scr Mater. 2007;56(9):797.

    Article  CAS  Google Scholar 

  3. Thakur S, Katyal SC, Singh M. J Magn Magn Mat. 2009;321:1.

    Article  CAS  Google Scholar 

  4. Chen Z, Gao L. Mater Sci Eng B. 2007;141:82.

    Article  CAS  Google Scholar 

  5. Vital A, Angermann A, Dittmann R, Graule T, Topfer J. Acta Mater. 2007;55:1955.

    Article  CAS  Google Scholar 

  6. Hua ZH, Chen RS, Li CL, Yang SG, Lu M, Gu XB, et al. J Alloys Compd. 2007;427:199.

    Article  CAS  Google Scholar 

  7. Singhal S, Singh J, Barthwal SK, Chandra K. J Solid State Chem. 2005;178:3183.

    Article  CAS  Google Scholar 

  8. Baykal A, Kasapoglu N, Koseoglu Y, Basaran AC, Kavas H, Toprak MS. Cent Eur J Chem. 2008;6(1):125.

    Article  CAS  Google Scholar 

  9. Kasapoglu N, Birsoz B, Baykal A, Koseoglu Y, Toprak MS. Cent Eur J Chem. 2007;5(2):570.

    Article  CAS  Google Scholar 

  10. Shobana MK, Rajendran V, Jeyasubramanian K, Suresh Kumar N. Mater Lett. 2007;61:2616.

    Article  CAS  Google Scholar 

  11. Ryu BH, Chang HJ, Choi YM, Kong KJ, Lee JO, Kim CG, et al. Phys Status Solidi a. 2004;201(8):1855.

    Article  CAS  Google Scholar 

  12. Jiang J. Mater Lett. 2007;61:3239.

    Article  CAS  Google Scholar 

  13. Verenkar VMS, Rane KS. In: Dharwadkar SR, Bharadwaj SR, Mukherjee SK, Sood DD, editors. Proc. 10th Nat. Symp. on Thermal Analysis, DMSRDE; Kanpur. Mumbai: Indian Thermal Analysis Society; 1995. p. 175.

  14. Verenkar VMS, Rane KS. In: Ravindran PV, Sudersanan M, Misra NL, Venugopal V, editors. Proc. 12th Nat. Symp. on Thermal Analysis, Gorakhpur, India. Mumbai: Indian Thermal Analysis Society; 2000. p. 194.

  15. Sawant SY, Verenkar VMS, Mojumdar SC. J Therm Anal Calorim. 2007;90:669.

    Article  CAS  Google Scholar 

  16. More A, Verenkar VMS, Mojumdar SC. J Therm Anal Calorim. 2008;94(1):63.

    Article  CAS  Google Scholar 

  17. Gonsalves LR, Verenkar VMS, Mojumdar SC. J Therm Anal Calorim. 2009;96(1):53.

    Article  CAS  Google Scholar 

  18. Porob RA, Khan SZ, Mojumdar SC, Verenkar VMS. J Therm Anal Calorim. 2006;86:605.

    Article  CAS  Google Scholar 

  19. More A, Mojumdar SC, Parab S, Verenkar VMS. 15th CTAS Annual Workshop and Exhibition, 17–18 May 2005. National Research Council Canada, Bouchervile, Quebec, J4B 6Y4, Canada. p. 22.

  20. Sawant SY, Kannan KR, Verenkar VMS. In: Pillai CGS, Ramakumar KL, Ravindran PV, Venugopal V, editors. Proc. 13th Nat. Symp. on Thermal Analysis, B.A.R.C., Mumbai. Mumbai: Indian Thermal Analysis Society; 2002. p. 154.

  21. Verenkar VMS, Rane KS. In: Dharwadkar SR, Bharadwaj SR, Mukherjee SK, Sood DD, editors. Proc. 10th Nat. Symp. on Thermal Analysis, DMSRDE; Kanpur. Mumbai: Indian Thermal Analysis Society; 1995. p. 171.

  22. Rane KS, Verenkar VMS, Sawant PY. J Mater Sci Mater Electron. 1999;10:133.

    Article  CAS  Google Scholar 

  23. Xie W, Gao Z, Liu K, Pan WP, Vaia R, Hunter D, et al. Thermochim Acta. 2001;367:339.

    Article  Google Scholar 

  24. Mojumdar SC. Res J Chem Environ. 2005;9:23.

    CAS  Google Scholar 

  25. Davis RD, Gilman JW, Sutto T, Callahan JH, Trulove PC, De Long H. Clays Clay Miner. 2004;52:171.

    Article  CAS  Google Scholar 

  26. Ovadyahu D, Lapides I, Yariv S. J Therm Anal Calorim. 2007;87:125.

    Article  CAS  Google Scholar 

  27. Mojumdar SC. J Therm Anal Calorim. 2001;64:629.

    Article  CAS  Google Scholar 

  28. Czakis-Sulikowska D, Czylkowska A, Malinowska A. J Therm Anal Calorim. 2002;67:667.

    Article  CAS  Google Scholar 

  29. Mojumdar SC, Raki L. J Therm Anal Calorim. 2006;85:99.

    Article  CAS  Google Scholar 

  30. Bylina I, Trevani L, Mojumdar SC, Tremaine P, Papangelakis VG. J Therm Anal Calorim. 2009;96:117.

    Article  CAS  Google Scholar 

  31. Mojumdar SC, Varshney KG, Agrawal A. Res J Chem Environ. 2006;10:89.

    CAS  Google Scholar 

  32. Dováľ M, Palou M, Mojumdar SC. J Therm Anal Calorim. 2006;86:595.

    Article  Google Scholar 

  33. Madhurambal G, Ramasamy P, Srinivasan PA, Mojumdar SC. J Therm Anal Calorim. 2007;90:673.

    Article  CAS  Google Scholar 

  34. Varshney KG, Agrawal A, Mojumdar SC. J Therm Anal Calorim. 2007;90:731.

    Article  CAS  Google Scholar 

  35. Mojumdar SC, Melník M, Jóna E. J Anal Appl Pyrolysis. 2000;53:149.

    Article  CAS  Google Scholar 

  36. Borah B, Wood JL. Can J Chem. 1976;50:2470.

    Article  Google Scholar 

  37. Mojumdar SC, Sain M, Prasad R, Sun L, Venart JES. J Therm Anal Calorim. 2007;90:653.

    Article  CAS  Google Scholar 

  38. Ramadevi A, Srinivasan K. Res J Chem Environ. 2005;9:54.

    CAS  Google Scholar 

  39. Meenakshisundaram S, Parthiban S, Madhurambal G, Mojumdar SC. J Therm Anal Calorim. 2008;94:21.

    Article  CAS  Google Scholar 

  40. Skoršepa JS, Györyová K, Melník M. J Therm Anal. 1995;44:169.

    Article  Google Scholar 

  41. Ondrušová D, Jóna E, Šimon P. J Therm Anal Calorim. 2002;67:147.

    Article  Google Scholar 

  42. Verma RK, Verma L, Ranjan M, Verma BP, Mojumdar SC. J Therm Anal Calorim. 2008;94:27.

    Article  CAS  Google Scholar 

  43. Jona E, Rudinska E, Sapietova M, Pajtasova M, Ondrusova D. Res J Chem Environ. 2006;10:31.

    CAS  Google Scholar 

  44. Kubranová M, Jóna E, Rudinská E, Nemčeková K, Ondrušová D, Pajtášová M. J Therm Anal Calorim. 2003;74:251.

    Article  Google Scholar 

  45. Jóna E, Hvastijová M, Kohout J. J Therm Anal. 1994;41:161.

    Article  Google Scholar 

  46. Czakis-Sulikowska D, Czylkowska A. J Therm Anal Calorim. 2003;71:395.

    Article  CAS  Google Scholar 

  47. Madhurambal G, Ramasamy P, Anbusrinivasan P, Vasudevan G, Kavitha S, Mojumdar SC. J Therm Anal Calorim. 2008;94:59.

    Article  CAS  Google Scholar 

  48. Ukraintseva EA, Logvinenko VA, Soldatov DV, Chingina TA. J Therm Anal Calorim. 2004;75:337.

    Article  CAS  Google Scholar 

  49. Mojumdar SC, Melník M, Jóna E. J Therm Anal Calorim. 1999;56:541.

    Article  CAS  Google Scholar 

  50. Rathore HS, Varshney G, Mojumdar SC, Saleh MT. J Therm Anal Calorim. 2007;90:681.

    Article  CAS  Google Scholar 

  51. Mojumdar SC, Madhurambal G, Saleh MT. J Therm Anal Calorim. 2005;81:205.

    Article  CAS  Google Scholar 

  52. Varshney KG, Agrawal A, Mojumdar SC. J Therm Anal Calorim. 2005;81:183.

    Article  CAS  Google Scholar 

  53. Mojumdar SC, Šimon P, Krutošíková A. J Therm Anal Calorim. 2009;96:103.

    Article  CAS  Google Scholar 

  54. Jóna E, Rudinská E, Sapietová M, Pajtášová M, Ondrušová D, Jorík V, et al. Res J Chem Environ. 2005;9:41.

    Google Scholar 

  55. Mojumdar SC, Miklovic J, Krutošíková A, Valigura D, Stewart JM. J Therm Anal Calorim. 2005;81:211.

    Article  CAS  Google Scholar 

  56. Vogel I. Vogel’s text book. In: Jeffery GH, Bassett J, Mendham J, Denney RC, editors. Quantitative inorganic analysis, 5th ed. London, UK: Longman Scientific and Technical; 1989, p.1–906.

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Goa University, Taleigao Plateau, Goa, 403206, India

    L. R. Gonsalves & V. M. S. Verenkar

  2. Department of Engineering, University of New Brunswick, Saint John, NB, E2L 4L5, Canada

    S. C. Mojumdar

Authors
  1. L. R. Gonsalves
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  2. S. C. Mojumdar
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  3. V. M. S. Verenkar
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Correspondence to S. C. Mojumdar.

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Gonsalves, L.R., Mojumdar, S.C. & Verenkar, V.M.S. Synthesis of cobalt nickel ferrite nanoparticles via autocatalytic decomposition of the precursor. J Therm Anal Calorim 100, 789–792 (2010). https://doi.org/10.1007/s10973-010-0719-7

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