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Alanine- and taurine-salicylal Schiff base complexes of magnesium

Synthesis, characterization and thermal decomposition

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Abstract

The complexes of α-alanine-salicylal Schiff base of magnesium (α-ASSM), β-alanine-salicylal Schiff base of magnesium (β-ASSM) and taurine-salicylal Schiff base of magnesium (TSSM) were synthesized. The formulae of the complexes are Mg[OC6H4CHNCH(CH3)COO]·2H2O, Mg[OC6H4CHNCH2CH2COO]·2H2O and Mg[OC6H4CHNCH2CH2SO3]·2H2O. The crystal structure belongs to orthorhombic system with the lattice parameters: a=1.6954 nm, b=2.0873 nm and c=2.3037 nm for the β-ASSM, to orthorhombic system with the lattice parameters: a=1.5586 nm, b=1.8510 nm and c=2.6240 nm for the β-ASSM, to monoclinic system with the lattice parameters: a=1.3232 nm, b=1.4960 nm, c=2.1543 nm and β=98.04° for the TSSM, respectively. The results of the thermal decomposition processes and infrared spectra of the complexes show that the complexes may possess different coordination structures.

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Authors and Affiliations

  1. Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai, 200237, P.R. China

    S. R. Luan & Y. H. Zhu

  2. Research Center of Analysis and Test, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai, 200237, P.R. China

    S. R. Luan

  3. Department of Chemistry, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai, 200237, P.R. China

    Y. Q. Jia

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  1. S. R. Luan
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  2. Y. H. Zhu
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  3. Y. Q. Jia
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Correspondence to S. R. Luan.

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Luan, S.R., Zhu, Y.H. & Jia, Y.Q. Alanine- and taurine-salicylal Schiff base complexes of magnesium. J Therm Anal Calorim 95, 951–956 (2009). https://doi.org/10.1007/s10973-008-8926-1

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  • DOI: https://doi.org/10.1007/s10973-008-8926-1

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