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Nickel(II) complexes prepared from NNN type ligands and pseudohalogens

Synthesis, structure and thermal decomposition

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Abstract

Six nickel(II) complexes, using azide and thiocyanate ions, have been synthesized from bis-2,6(pyrazol-1-yl)pyridine (pp) and some methyl derivatives, 2-(3,5-dimethyl(pyrazol-1-yl)-6-(pyrazol-1-yl)pyridine (app) and bis-2,6(3,5-dimethyl(pyrazol-1-yl) pyridine (dmpp) in non-aqueous media. The complex structures were analyzed using elemental analysis, IR spectroscopy and thermogravimetry. Appropriate crystals of complex, containing azide [Nipp(N3)2]·MeOH (I) and thiocyanate [Nidmpp(SCN)2·MeOH] (VI) were prepared and the molecular structures determined using X-ray diffraction. Complex I was seen to be dinuclear as stated in literature, space group P21/n, monoclinic, a=10.503, b=10.681, c=13.291 Å, β=106.56° and Z=2 whereas complex VI was found to be mononuclear, space group P21/n, monoclinic, a=8.646, b=12.614, c=20.697 Å, β=97.18° and Z=2. The Ni(II) coordination in both complexes were octahedral. Thermogravimetric studies showed azide containing structures to resemble the characteristics of explosive materials. Coordinative MeOH were seen to leave the structure in thiocyanate containing complexes, followed by irregular degradation above 300°C.

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Authors and Affiliations

  1. Faculty of Pharmacy, Department of Analytical Chemistry, Mersin University, Mersin, Turkey

    F. Nazli Dınçer Kaya

  2. Strukturforschung, FB Materialwissenschaft, Technische Hochschule, Darmstadt Petersenstrasse 23, D-64287, Darmstadt, Germany

    Ingrid Svoboda

  3. Science Faculty, Department of Chemistry, Ankara University, Tando ğan, 06100, Ankara, Turkey

    Orhan Atakol, Ümıt Ergun, Adnan Kenar & Kaan C. Emregül

  4. Faculty of Education, Gazi University, Beşevler Ankara, Turkey

    Musa Sari

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  1. F. Nazli Dınçer Kaya
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  2. Ingrid Svoboda
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  3. Orhan Atakol
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  4. Ümıt Ergun
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  7. Kaan C. Emregül
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Correspondence to Orhan Atakol.

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In dedication to the 66th birthday of Prof. Dr. h.c. Hartmut Fuess

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Nazli Dınçer Kaya, F., Svoboda, I., Atakol, O. et al. Nickel(II) complexes prepared from NNN type ligands and pseudohalogens. J Therm Anal Calorim 92, 617–624 (2008). https://doi.org/10.1007/s10973-007-7709-4

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  • DOI: https://doi.org/10.1007/s10973-007-7709-4

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