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Adsorption and porosity properties of carbon-covered alumina surfaces

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Abstract

Uniformly carbon-covered alumina (CCA) was prepared via the carbonisation of sucrose highly dispersed on the alumina surface. Using special thermogravimetry and sorptometry methods physicochemical properties of carbon-covered alumina surfaces were investigated. A numerical and analytical procedure for the evaluation of total heterogeneous properties (desorption energy distribution and pore-size distribution functions) on the basis of liquid thermodesorption from the sample surfaces under the quasi-equilibrium conditions are presented. The desorption energy distribution was derived from the mass loss Q-TG and the differential mass loss Q-DTG curves of thermodesorption of pre-adsorbed polar and apolar liquid films. For the first time, the evaluation of the fractal dimensions of carbon-covered alumina using the sorptometry, thermogravimetry and AFM data is presented.

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Błachnio, M., Staszczuk, P., Grodzicka, G. et al. Adsorption and porosity properties of carbon-covered alumina surfaces. J Therm Anal Calorim 88, 601–606 (2007). https://doi.org/10.1007/s10973-006-8067-3

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  • DOI: https://doi.org/10.1007/s10973-006-8067-3

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