Abstract
Heat capacity C p(T) of dysprosium diboride is experimentally investigated at the temperatures of 5–300 K. On the dependence C p(T) smooth anomaly at the temperatures of 15–20 K and sharp anomalies at T m1=47.8 K and T m2=178.8 K are revealed. Anomaly at T m1 is caused, obviously, by ferromagnetic phase transition in DyB2. The lattice contribution to DyB2 heat capacity is determined by comparison with heat capacity of non-magnetic YB2. The estimation of Schottky contribution to DyB2 heat capacity is made, the scheme of splitting of the ground state of Dy3+ ion is offered.
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K. H. J. Buschov, Boron and Refractory Borides, V. I. Matkovich, Ed., NY 1977, p. 494.
G Will KHJ Buschov V Lehman (1978) Inst. Phys. Conf. Ser. 37 255 Occurrence Handle1:CAS:528:DyaE1cXkvVertbg%3D
NN Sirota AM Antyukhov VV Novikov VA Fyodorov (1982) Cryst. Res. Technol. 13 279 Occurrence Handle10.1002/crat.2170170302
JW Stout E Catalano (1955) J. Chem. Phys. 23 2013 Occurrence Handle10.1063/1.1740657 Occurrence Handle1:CAS:528:DyaG28XhsV2hsg%3D%3D
S. A. Altshuler and B. M. Kozyrev, Electron Paramagnetic Resonance, Moscow 1961, p. 368.
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Novikov, V.V., Matovnikov, A.V. Low-temperature heat capacity of dysprosium diboride. J Therm Anal Calorim 88, 597–599 (2007). https://doi.org/10.1007/s10973-006-8054-8
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DOI: https://doi.org/10.1007/s10973-006-8054-8