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Thermal and dynamic mechanical analysis of cross-linked poly(esterurethanes)

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Abstract

New cross-linked poly(esterurethanes) (PEU) based on unsaturated olygo(alkyleneester)diol (OAE), 4,4’-diphenylmethane diisocyanate (MDI) and styrene or methyl methacrylate as curing monomers were prepared. The synthesis of PEU was performed in two steps. In the first step OAE was obtained from adipic acid, maleic anhydride and ethylene glycol. In the second step a prepolymer was obtained in a reaction of OAE with different amounts of 4,4’-diphenylmethane diisocyanate followed by crosslinking using previously mentioned curing monomers. The influence of structure of the poly(esterurethanes) on thermal and dynamic mechanical properties is studied. Thermogravimetric analysis shows that cross-linked poly(esterurethanes) demonstrate high thermal stability. Moreover the dynamic mechanical thermal analysis shows that the presence of styrene cross-linking chains in polymers lead to the phase separation in cross-linked poly(esterurethanes).

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Authors and Affiliations

  1. Faculty of Chemistry, Department of Polymer Technology, Gdańsk University of Technology, Gdańsk, Poland, 80-952, Narutowicza St 11/12

    Lidia Jasińska, A. Balas & J. T. Haponiuk

  2. Faculty of Physics, Department of Macromolecular Physics, Adam Mickiewicz University, Poznań, Poland, 61-614, Umultowska St 85

    G. Nowaczyk & S. Jurga

Authors
  1. Lidia Jasińska
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  2. A. Balas
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  3. J. T. Haponiuk
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  4. G. Nowaczyk
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  5. S. Jurga
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Correspondence to Lidia Jasińska.

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Jasińska, L., Balas, A., Haponiuk, J.T. et al. Thermal and dynamic mechanical analysis of cross-linked poly(esterurethanes). J Therm Anal Calorim 88, 419–423 (2007). https://doi.org/10.1007/s10973-006-8033-0

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  • DOI: https://doi.org/10.1007/s10973-006-8033-0

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