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Three N2O2 ligands derived from the condensation of 1,2-cyclohexanediaminewith salicylaldehyde, acetylacetone and benzoylacetone

A new contribution to the energetical characterization of Schiff bases

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Abstract

The standard (p 0=0.1 MPa) molar enthalpies of formation, at T=298.15 K, in the gaseous phase, for three tetradentate Schiff bases involving a N2O2 set, N,N’-bis(salicylaldehydo)cyclohexanediimine (H2salch), N,N’-bis(acetylacetone)cyclohexanediimine (H2acacch) and N,N’-bis(benzoylacetone)cyclohexanediimine (H2bzacch), were determined from their enthalpies of combustion and sublimation, obtained by static bomb calorimetry in oxygen and by the Knudsen effusion technique, respectively. The results are compared with identical parameters for related compounds previously studied, resulting from the condensation of salicylaldehyde or β-diketone with aliphatic diamines.

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Authors and Affiliations

  1. Centro de Investigação em Química, Departamento de Química, Faculdade de Ciências, Universidade do Porto, Porto, Portugal, 4169-007, Rua do Campo Alegre, 687

    Maria D. M. C. Ribeiro da Silva, N. R. M. Araújo, A. L. R. Silva, L. C. M. da Silva, N. P. S. M. Barros, J. M. Gonçalves & M. A. V. Ribeiro da Silva

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  1. Maria D. M. C. Ribeiro da Silva
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  2. N. R. M. Araújo
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  3. A. L. R. Silva
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  4. L. C. M. da Silva
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  5. N. P. S. M. Barros
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  6. J. M. Gonçalves
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  7. M. A. V. Ribeiro da Silva
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Correspondence to Maria D. M. C. Ribeiro da Silva.

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Ribeiro da Silva, M.D.M.C., Araújo, N.R.M., Silva, A.L.R. et al. Three N2O2 ligands derived from the condensation of 1,2-cyclohexanediaminewith salicylaldehyde, acetylacetone and benzoylacetone. J Therm Anal Calorim 87, 291–296 (2007). https://doi.org/10.1007/s10973-006-7808-7

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  • DOI: https://doi.org/10.1007/s10973-006-7808-7

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