Skip to main content
SpringerLink
Log in

Temperature-programmed desorption of n-hexane from hydrated HZSM-5 and NH4ZSM-5 zeolites

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Temperature-programmed desorption coupled with mass spectrometer as a detector (TPD), IR and 13C NMR measurements are used to study the adsorption of n-hexane on hydrated HZSM-5 and NH4ZSM-5 zeolites. The 13C NMR measurements show that n-hexane can access the pore structure of ZSM-5 zeolites previously saturated with water. TPD spectra of n-hexane are monitored in the temperature region 50–300°C, in the case of fully or partially hydrated samples; two-stage desorption of n-hexane is found. Simultaneous desorption of water and n-hexane in the same temperature region are found, in all investigated samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. B Smit JI Siepmann (1994) Science 264 1118 Occurrence Handle1:CAS:528:DyaK2cXktFyru7s%3D

    CAS  Google Scholar 

  2. SP Bates WJM van Well RA van Santen B Smit (1996) J. Am. Chem. Soc. 118 6753 Occurrence Handle10.1021/ja953856q Occurrence Handle1:CAS:528:DyaK28Xjsl2ruro%3D

    Article  CAS  Google Scholar 

  3. F Eder JA Lercher (1997) Zeolites 18 75 Occurrence Handle10.1016/S0144-2449(96)00127-3 Occurrence Handle1:CAS:528:DyaK2sXptFaquw%3D%3D

    Article  CAS  Google Scholar 

  4. WJM van Well JP Wolthuizen B Smit JHC Hooff RA van Santen (1995) Angew. Chem., Int. Ed. Engl. 34 2543 Occurrence Handle10.1002/anie.199525431 Occurrence Handle1:CAS:528:DyaK2MXpslOms7g%3D

    Article  CAS  Google Scholar 

  5. WJM van Well JP Wolthuizen B Smit JHC Hooff RA van Santen (1997) Stud. Surf. Sci. Catal. 105 2347

    Google Scholar 

  6. MS Sun O Talu DB Shan (1996) J. Phys. Chem. 100 17276 Occurrence Handle1:CAS:528:DyaK28XlvF2is7s%3D

    CAS  Google Scholar 

  7. B Smit TLM Maesen (1995) Nature 374 42 Occurrence Handle1:CAS:528:DyaK2MXktFCrtr0%3D

    CAS  Google Scholar 

  8. RE Richards LVC Rees (1987) Langmuir 3 335 Occurrence Handle10.1021/la00075a009 Occurrence Handle1:CAS:528:DyaL2sXhvVejtLY%3D

    Article  CAS  Google Scholar 

  9. AG Stepanov TO Shegai MV Luzgin H Jobic (2003) Eur. Phys. J. 12 57 Occurrence Handle1:CAS:528:DC%2BD3sXpvV2gsro%3D

    CAS  Google Scholar 

  10. PA Jacobs HK Beyer J Valyon (1981) Zeolites 1 1 Occurrence Handle10.1016/S0144-2449(81)80006-1 Occurrence Handle1:CAS:528:DyaL38XjtlKlsQ%3D%3D

    Article  CAS  Google Scholar 

  11. Y Yang LVC Rees (1997) Microporous Mater. 12 177

    Google Scholar 

  12. H Morell K Angermund AR Lewis DH Brouwer CA Fyfe H Gies (2002) Chem. Mater. 14 2192 Occurrence Handle10.1021/cm011267f Occurrence Handle1:CAS:528:DC%2BD38XivVGnsbY%3D

    Article  CAS  Google Scholar 

  13. DH Olson PT Reischman (1996) Zeolites 17 434 Occurrence Handle10.1016/S0144-2449(96)00087-5 Occurrence Handle1:CAS:528:DyaK28XmsVCrsL4%3D

    Article  CAS  Google Scholar 

  14. Y Yang LVC Ress (1997) Microporous Mater. 12 223 Occurrence Handle1:CAS:528:DyaK2sXnt1GrsrY%3D

    CAS  Google Scholar 

  15. B Millot A Methivier H Jobic (1998) J. Phys. Chem. B 103 3210

    Google Scholar 

  16. W Makowski D Majda (2004) Thermochim. Acta 412 131 Occurrence Handle10.1016/j.tca.2003.09.003 Occurrence Handle1:CAS:528:DC%2BD2cXhvV2ntrg%3D

    Article  CAS  Google Scholar 

  17. AG Stepanov AA Shubin MV Luzgin TO Shegai H Jobic (2003) J. Phys. Chem. B 107 7095 Occurrence Handle1:CAS:528:DC%2BD3sXkvFWlsLg%3D

    CAS  Google Scholar 

  18. LJM van de Ven JW de Haan A Bucinska (1982) J. Phys. Chem. 86 2516

    Google Scholar 

  19. WJM van Well X Cottin JW de Haan B Smit G Nivarthy JA Lercher JHC van Hooff RA van Santen (1998) J. Phys. Chem. B 102 3945 Occurrence Handle1:CAS:528:DyaK1cXjt1GitLc%3D

    CAS  Google Scholar 

  20. S Ashtekar AS McLeod MD Mantle PJ Barrie LF Gladden JJ Hastings (2000) J. Phys. Chem. B 104 5281 Occurrence Handle10.1021/jp993966+ Occurrence Handle1:CAS:528:DC%2BD3cXjtV2msbk%3D

    Article  CAS  Google Scholar 

  21. JE Gallot H Fu MP Kapoor S Kaliaguine (1996) J. Catal. 161 798 Occurrence Handle10.1006/jcat.1996.0243 Occurrence Handle1:CAS:528:DyaK28XltVCmu7s%3D

    Article  CAS  Google Scholar 

  22. B Hunger S Matysik M Heuchel WD Einicke (2001) J. Therm. Anal. Cal. 64 1183 Occurrence Handle10.1023/A:1011501214204 Occurrence Handle1:CAS:528:DC%2BD3MXlslKqurs%3D

    Article  CAS  Google Scholar 

  23. A Malka-Edery K Abdallah Ph Grenier F Meunier (2001) Adsorption 7 17 Occurrence Handle10.1023/A:1011216832274 Occurrence Handle1:CAS:528:DC%2BD3MXjs1ajtLs%3D

    Article  CAS  Google Scholar 

  24. V Dondur V Rakić Lj Damjanović A Auroux (J. Serb. Chem. Soc.) 2005 70 357

    Google Scholar 

  25. DH Olson WD Haag RM Lago (1980) J. Catal. 61 390 Occurrence Handle10.1016/0021-9517(80)90386-3 Occurrence Handle1:CAS:528:DyaL3cXktFeksLg%3D

    Article  CAS  Google Scholar 

  26. H Nakamoto H Takahashi (1982) Zeolites 2 67 Occurrence Handle10.1016/S0144-2449(82)80002-X Occurrence Handle1:CAS:528:DyaL38Xksl2nurg%3D

    Article  CAS  Google Scholar 

  27. M Noack P Kölch V Seefeld P Toussaint G Georgi J Caro (2005) Microporous Mesoporous Mater. 79 329 Occurrence Handle1:CAS:528:DC%2BD2MXisVSgu7o%3D

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Physical Chemistry, Belgrade, Serbia and Montenegro, 11000, Studentski trg 12–16

    Dondur Vera, Damjanović Ljiljana & Hercigonja Radmila

  2. Faculty of Agriculture, Belgrade-Zemun, Serbia and Montenegro, 11080, Nemanjina 6

    Rakić Vesna

  3. Institut de Recherches sur la Catalyse, Villeurbanne, France, 69626, 2 Av. A. Einstein

    Auroux Aline

Authors
  1. Dondur Vera
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Rakić Vesna
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Damjanović Ljiljana
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Hercigonja Radmila
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Auroux Aline
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Dondur Vera.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dondur, V., Rakić, V., Damjanović, L. et al. Temperature-programmed desorption of n-hexane from hydrated HZSM-5 and NH4ZSM-5 zeolites. J Therm Anal Calorim 84, 233–238 (2006). https://doi.org/10.1007/s10973-005-7160-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-005-7160-3

Keywords

Search

Navigation