Skip to main content
SpringerLink
Log in

Kinetics of thermal decomposition of mixed-ligand nikkel(II) and copper(II) complexes of 4-acyl pyrazolone derivative and pyridine

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Thermal behaviors of two mixed-ligand complexes, [Ni(PMPP-SAL)(Py)3] and [Cu(PMPP-SAL)Py]·MeOH, (PMPP-SAL=1-phenyl-3-methyl-4-(salicylidene hydrazide)-propenylidene-pyrazolone-5, Py=pyridine), were studied by TG-DTG-DTA in dynamic air atmosphere. The complexes show the loss of pyridine molecule is followed by the decomposition of the PMPP-SAL anion and give respective metal oxides as residues. Meanwhile, the Ozawa-Flynn-Wall model-free analyses and multivariate non-linear regressions were applied to perform single and overall steps optimization. Kinetic parameters were given and the most probable mechanism functions were suggested in this study.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N. Raman, A. Kulandaisamy, A. Shunmugasundaram and K. Jeyasubramanian, Transit. Met. Chem., 26 (2001) 131.

    Article  CAS  Google Scholar 

  2. T. Yoshikuni, J. Mol. Catal. A-Chem., 148 (1999) 285.

    Article  CAS  Google Scholar 

  3. B. A. Uzoukwu, P. U. Adiukwu, S. S. Al-Juaid, P. B. Hitchcock and J. D. Smith, Inorg. Chim. Acta, 250 (1996) 173.

    Article  CAS  Google Scholar 

  4. Z. Y. Yang, R. D. Yang, F. S. Li and K. B. Yu, Polyhedron, 19 (2000) 2599.

    Article  CAS  Google Scholar 

  5. W. F. Yang, S. G. Yuan, Y. B. Xu, Y. H. Xiao and K. M. Fang, J. Radioanal. Nucl. Ch., 256 (2003) 149.

    Article  CAS  Google Scholar 

  6. A. K. El-Sawaf and D. X. West, Transition Met. Chem., 23 (1998) 417.

    Article  CAS  Google Scholar 

  7. N. Kalarani, S. Sangeetha, P. Kamalakannan and D. Venkappayya, Russ. J. Coord. Chem., 29 (2003) 845.

    Article  CAS  Google Scholar 

  8. C. Pettinari, F. Marchetti, C. Santini, R. Pettinari, A. Drozdov, S. Troyanov, G. A. Attiston and R. Gerbasi, Inorg. Chim. Acta, 315 (2001) 88.

    Article  CAS  Google Scholar 

  9. F. Marchetti, C. Rettinar, R. Pettinari, A. Cingolani, D. Leonesi and A. Lorenzotti, Polyhedron, 18 (1999) 3041.

    Article  CAS  Google Scholar 

  10. O. N. Kataeva, A. T. Gubaidullin, I. A. Litvinov, O. A. Lodochnikova, L. R. Islamov, A. I. Movchan and G. A. Chmutova, J. Mol. Stuct., 610 (2002) 175.

    Article  CAS  Google Scholar 

  11. Y. Akama and A. Tong, Microchem. J., 53 (1996) 34.

    Article  CAS  Google Scholar 

  12. Y. Akama, A. Tong, N. Matsumoto, T. Ikeda and S. Tunaka, Vib. Spectrosc., 13 (1996) 113.

    Article  CAS  Google Scholar 

  13. M. F. Iskander, L. Sayed, A. F. M. Hefny and S. E. Zayan, J. Inorg. Nucl. Chem., 38 (1976) 2209.

    Article  CAS  Google Scholar 

  14. G. H. Havanur and V. B. Mahale, Indian J. Chem., 26A (1987) 1063.

    CAS  Google Scholar 

  15. H. Adams, D. E. Fenton, G. Minardi, E. Mura and M. Angelo, Inorg. Chem. Commun., 3 (2000) 4.

    Google Scholar 

  16. X. C. Tang, D. Z. Jia, K. B. Yu, X. G. Zhang, X. Xia and Z. Y. Zhou, J. Photochem. Photobiol. A: Chem., 134 (2000) 23.

    Article  CAS  Google Scholar 

  17. L. Liu, D. Z. Jia, Y. L. Ji and K. B. Yu, J. Photochem. Photobiol. A: Chem., 154 (2003) 117.

    Article  CAS  Google Scholar 

  18. L. Liu, D. Z. Jia and Y. L. Ji, Synth. React. Inorg. Met.-Org. Chem., 32 (2002) 739.

    Article  Google Scholar 

  19. Y. L. Ji, L. Liu, D. Z. Jia and K. B. Yu, Chinese J. Inorg. Chem., 19 (2003) 345.

    CAS  Google Scholar 

  20. L. Zhang, L. Liu, D. Z. Jia and K. B. Yu, Struct. Chem., 15 (2004) 327.

    Article  Google Scholar 

  21. L. Zhang, L. Liu, D. Z. Jia, G. C. Xu and K. B. Yu, Inorg. Chem. Commun., 7 (2004) 1306.

    Article  CAS  Google Scholar 

  22. B. S. Jensen, Acta Chem. Scand., 13 (1959) 1668.

    Article  CAS  Google Scholar 

  23. R. Q. Huang, H. L. Wang and J. Zhou, Preparation of Organic Intermediates, Chemistry Industrial Press, China 1997, p. 109.

    Google Scholar 

  24. D. Dollimore, P. Tong and K. S. Alexander, Thermochim. Acta, 282–283 (1996) 13.

    Article  Google Scholar 

  25. J. Opfermann, J. Therm. Anal. Cal., 60 (2000) 641.

    Article  CAS  Google Scholar 

  26. V. Logvinenko, A. Minina, Y. Mikhaylov, Y. Yukhin and B. Bokhonov, J. Therm. Anal. Cal., 74 (2003) 407.

    Article  CAS  Google Scholar 

  27. J. H. Hong, T. Y. Yi, J. Min, C. J. Cong and K. L. Zhang, Thermochim. Acta, 440 (2006) 31.

    Article  CAS  Google Scholar 

  28. S. K. Padhi, Thermochim. Acta, 448 (2006) 1.

    Article  CAS  Google Scholar 

  29. H. L. Friddman, J. Polym. Sci., 6 (1965) 183.

    Google Scholar 

  30. T. Ozawa, Bull. Chem. Soc. Jpn., 38 (1965) 1881.

    Article  CAS  Google Scholar 

  31. K. Uemura, S. Kitagawa, K. Saito, K. Fukui and K. Matsumoto, J. Therm. Anal. Cal., 81 (2005) 529.

    Article  CAS  Google Scholar 

  32. V. Alvarez, E. Rodriguez and A. Vazquez, J. Therm. Anal. Cal., 85 (2006) 383.

    Article  CAS  Google Scholar 

  33. L. S. Guinesi, C. A. Ribeiro, M. S. Crespi, A. F. Santos and M. V. Capela, J. Therm. Anal. Cal., 85 (2006) 301.

    Article  CAS  Google Scholar 

  34. S. Vyazovkin, Thermochim. Acta, 355 (2000) 155.

    Article  CAS  Google Scholar 

  35. P. Šimon, J. Therm. Anal. Cal., 76 (2004) 123.

    Article  Google Scholar 

  36. J. R. Opfermann, E. Kaisersberger and H. J. Flammersheim, Thermochim. Acta, 391 (2002) 119.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Applied Chemistry, Xinjiang University, Urumqi, 830046, P.R. China

    G. -C. Xu, L. Zhang, L. Liu, G. -F. Liu & D. -Z. Jia

Authors
  1. G. -C. Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. -F. Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. D. -Z. Jia
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to D. -Z. Jia.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Xu, G.C., Zhang, L., Liu, L. et al. Kinetics of thermal decomposition of mixed-ligand nikkel(II) and copper(II) complexes of 4-acyl pyrazolone derivative and pyridine. J Therm Anal Calorim 89, 547–553 (2007). https://doi.org/10.1007/s10973-005-6947-6

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-005-6947-6

Keywords

Search

Navigation