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Thermal degradation studies of substituted conducting polyanilines

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Abstract

The synthesis of conducting polymers based on m-nitroaniline, m-chloroaniline and m-aminophenol by aniline initiated ammonium peroxydisulfate oxidation, has been attempted. The IR spectra of the polymers have been studied. Thermogravimetric analysis of the conducting polymers has been followed using a computer analysis method LOTUS PACKAGE, developed by us for assigning the degradation mechanism. A number of equations have been used to evaluate the kinetic parameters. The mechanism of degradation of the conducting polymers has been explained on the basis of their kinetic parameters.

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References

  1. AF Diaz KK Kanazawa GP Gardini (1979) J. Chem. Soc., Chem. Commnun. 1 634

    Google Scholar 

  2. G Tourillon F Garnier (1982) J. Electroanal. Chem. 1 135

    Google Scholar 

  3. M Satoh M Tabata K Kaneto K Yoshino (1985) Polym. Commun. 26 356 Occurrence Handle1:CAS:528:DyaL28XovFKmsA%3D%3D

    CAS  Google Scholar 

  4. AF Diaz JL Logan (1980) J. Electroanal. Chem. 11 111 Occurrence Handle10.1016/S0022-0728(80)80081-7

    Article  Google Scholar 

  5. S Chao MS Wrighton (1987) J. Am. Chem. Soc. 109 6227

    Google Scholar 

  6. Y Wei WW Focke GE Wnek A Ray AG MacDiarmid (1989) J. Phys. Chem. 93 495 Occurrence Handle1:CAS:528:DyaL1MXjvFCltg%3D%3D Occurrence Handle10.1021/j100338a095

    Article  CAS  Google Scholar 

  7. CB Duke HW Gibson Kirk-Othmer et al. (1981) Encyclopedia of Chemical Technology John Wiley & Sons, Inc. New York Vol 18, 755

    Google Scholar 

  8. AG MacDiarmid SL Mu MLD Somasiri W Wu (1985) Mol. Cryst. Liq. Cryst. 121 187 Occurrence Handle1:CAS:528:DyaL2MXltFajtrc%3D

    CAS  Google Scholar 

  9. MT Nguyen LH Dao (1989) J. Electrochem. Sci. 136 2131 Occurrence Handle1:CAS:528:DyaL1MXlvVaqtLw%3D Occurrence Handle10.1149/1.2097220

    Article  CAS  Google Scholar 

  10. DT Hoa TNS Kumar NS Punekar RS Srinivasa R Lal (1992) Q. Contractor Anal. Chem 64 2645 Occurrence Handle1:CAS:528:DyaK38XmtVChsr8%3D Occurrence Handle10.1021/ac00045a031

    Article  CAS  Google Scholar 

  11. M. Angelopopulos, Presented at the NATO ARW Applications of Intrinsically Conducting Polymers, Champaign, VT, Oct. 1992.

  12. M Leclerc J Guay LH Dao (1989) Macromolecules 22 649 Occurrence Handle1:CAS:528:DyaL1MXpsF2jtQ%3D%3D Occurrence Handle10.1021/ma00192a024

    Article  CAS  Google Scholar 

  13. M Leclerc J Guay LH Dao (1988) J. Electroanal. Chem. 251 21 Occurrence Handle1:CAS:528:DyaL1cXlvF2rsLo%3D Occurrence Handle10.1016/0022-0728(88)80381-4

    Article  CAS  Google Scholar 

  14. HSO Chan MYB Teo E Khor CN Lim (1989) J. Thermal Anal. 35 765 Occurrence Handle1:CAS:528:DyaK3cXjs1Kkuw%3D%3D Occurrence Handle10.1007/BF02057231

    Article  CAS  Google Scholar 

  15. JC Chiang AG MacDiarmid (1986) Synth. Met. 13 193 Occurrence Handle1:CAS:528:DyaL28XhtlSmu78%3D Occurrence Handle10.1016/0379-6779(86)90070-6

    Article  CAS  Google Scholar 

  16. SN Swain KK Rao PL Nayak (2004) J. Appl. Polym. Sci. 93 2590 Occurrence Handle1:CAS:528:DC%2BD2cXms1ehs70%3D Occurrence Handle10.1002/app.20729

    Article  CAS  Google Scholar 

  17. X Gao D Dollimore (1993) Thermochim. Acta 215 47 Occurrence Handle1:CAS:528:DyaK3sXisVWrs7g%3D Occurrence Handle10.1016/0040-6031(93)80081-K

    Article  CAS  Google Scholar 

  18. SN Swain KK Rao PL Nayak (2004) J. Therm. Anal. Cal. 79 33 Occurrence Handle10.1007/s10973-004-0558-5

    Article  Google Scholar 

  19. S Jeyanthi et al. (2004) Thermal studies on strontium oxalate doped with lanthanides, Ph.D. thesis Utkal University India 157

    Google Scholar 

  20. B Jurka I Salageanu E Segal (2000) J. Therm. Anal. Cal. 62 845 Occurrence Handle10.1023/A:1026798131113

    Article  Google Scholar 

  21. EM Abd Alla MI Abdel Hamid (2000) J. Therm. Anal. Cal. 62 769 Occurrence Handle10.1023/A:1026789828387

    Article  Google Scholar 

  22. T Pattnaik PL Nayak S Lenka S Mohanty KK Rao (1994) Thermochim. Acta 240 235 Occurrence Handle1:CAS:528:DyaK2cXlvVSrtr8%3D Occurrence Handle10.1016/0040-6031(94)87045-4

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Biodegradable Polymer Research Laboratory, Department of Chemistry, Ravenshaw University, Orissa, India, Cuttack-753003

    D. K. Dash, S. K. Sahu & P. L. Nayak

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  1. D. K. Dash
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  2. S. K. Sahu
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  3. P. L. Nayak
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Correspondence to P. L. Nayak.

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Dash, D.K., Sahu, S.K. & Nayak, P.L. Thermal degradation studies of substituted conducting polyanilines. J Therm Anal Calorim 86, 517–520 (2006). https://doi.org/10.1007/s10973-005-6845-y

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  • DOI: https://doi.org/10.1007/s10973-005-6845-y

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