Abstract
The preparation of YBa2Cu3O7−x (YBCO) film by low fluorine metal-organic deposition methodology has been extensively studied recently for its high efficiency and low cost. However, the relationship between the heating rate during pyrolysis and the fluorine content of precursor is still unclear and hence no universal thermal process has been widely accepted. In this work, we present the influence of different decomposition time for the YBCO films prepared by the precursor solutions with three F/Ba mole ratios of 6:1, 2:1, and 1:1 (the fluorine contents are 28.6, 9.5, and 4.8 % in the solutions, respectively). The similar X-ray diffraction (XRD) curves show that YBCO films with favorable c-axis oriented textures can be obtained by all the solutions and thermal processes. However, the ω-scan results and surface morphologies indicate that the film prepared by the low-fluorine solutions tend to deteriorate in out-of-plane orientation, but the surface morphologies are not easily wrinkled as the heating rates increase. Jc-B results show that the superior YBCO film with the Jc value up to 5.2 MA/cm2 could be prepared by the precursor with the F/Ba mole ratio of 2:1 under the optimal decomposition process (a heating rate of 2 K/min). Considering the synergistic effect of the heating rate and fluorine content, a heat treatment strategy for obtaining satisfactory YBCO films was also proposed.
Typical comparison of YBa2Cu3O7−x films prepared by different heat treatment processes in the decomposition stage. An ultra-high critical current density (ec) can be achieved as an optimized heating rate is adopted. Then the Jc value will drop significantly if the heating rate exceeds the wrinkle rate.
Highlights
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The extraordinary high Jc value up to 5.2 MA/cm2 was obtained in the pure YBCO film by optimizing the heat treatment process for the specific precursor solution.
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The orientation, surface morphology, texture, and performance of YBCO films fabricated by the different low-fluorine precursor solutions and heating rates are systematically investigated for the first time.
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A reasonable heat treatment strategy is proposed for obtaining satisfactory YBCO films considering the synergistic effect of the heating rate and fluorine content.
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Acknowledgements
Project supported by the National Natural Science Foundation of China (Grant No. 51577180, Grant No. 51577181, and Grant No. 51477168) and the Youth Innovation Promotion Association of the Chinese Academy of Sciences (2016128).
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Dong, Z., Gu, H., Zhang, H. et al. Heat treatment design of precursor solutions with different fluorine contents for YBa2Cu3O7−x films through the sol-gel approach. J Sol-Gel Sci Technol 90, 263–270 (2019). https://doi.org/10.1007/s10971-019-04940-5
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DOI: https://doi.org/10.1007/s10971-019-04940-5