Skip to main content
SpringerLink
Log in

Synthesis and characterization of immobilized-polysiloxane monoamine-thiol triacetic acid and its diamine and triamine derivatives

  • Original Paper: Sol-gel, hybrids and solution chemistries
  • Published:
Journal of Sol-Gel Science and Technology Aims and scope Submit manuscript

Abstract

In this work, a new porous solid polysiloxane material with thiol-amine-based multiple functional groups polysiloxane-(monoamine-thiol) triacetate, P-(N-S)-TrEA (where P- represents [Si–O]n polysiloxane network), was synthesized using one-pot reaction of TEOS with 3-iminodiethylacetatepropyltrimethoxysilane and 3-thiolethylacetatepropyltrimethoxysilane in the presence of CTAB as a surfactant. Its ethylenediamine and diethylenetriamine-modified polysiloxane-(monoamine-thiol)-tris(N-2-aminoethylacetamide), P-(N-S)-TrEA-NN, and polysiloxane-(monoamine-thiol)-tris(N-3,6-diazahexylacetamide), P-(N-S)-TrEA-NNN, chelating ligand systems were also obtained. The previously reported simple functionalized polysiloxane (monoamine-thiol) has been modified to obtain thiol-monoamine-based multiple functional groups. A variety of methods and techniques including FTIR, solid-state 13C NMR, XPS and TGA have been used for establishing their structure.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Scheme 2
Scheme 3
Scheme 4
Scheme 5
Fig. 1
Fig. 2
Scheme 6
Scheme 7
Scheme 8
Scheme 9
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16
Fig. 17
Fig. 18
Fig. 19

Similar content being viewed by others

References

  1. McLaren JW, Mykytiuk AP, Willie SN, Berman SS (1985) Anal Chem 57:2907–2911

    Article  Google Scholar 

  2. Sharma RK (2001) Pure Appl Chem 73(1):181–186

    Article  Google Scholar 

  3. Kvitek RJ, Evans JF, Carr PW (1982) Anal Chim Acta 144:93–98

    Article  Google Scholar 

  4. Van Grieken R (1982) Anal Chim Acta 143:3–34

    Article  Google Scholar 

  5. Sulthivaiyakit P, Kettrup A (1985) Anal Chim Acta 169:331–339

    Article  Google Scholar 

  6. Jal PK, Dutta RK, Sudershan M, Saha A, Bhattacharya SN, Chintalapudi SN, Mishra BK (2001) Talanta 55:233–240

    Article  Google Scholar 

  7. Khatib IS, Parish RV (1989) J Organomet Chem 369:9–16

    Article  Google Scholar 

  8. El-Nahhal IM, Parish RV (1993) J Organomet Chem 452:19–22

    Article  Google Scholar 

  9. Ahmed I, Parish RV (1993) J Organomet Chem 452:23–28

    Article  Google Scholar 

  10. El-Nahhal IM, El-Shetary BA, Salib KAR, El-Ashgar NM, El-Hashash AM (2001) Anal Lett 34:2189–2202

    Article  Google Scholar 

  11. El-Nahhal IM, El-Ashgar NM, Chehimi MM (2003) Microporous Mesoporous Mater 65(2–3):299–310

    Article  Google Scholar 

  12. El-Ashgar NM (2008) J Chem 5:107–113

    Google Scholar 

  13. Saadeh SM, El-Ashgar NM, El-Nahhal IM, Chehimi MM, Maquet J, Babonneau F (2005) Appl Organomet Chem 19:759–767

    Article  Google Scholar 

  14. El-Ashgar NM, El-Nahhal IM, Chehimi MM, Babonneau F, Livage J (2005) Monats Chem 137:263–275

    Article  Google Scholar 

  15. El-Nahhal IM, El-Ashgar NM, Livage J, Chehimi MM, Babonneau F (2007) Mater Lett 61:4553–4558

    Article  Google Scholar 

  16. El-Ashgar NM, El-Nahhal IM, Chehimi MM, Babonneau F, Livage J (2009) Int J Environ Anal Chem 89(14):1057–1069

    Article  Google Scholar 

  17. Innocenzi P, Zub YL, Kessler VG (2008) Sol–gel methods for materials processing, NATO science for peace and security series C: environmental security. Springer, New York

    Google Scholar 

  18. El-Ashgar NM, El-Nahhal IM, Chehimi MM, Babonneau F, Livage J (2012) Phosphorus Sulfur Silicon Relat Elem 187:392–402

    Article  Google Scholar 

  19. El-Nahhal IM, El-Ashgar NM, Abu-Shawish AA, Ahmed MA, Babonneau F (2015) Phosphorus Sulfur Silicon Relat Elem. doi:10.1080/10426507.2015.1012667

    Google Scholar 

  20. El-Ashgar NM, Silmi MK, El-Nahhal IM, Chehim MM, Babonneau F (2015) Silicon. doi:10.1007/s12633-015-9303-x

    Google Scholar 

  21. El-Nahhal IM, El-Ashgar NM (2007) J Organomet Chem 692:2861–2886

    Article  Google Scholar 

  22. El-Nahhal IM, Yang JJ, Chuang IS, Maciel GE (1996) J Non Cryst Solids 208:105–117

    Article  Google Scholar 

  23. Yang JJ, El-Nahhal IM, Maciel GE (1997) J Non Cryst Solids 212:281–291

    Article  Google Scholar 

  24. El-Nahhal IM (2000) Phosphorus Sulfur Silicon Relat Elem 162:245–258

    Article  Google Scholar 

  25. Yang JJ, El-Nahhal IM, Chung IS, Maciel GE (1997) J Non-Cryst Solid 202:19–39

    Article  Google Scholar 

  26. El-Nahhal IM, El-Ashgar NM (2006) J Dispers Sci Technol 27(7):915–919

    Article  Google Scholar 

  27. Davornic PR, Lenz RW (1990) High temperature siloxane elastomers. Huthing and Wepf Verlag, Basel, Heidelberg, New York

    Google Scholar 

  28. Vansant EF, Van Der Voort P, Vrancken KC (1995) Characterization and chemical modification of the silica surface. In: Studies in surface science catalysis. Elsevier Science, Amsterdam

  29. Klonkowski AM, Koehler K, Schlaepfer CW (1993) J Mater Chem 3:105–110

    Article  Google Scholar 

  30. Kłonkowski AM, Koehler K, Widernik T, Grobelna B (1996) J Mater Chem 6(4):579–584

    Article  Google Scholar 

  31. Klonkowski AM, Widernik T, Grobelna B (2001) J Sol–Gel Sci Technol 20:161–180

    Article  Google Scholar 

  32. Jovanovic JD, Govedarica MN, Dvornic PR, Popovic IG (1998) Polym Degrad Stab 61:87–93

    Article  Google Scholar 

  33. Sakpal T, Kumar A, Kamble S, Kumar R, Chemical Engineering and Process Development (2012) Division CSIR-National Chemical Laboratory, Pune 411 008, India

Download references

Acknowledgments

The authors would like to thank the French Government for the Al-Maqdisi grant jointly with the Palestinian Ministry of Higher Education.

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Women for Arts, Science and Education, Ain Shams University, Cairo, Egypt

    Mona A. Ahmed & Asmah A. Abu Shaweesh

  2. Department of Chemistry, The Islamic University of Gaza, PO Box 108, Gaza, Palestine

    Nizam M. El-Ashgar

  3. Department of Chemistry, Al-Azhar University, PO Box 1277, Gaza, Palestine

    Issa M. El-Nahhal

  4. ITODYS Laboratory, Leader of the Surface and Interface Research Team Université Paris, Diderot -CNRS (UMR 7086), 15 rue Jean de Baïf, 75013, Paris, France

    Mohamed M. Chehimi

  5. Laboratoire de Chimie de la Matière Condensée de Paris, Université Pierre Curie-Paris 6, Paris, France

    Florence Babonneau

  6. CNRS, Collège de France, 11 Place Marcelin Berthelot, 75231, Paris, France

    Florence Babonneau

Authors
  1. Mona A. Ahmed
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Asmah A. Abu Shaweesh
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Nizam M. El-Ashgar
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Issa M. El-Nahhal
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Mohamed M. Chehimi
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Florence Babonneau
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Nizam M. El-Ashgar.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ahmed, M.A., Abu Shaweesh, A.A., El-Ashgar, N.M. et al. Synthesis and characterization of immobilized-polysiloxane monoamine-thiol triacetic acid and its diamine and triamine derivatives. J Sol-Gel Sci Technol 78, 660–672 (2016). https://doi.org/10.1007/s10971-016-3980-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10971-016-3980-9

Keywords

Search

Navigation